臺灣博碩士論文加值系統

本研究使用苯乙烯(Styrene)單體、γ-甲基丙烯酰氧基丙基三甲氧基矽烷(MPS)單體，經由自由基聚合反應(Free-Radical Polymerization)合成出具矽氧烷基之寡分子共聚物，再利用共聚物官能基自身還原反應，製備出穩定分散之奈米鈀貴金屬粒子，形成高分子/奈米金屬複合材料，稱為[poly(St-co-MPS)/Pd]觸媒墨水。由於矽氧烷化合物具有自身縮合以及與羥基反應鍵結之能力，可藉此增加墨水於基材之附著力，並利用鈀金屬觸媒之催化能力，藉以無電電鍍方式，在基材上製備出高連續性之導電金屬鍍層。合成之寡聚物可藉由霍氏紅外線光譜儀(FT-IR)、故態核磁共振儀(13C-NMR、29Si-NMR)分析檢定分子結構分析與鍵結官能基改變的狀況，GPC測量分子量大小，並利用穿透式電子顯微鏡(TEM)，觀察共聚寡分子還原金屬後的型態與微分散狀況，再以奈米粒子穩定性分析儀(LUM)觀察其穩定性。
將觸媒墨水塗佈於玻璃基材上進行無電鍍金屬化，藉由不同烘烤之溫度觀察矽氧烷與玻璃基材鍵結程度，並以光電子能譜儀(XPS)鑑定分析，並浸泡不同pH值水溶液進行交聯反應，藉此提升墨水與基材之附著力，最後可於基材上製備出鍍層厚度高達8.51 μm，經由百格測試可達5 B之等級。
應用部分利用最佳參數之觸媒墨水與新穎之噴印技術作結合，直接將觸媒墨水噴印在玻璃機殼基材上，來製備手機WWAN天線，再透過觸媒活化後，即以無電電鍍方式，成形金屬圖案於玻璃基材上，製備應用金屬元件，利用天線規範訊號之反射損失(Return Loss,RL)來測量訊號，結果發現在特殊頻率1.0-2.0 GHz之間，反射損失在低於-10 dB之頻帶出現，表示該天線得以運作。

In this study, the preparation of St-co-MPS copolymer with both styrene(St) monomer and γ-methacryloxypropyltrimethoxysilane (γ-MPS) monomer by free radical polymerization. Poly(St-co-MPS)/Pd was prepared via self-reduction of palladium ions by St-co-MPS oligomer without using any reducing agent or surfactant. It was shown that Pd was reduced by the chain-end sulfate groups of styrene when copolymer reacted with the metallic ions. These St-co-MPS copolymer was characterized by 13C-NMR, 29Si-NMR and FTIR to confirm polymer composition and quantity sulfonation, and those self-assembly polymer-metal nanocomposites were characterized by electron microscopy (TEM), observe the stability of LU Misizer(LUM).
The Poly(St-co-MPS)/Pd used as ink for catalytic pattern of glasses, which allows to from the metallic pattern by electroless deposition. The cross-linking extend of Poly(St-co-MPS)/Pd ink and glasses dipping with different pH condition was characterized by X-ray photoelectron spectroscope(XPS) to enhance the adhesion of the Poly(St-co-MPS)/Pd ink and glass substrate. The pattern thickness of Ni layer about 8.51 μm.
Finally, we used Inkjet printing metallization process has been used in the fabricated of mobile antenna on special glass case, The WWAN five band antenna was made on the new glass case substrate by the printing of the catalyst activation and electroless plating forming the metal pattern. It will simplify the institutions of the antenna, and resolve the configuration problems of the limited space in the mobile phone's.

誌謝 ii
摘要 iii
Abstract iv
目錄 v
表目錄 vii
圖目錄 viii
1. 緒論 1
1.1前言 1
1.2研究動機 3
1.3研究目的 3
2. 文獻回顧 5
2.1矽氧烷化合物 5
2.2高分子還原奈米金屬粒子 11
2.3印刷金屬化墨水 18
2.4無電電鍍原理 20
3. 實驗 28
3.1實驗流程及參數 28
3.1.1苯乙烯-矽氧烷共聚寡分子之合成 28
3.1.2苯乙烯-矽氧烷共聚寡分子還原貴金屬奈米粒子 30
3.1.3聚矽氧烷觸墨水分析與鍵定 31
3.1.4聚矽氧烷觸媒墨水無電電鍍金屬化實驗 33
3.1.5聚矽氧烷觸媒墨水製備天線 34
3.2 實驗藥品與設備 35
3.2.1 實驗藥品 35
3.2.2 實驗設備 36
3.2.3 檢測方式 37
4. 結果與討論 41
4.1 Poly(St-co-MPS)寡分子之合成與還原貴金屬奈米粒子 41
4.1.1 Poly(St-co-MPS)寡分子之製備與鑑定 41
4.1.2 poly(St-co-MPS)寡分子還原貴金屬奈米粒子之探討 51
4.2金屬化製程參數對鍍層附著度之影響 57
4.2.1烘烤溫度影響基材與高分子鍵結程度之影響 57
4.2.2環境pH值對高分子交聯反應之影響 64
4.3墨水應用於金屬天線之研究 76
5. 結論 82
參考文獻 83
自傳 91

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