臺灣博碩士論文加值系統

利用鹼催化使4-甲基喹啉 碘鹽和7-二甲基胺-4-羥基-3-醯基香豆素進行環化反應，並有效率的合成出四種香豆素與啡啶融合的雜環化合物。所有製備的化合物皆對光靈敏，且在紫外光照射下會改變顏色。此外，經測試發現其中有化合物2、12和27，都具有負向的熱致變色性質；當溫度上升時顏色變黃，反之則顏色變橘紅，且具有新的變色反應機構。

Four coumarin and phenanthridine-fused heterocycles 1, 2, 12, and 27 were efficiently synthesized using base-catalyzed annulation of 4-methylquinolinium iodide and coumarin as a key step. Compound 1 is sensitive to light and changes color upon UV irradiation, compounds 12 and 27 are sensitive to heat and possesses thermochromic properties, and compound 2 is sensitive to both light and heat. A novel heat and light-sensitive molecular skeleton is introduced.

中文摘要…………………………………………I
英文摘要……………………………….………II
目錄……………………………………………III
圖譜目錄…………………………………………V
圖表目錄………………………………………VII

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