臺灣博碩士論文加值系統

本論文運用鋁二次陽極處理技術，製備出高垂直陣列式的奈米孔結構，再透過真空熱壓鑄法將鋅與鉛等金屬填入陽極氧化鋁膜板中，並以不同的後處理方式製備出氧化鋅與硫化鉛奈米線。
實驗中以高純度鋁做為基材，運用二次陽極處理技術製備出陣列式奈米孔結構做為模板，透過改變製程中的溶液、電壓、反應時間等參數，製備出不同孔徑大小的模板，並以後處理改善孔洞結構的均勻性以及近一步調整孔洞尺寸。之後利用真空熱壓鑄法將鋅、鉛等金屬填入模板中，在透過熱處理等後製程，製備出氧化鋅以及硫化鉛奈米線。
分析採用SEM觀察氧化鋁膜板的結構形貌以及金屬奈米線的填充情形，以EDS分析成分比列與元素的分布情形，透過XRD分析元素成分及結晶結構。
驗結果顯示，鉛、鋅等金屬均有填入模板中，分別透過硫化與氧化處理後，鋅金屬奈米線的部分，以成分比例的分析結果來看，有氧化鋅的奈米線結構，而鉛金屬奈米線部分，透過不同參數的硫化處理後，成功將鉛奈米線硫化為硫化鉛奈米線，並加以觀察出在不同溫度下硫元素在模板內部的硫化情形。

In this study, the Anodic Aluminium Oxide(AAO) template, having ordered the array nanoporous structure was fabricated by two-step anodization. Then make Zn-nanowires and Pb-nanowires by vacuum, high temperature, injection technique. Fabricate ZnO-nanowires and PbS-nanowires with after-treatment .And analyze the result about manufactures of ZnO-nanowires and PbS-nanowires.
The experiment is about use high-purity aluminum to make array nanoporous structure template by two-step anodization .Make some templates with many different holes size by adjust the parameter of solution, voltage and anodizing time ,and in order holes structure size to balance. Then, the Zn and Pb was melted in the vacuum furnace and injected into an template and use heat treatment as well as other after-treatments to fabricate ZnO-nanowires and PbS-nanowires.
With scanning electron microscopy(SEM),we can find the structure of AAO template and the padding of metal nanowires. Then analyze the proportion of chemical composition and the branch of elements by energy dispersive X-ray spectrum (EDS).At last we can analyze the proportion of elements and the structure of crystals by x-ray diffraction(XRD).
Final results of the experiment, both of Zn and Pb injected into an template. Analyze the proportion of chemical composition about Zn-nanowires, by vulcanization and oxidation. We can find the structure of nanowires including ZnO. The part of Pb-nanowires, we turn it to PbS-nanowires successfully by vulcanize treatment with many parameters. And then, we can find the variation of Pb turn into PbS in template at different of temperature.

摘要 ---------------------------------------------I
ABSTRACT ----------------------------------------II
誌謝 --------------------------------------------IV
目錄 ---------------------------------------------V
表目錄 -----------------------------------------VII
圖目錄 ----------------------------------------VIII
第一章 緒論 --------------------------------------1
1.1 前言 -----------------------------------------1
1.2 研究動機與目的 --------------------------------4
1.3研究架構 ---------------------------------------5
第二章 文獻回顧 -----------------------------------6
2.1陽極處理氧化鋁膜板之應用 ------------------------6
2.2陽極氧化鋁膜板之生成機制 ------------------------7
2.2.1陽極氧化鋁膜板反應過程 ------------------------8
2.2.2陽極氧化鋁膜板製程控制變因 --------------------11
2.3氧化鋁模板備製奈米線 ----------------------------13
2.4電化學拋光 -------------------------------------14
2.5氧化鋅的基本性質及製備方法 -----------------------15
2.6硫化鉛的基本性質及製備方法 -----------------------16
第三章 研究方法與設備 ------------------------------17
3.1陽極氧化鋁膜板製程 ------------------------------18
3.2金屬真空熔煉 ------------------------------------21
3.3金屬真空高溫壓鑄 --------------------------------22
3.4鋅、鉛金屬奈米線的氧化與硫化 ---------------------24
3.5 實驗設備 --------------------------------------25
3.5.1研究設備 -------------------------------------25
3.5.2分析設備 -------------------------------------31
第四章 結果與討論 ----------------------------------33
4.1陽極氧化鋁模製備結果 ----------------------------33
4.2鋅金屬奈米線壓鑄結果 ----------------------------36
4.3鉛金屬奈米線壓鑄結果分析 ------------------------37
4.4鉛金屬奈米線硫化結果分析 ------------------------38
第五章 結論----------------------------------------63
參考文獻 ------------------------------------------64

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