臺灣博碩士論文加值系統

對化工程序的設計與開發，及流體相行為的理解，相平衡是一個不可缺少的單元。
本文測定Isopropanol＋1-Chlorobutane＋Acetonitrile的二成份系統及三成份系統的汽液平衡，系統壓力設定於一大氣壓。所有二成份系統Isopropanol＋1-Chlorobutane、IsopropanOl＋Acetonitrile與1-Chlorobutane＋Acetonitrle的實驗數據，皆符合Herington的一致性測試。
在實驗數據的處理中，對二成份系統及三成份系統的數據迴歸，均使用van Laar、Margules、Wilson、NRTL以及UNIQUAC等方程式。五種模式對二成份系統及三成份系統的迴歸效果類似，然而結果皆以Wilson方程式之效果最好。而以所組成的二成份系統來預測此三成份系統，則以Wilson與NRTL效果比較好。

Vapor-Liquid Equilibrium is a necessary element for desinging and developing chemical processes as well as enhancing our understanding of fluid-phase behaviors.
In this work, VLE data of binary and ternary systems of Isopropanol + 1-Chlorobutane + Acetonitrile have been measured under constant pressure of 101.3 kPa. Experimental data of the binary systems of Isopropanol + 1-Chlorobutane, Isopropanol + Acetonitrile and 1- Chlorobutane + Acetonitrile were thermodynamic consistent via Herington analysis.
In the treatment of experimental data, both binary systems and the ternary system were correlated by van Laar, Margules, Wilson, NRTL and UNIQUAC equations. The performance of the five models used was almost the same accuracy in the correlation of each binary and the ternary systems, while the performance of the Wilson equation was the best. In the prediction of the ternary system from their constituent binaries, the Wilson and NRTL equations gave the better results for this work.