臺灣博碩士論文加值系統

針對臭氧問題，著眼於控制臭氧前驅物揮發性有機物排放的效益上，以臭
氧生成潛勢概念所研擬的控制策略較傳統以質量觀點的管制方法為佳。本
研究以台灣排放資料庫(TEDS)為基礎，配合美國環保署Speciate資料庫，
直接採用Carter所建立揮發性有機物之MIR(最大增量反應性)指標，探討
台灣南部地區揮發性有機物的臭氧生成潛勢。
在碳氫化合物排放量和臭氧生成潛勢方面，皆以生物源為最大。而物種在
各污染源之臭氧生成當量方面，其中點源以乙烯的臭氧生成當量最大，線
源為一氧化碳，面源為甲苯，生物源以乙烯為最大。若不考量生物源，只
討論點線面三種污染源物種之臭氧生成潛勢，乙烯、甲苯和一氧化碳佔全
部臭氧生成當量的40.10﹪。
應用光化學反應性軌跡模式檢討MIR指標對南部地區之適用性，對點線面
三種污染源臭氧當量前三名的物種：乙烯、甲苯和一氧化碳，減量100﹪
，對降低臭氧濃度並不能有顯著的效果 (＜2.00﹪)。若針對NOx污染源予
以減量20﹪，臭氧濃度降低的效果可達約60﹪以上。而MIR指標較適用於
臭氧生成的敏感因子為VOC，然而南部地區在EKMA減量模式中，是屬於NOx
為限制因子，故MIR指標應用於南部地區臭氧前驅物減量方面並不是一個
敏感指標。

To improve ozone air quality, the benefit of reduction in
volatile organic compounds (VOCs) according to ozone formation
potential was better than to traditional mass control. Using
the Taiwan Emission Data System (TEDS) in association with the
Speciate database developed by the U.S. EPA, the ozone
formation potential in Southern Taiwan was determined by the
Maximum Incremental Reactivity (MIR) Scale of volatile organic
compounds (VOCs).
The results show that the major source of VOC emissions and
ozone formation was biogenic emissions. With regards to ozone
formation by pollution type, the VOC with the maximum ozone
formation potential was ethylene in point source pollution,
carbon monoxide in line source pollution, toluene in area
source pollution, and ethylene in biogenic source pollution.
Excepting the biogenic source, ethylene, toluene, and carbon
monoxide accounted for 40.10﹪of total estimated ozone
formation.
The photochemical trajectory model was used to evaluate whether
the MIR scale was applicable to Southern Taiwan. Reduction in
ozone concentrations by completely eliminating ethylene,
toluene, and carbon monoxide was not significant (<2.00﹪).
Decreasing NOx emissions by 20﹪on the other hand, increased
ozone reduction to over 60﹪. The MIR scale is more suitable
for conditions where ozone formation is the most sensitive to
VOC. According to the EKMA elimination model, ozone formation
in Southern Taiwan is l