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研究生:蔣作群
研究生(外文):CHIANG, TSO CHUNG
論文名稱:高鑄造性及表面處理性之鋁合金研究
論文名稱(外文):The reaserch of casting and anodizing for aluminum alloy
指導教授:歐炳隆、陳炎成陳炎成引用關係、歐陽浩
指導教授(外文):Ou Bin-Lung、Si-lang Liao、Amie Parry
學位類別:碩士
校院名稱:國立中央大學
系所名稱:機械工程學系
學門:工程學門
學類:機械工程學類
論文種類:學術論文
論文出版年:1997
畢業學年度:85
語文別:中文
論文頁數:62
中文關鍵詞:高鑄造性、表面處理性、銲接性、鋁合金
外文關鍵詞:514、7005、514、7005、casting、anodizing、welding、aluminum alloy
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摘 要 本研究,分兩階段執行。第一階段主要配合7000系的
A7005鋁合金 擠形管材,針對Al-Mg系鑄造514鋁合金;第二階段則針對鑄
造鋁 合金,分別以調整合金成分和均質化處理為手段,來控制合金內部
的元素分布(segregation)和微結構(microstructure),以達到本研 究目
的。在第一階段中以Al-Mg系鑄造,選擇514鋁合金為研究對 象,其主要
考慮因素﹐為母材中含所Si較低,經表面處理後,銲接 後色澤將不會偏
暗,可與擠型材(7005)色澤一致,故採低Si含量之 Al-Mg進行研究﹐但當
Si含量過低時(0.2%),鑄造時會造成鋁水 流動性大幅下降,流動不佳,
造成鑄板無法成形及孔洞現象。對鑄 造而言,為首要克服問題﹐故本研
究先行找出可行鑄造方案予以解 決。 經改良後之鑄造方式,採由冒口處
,直接頂灌澆鑄,並將鑄模傾斜 45度方式進行鑄造,可爭取極短時間,
鑄出較佳試件。另配合溫度 控制條件:鋁水溫度在770℃至810℃之間;
模溫在350℃至370 ℃之間,可以有效改善鑄件品質。為建立Al-Mg系鑄造
鋁合金的高鑄造性、防止鑄造熱裂的鑄造技術。可藉由除氣除渣,並調整
鑄造條件,以控制鋁水的流動、縮孔和熱裂。由以上方式控制分散粒子分
佈、元素偏析以及鑄造組織,以探討這些微組織結構對於表面處理的相關
性。再以三種不同焊條4043、5183與5356進行7005 與514銲接,最後實施
表面處理顏色比對,效果以5356色澤,最符合要求。後續銲接施工,均
以5356焊條為主,進行一系列拉伸試驗及測硬度、觀察金相微組織等試驗
。本實驗共分四批,第一批514在鑄造時未添加任何元素及未作任何均質
化處理;第二批514在鑄造時未添加任何元素,但鑄後進行均質化及銲接
後T53熱處理(110℃8hr,150℃16hr);第三批於514鑄材中添加細晶劑(
Al-5%Ti-1%B),鑄出後再經不同均質化處理:(1) 410℃ 6hr;(2)430℃
6hr;(3)450℃ 6hr;第四批於514鑄(2) 材中,同時添加細晶劑(Al-5%
Ti-1%B)及Zr元素,再經不同(3) 均質化條件處理:(1)450℃ 6hr
;(2)470℃ 6hr;(3)490℃(4) 6hr。以上四批不同514材料,經過拉伸試
驗及量測硬度曲線、(5) 及觀察金相微組織等試驗,並輔以EPMA元素分析
及SEM斷面掃(6) 瞄等分析,實驗結果可從下列六方面,予以分析檢討
:(7) 拉伸試驗結果分析。(8) 拉伸試驗斷面分析。(9) 硬度曲線分析
。(10) EPMA元素分布分析。(11) 金相微組織分析。(12) 銲接後表面處
理分析。從結果得知,第四批抗拉強度及伸長率為最佳,由於晶粒細化,
減少偏析發生,故機械性能大幅上昇。

AbstractThe purpose of the research is
to improve the capability of casting ,welding and coloring
anodized aluminum of two different materials , such as Al-Mg 514
cast alloy aluminum and Al-Zn-Mg 7005 extrusion aluminum. Since
casting a 514 alloy thin rectangular test plate (250㎜×120㎜×4
㎜)for welding was not easy , the author adopted four methods
for casting and did many tests to solve it. Subsequently the
property of 514 alloy was promoted by using various
homogenization treatments and adding grain refiner , degassing
and altering cast conditions , controlling the flow rate of melt
alloy to reduce the phenomenon of shrinkage and hot tearing and
enhance the mechanical properties of 514 alloy . The suitable
cast conditions are recommended:(1)the temperature of melted
aluminum alloy be controlled in the range from 770℃to 810℃(2)
the temperature of mold be controlled in the range from 350℃to
370℃.The influence of adding alloy element and altering
homogenization treating temperature was observed by means of
Optical Microscope(OM), Scanning Electron Microscope(SEM), and
Multiple tensile test(MTS).With altering various homogenization
temperatures and adding alloy Al-Ti-B refiners and zirconium
alloy elements, the results showed that mechanical properties of
514 alloy could be improved effectively . For 514 alloy ,higher
homogenization temperature (450℃~490℃)was better than lower
homogenization temperature (410℃~430℃). In observing
microstructure of 514 alloy , it was interesting to find that
the higher homogenization temperature was , the lower the
eutectic phase in microstructure was , and the refiner in
microstructure region observed was.In the mean time , adding the
Al-Ti-B refiners and Zr adequately ,the tensile strength and
elongation of the specimens will be excellent .The SEM
fractograph inspections of tension failure areas were also
applied to check the fracture morphology , which indicated that
the fracture was of a typical ductile fracture .Choosing a
proper filler , either 4043, 5183, 5356 , or so on , to weld two
different materials was very important . After comparing the
results of various welded specimens , it was found that the 5356
filler worked better than the others in coloring match if
theoperating conditions were in the range from 134 to 156 amp
and from 13 to 14.5v.Finally , to make sulfuring acid anodizing
aluminum have excellent corrosion and wear resistance , it was
oxide coated in the following conditions : (1)the concentration
of sulfuric acid is 15%(165g/l) , (2) the operating
temperature is 17℃, and (3) the operating time is 50 min.

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