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研究生:簡宏宮
論文名稱:纖維素系活性碳纖維之物在連續製程中活化生產速率對其性質影響之研究
論文名稱(外文):Effects of the Production Rate on Properties o Cellulose-based Activated Carbon Cloths by Continuous Process
指導教授:王吉祥王吉祥引用關係
學位類別:碩士
校院名稱:國立臺灣科技大學
系所名稱:纖維及高分子工程技術研究所
學門:工程學門
學類:紡織工程學類
論文種類:學術論文
論文出版年:1995
畢業學年度:83
語文別:中文
論文頁數:148
中文關鍵詞:硫酸銨磷酸氫二銨
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  本文係以Polynosic、Modal及Regular Rayon等再生纖維素織纖梭織物為原料,經硫酸銨和磷酸氫二銨(混合比85/15,濃度40wt%)複合耐燃藥劑之前處理,改進既有設備,自行設計以連續式之半開放高溫活化設備,採用CO2為活化氣體,進行活性碳纖維織物之研製,製程中以活化生產速率為彎數,除探討成品之物性外,並尋求最佳之製程條件。
  結果顯示,隨著活化生產速率的減緩,所得之製品其吸附性能有明顯地提高,但其抗拉強度卻隨之降低,且本系統之最佳活化生產速率指標為 4.75,以此條件可製得BET比表面積為1700m2/g、抗拉強度為4.2 kg/25.4mm之高性能活性碳織維織物。關於吸附性能測試方面,隨著比表面積的增加,液相及氣相的吸附效果,亦相繼地提高。此外,在活性碳纖維織物之微細結構探討方面,由TEM觀察分析,證實其微石墨結晶的存在;且由SEM之微觀結構分析,得知「孔洞」及是由其組成之微粒,以不同燒結程度的結合,而造就孔洞的生成,為一三次元綱狀脈絡的孔洞結構。
  This study is to seek the optimat conditions for th production of the Activated Carbon Cloth (ACC), whose production rate of the activated process is used as variables. The production process is to use the regenerated cellulose fiber fabric, such as Plynosic, Modal and Regular Rayon, as the rawmaterials and having passed the mixrure reagent process of the Ammonium Sulfate ((NH4)2SO4) and Ammonium Phosphate Dibasic ((NH4)2HPO4) (mixture ratio:85/15, concentration:40wt.%). The process is completed within the self-designed continuous semi-open high temoperature activation equipment and used carbon-dioxide (CO2) as the activatorgas.
  The results revealed that by decreasing the production rate of the activated process, the adsorption properties of the product were significantly increased. However, the tensile strength was decreased. In addition, the optimal production rate index of the activated process shall be 4.75. Under such condition, the high performance Activated Carbon Cloth of 1700m2/g BET specific surface area, 4.2kg/25.4mm tensile strength was produced. As for as the adsorption test, the liquid phase and gas phase adsorption properties tended to be better in the increase of the BET specific surface area. Nevertheless. by the observation analysis of the Transmission Electron Microscope (TEM) and the micro-structure investigation of the Activated carbon Cloth. we can confirmaed the existence of its micrographitic crystallites. From the micro-structure analysis of the Scanning Electron Microscope (SEM), "Pore" was caused due to the different compound degree of the micro-particles, with three dimensional netwrk structure.
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