臺灣博碩士論文加值系統

本研究以靜電紡絲技術製備核-殼奈米複合纖維膜，此纖維膜是藉由靜電紡絲奈米黏土/聚乙烯醇以及奈米黏土/奈米銀/聚乙烯醇而成。其中藉由開發出之奈米黏土薄片，以其無機物耐燃之特性，進一步應用於纖維膜上，形成一耐燃靜電紡絲核-殼奈米黏土/聚乙烯醇纖維膜；接著延續奈米黏土的應用，利用脫層黏土作為銀粒子的分散劑，並加入有機分散劑，達成分散之目的，接著以靜電紡絲技術製備一靜電紡絲核-殼 奈米黏土/奈米銀/聚乙烯醇纖維膜，並運用表面奈米金屬粒子特性應用於表面增強拉曼效應(SERS)。

In this study, we reported a facile synthesis of a flexible and free-standing substrate for fireflaming and surface-enhanced Raman spectroscopy (SERS), which has been successfully prepared by electrospinning.The nanomat hybrids were prepared via coaxial electrospinning process which assembling by NSP outside PVA and AgNPs/NSP/PVA outside PVA that surfacing to fabricate the core-shell structures.

摘要.....................................................................................................................................................I
Abstract.............................................................................................................................................Ⅲ
目錄....................................................................................................................................................Ⅴ
一、 緒論及文獻回顧............................................................................................................................1
1.1奈米材料介紹...................................................................................................................................1
1.2黏土介紹.........................................................................................................................................3
1.3銀奈米粒子......................................................................................................................................7
1.4界面活性劑.....................................................................................................................................11
1.5表面增強拉曼散射(SERS)理論..........................................................................................................13
1.6靜電紡絲........................................................................................................................................18
二、實驗材料與方法
2.1實驗材料........................................................................................................................................24
2.2實驗儀器........................................................................................................................................36
2.3 黏土製備.......................................................................................................................................27
2.4界面活性劑：聚異丁烯-醯亞胺 ( PIB-imide-PIB )製備........................................................................27
2.5合成 AgNPs/Clay/Dispersant Nanohybrids....................................................................................27
2.6靜電紡絲溶液配置..........................................................................................................................28
2.7 靜電紡絲製備奈米纖維...................................................................................................................28
2.8製備表面增強拉曼散射(SERS)基板...................................................................................................29
2.9鑑定及儀器....................................................................................................................................29
三、結果與討論
3.1靜電紡絲核-殼 奈米黏土/聚乙烯醇纖維膜於阻燃................................................................................30

3.2靜電紡絲核-殼 奈米黏土/奈米銀/聚乙烯醇纖維膜於表面增強拉曼基板..................................................38
四、結論............................................................................................................................................60
五、參考資料......................................................................................................................................61

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