臺灣博碩士論文加值系統

摘要 I
Abstract II
目錄 III
表目錄 VI
圖目錄 VII
附錄目錄 IX
第一章、前言 1
第二章、文獻回顧 2
2.1. 碳點 2
2.1.1. 簡介 2
2.1.2. 表面官能基與粒徑對碳點放射螢光的影響 2
2.1.3. 表面鈍化 3
2.1.4. 碳點之毒性 4
2.1.5. 傳統半導體量子點與碳點 5
2.1.6. 碳點的粹滅 6
2.1.7. 碳點的電化學螢光反應 7
2.2. 碳點合成的方法 7
2.2.1. 水熱法 8
2.2.2. 乾熱法 9
2.2.3. 微波 10
2.2.4. 酸氧化 10
2.2.5. 熱注射 11
2.2.6. 油浴 11
2.2.7. 氧化結合加熱 11
2.2.8. 常壓加熱攪拌法 11
2.3. 分離不同螢光性質的碳點 11
2.4. 原料對碳點特性的影響 12
2.4.1. 原料與碳點表面上的官能基 13
2.4.2. 光學性質 14
2.5. 碳點的應用 15
2.5.1. 細胞成像 16
2.5.2. 訊息加密 18
2.5.3. 奈米感測器 18
2.5.4. 奈米複合薄膜 18
2.6. 水產品廢棄物 19
2.6.1. 簡介 19
2.6.2. 蝦殼和蟹殼 19
第三章、實驗材料 21
3.1. 碳點原料 21
3.1.1. 蝦殼 21
3.1.2. 蟹殼 21
3.2. 細胞株 21
3.3. 實驗藥品 21
第四章、實驗架構與方法 24
4.1. 原料的處理 25
4.1.1. 蝦殼粉之製備 25
4.1.2. 三點蟹殼粉之製備 25
4.2. 碳點之合成 25
4.3. 碳點的基本特性 25
4.3.1. 螢光圖譜 25
4.3.2. 測定碳點之粒徑與觀察其形狀 25
4.3.3. 碳點表面官能基測定 25
4.3.4. 瓊脂凝膠電泳 26
4.3.5. 界達電位 26
4.3.6. 於不同溶劑中螢光強度的比較 26
4.3.7. 產率 27
4.3.8. 量子產率 27
4.3.9. 元素分析 28
4.4. 環境因素對碳點螢光強度的影響 28
4.4.1. pH對螢光強度的改變 28
4.4.2. 離子強度對螢光強度的改變 28
4.4.3. 放置時間對螢光強度的改變 29
4.5. 細胞實驗 29
4.5.1. 細胞成像 29
4.5.2. 細胞毒性實驗 29
4.6. 螢光墨水 29
4.7. 不同金屬離子於不同pH值下粹滅蝦蟹殼碳點螢光之能力 30
第五章、結果與討論 31
5.1. 蝦蟹殼碳點製備條件之探討 31
5.1.1. 乾熱溫度對產物外觀及螢光強度之影響 31
5.1.2. 離心條件 31
5.2. 基本特性 32
5.2.1. 螢光性質 32
5.2.2. 粒徑分佈與形狀 33
5.2.3. 碳點表面官能基 33
5.2.4. 瓊脂凝膠電泳 34
5.2.5. 於不同pH值下的界達電位 35
5.2.6. 於不同溶劑的螢光強度 35
5.2.7. 產率 35
5.2.8. 量子產率 36
5.2.9. 元素分析 36
5.3. 環境因素對碳點螢光強度的影響 36
5.3.1. 於不同pH值下的螢光強度 36
5.3.2. 離子強度穩定性 37
5.3.3. 時間穩定性 37
5.4. 細胞成像 37
5.5. 螢光墨水與訊息加密 38
5.6. 金屬離子粹滅碳點能力 38
5.7. 與幾丁聚醣碳點之綜合比較 46
第六章、結論 48
第七章、參考文獻 49
第八章、表 54
第九章、圖 64
第十章、附錄 124

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