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研究生:陳明怡
研究生(外文):Chen,ming-yie
論文名稱:芳香族聚酯/液晶聚酯之反應型增容摻合研究
論文名稱(外文):Reactive compatibilized polyer blends of PAR/LCP
指導教授:張豐志
指導教授(外文):Chang,Feng-Chih
學位類別:碩士
校院名稱:國立交通大學
系所名稱:應用化學研究所
學門:自然科學學門
學類:化學學類
論文種類:學術論文
論文出版年:1997
畢業學年度:85
語文別:中文
論文頁數:85
中文關鍵詞:摻合芳香族聚酯液晶高分子反應型相容劑環氧樹脂異氰酸酯
外文關鍵詞:blendpolyarylateliquid crystalline polymerreactive compatibilizerepoxyisocyanate
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本文利用四官能基環氧樹及異氰酸酯作為反應型相容劑,與芳香族聚酯(polyarylate)及液晶聚酯(liquid crystalline polymer)摻混系統中進行摻合反應.藉由熔融加工過程使反應型相容劑與PAR/LCP末端基進行反應,而生成PAR-co-LCP共聚物來改善兩相間相容性.期望利用LCP高流動性質,高剛性及自我補強效應來改善PAR之加工性及機械性質.從微差掃描式熱分析儀,毛細管流變儀及熔融指數測試均證明相容劑加入後基材分子量的改變. 掃描式電子顯微鏡及機械性質結果則更加證實反應型相容劑確實成功的改善了PAR/LCP摻混系統的相容性.

This article reveals that the already known improved properties of the thermoplastic polymer(TP) - liquid crystalline polymer(LCP) blends can be further improved substantially over the corresponding noncompatibilizationcounterparts by using a reaction in-situ compatibilizer, a commercially anailable tetra-functional epoxy and isocyanate. The effect of the compatibilization was investigated by morphology, rheology and mechanical properties. Morphologyof compatibilized in-situ composites was found the fiber in the skin become finer and the domain on the core was small than noncompatibilizer. Thisimprovement is ascribed to better adhesion between the PAR matrix with the LCPfiber and better dispersion of the LCP fiber. It required only a very small amount of the epoxy and isocyanate monomers, a few fractions of one precent,to improve drastically the mechanical properties of the PAR/LCP blends. Theshear viscosity was increase when added epoxy and isocyanate monomers and demonstrate the molecular weight was increased.

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