臺灣博碩士論文加值系統

過渡金屬化合物(CoCl2、Zn(NO3)2、Pb(NO3)2、Ni(OAc)2、Ni(NO3)2)與口比啶羧酸(3-pcH和4-pcH)或口比啶雙羧酸(2,3-pdcH2、2,4-pdcH2、2,5-pdcH2、2,6-pdcH2、3,4-pdcH2和3,5-pdcH2)，在110~190℃，10~72小時狀況下，經水熱合成，得出
零維：NCKU-1,[Co(4-pc)2(H2O)4]、
NCKU-13,[Co(2,6-pdc)2•Co(H2O)6•2H2O]
一維：NCKU-9,[Ni(2,3-pdc)(H2O)3]n、
二維：NCKU-8,[Pb(2,3-pdc)]n、
NCKU-16,[Co(3,5-pdc)(H2O)2]n、
NCKU-18,
[Cd(2,3-pdc)(H2O)(μ-2,3-pdc)2Ni(2,3-pdc)(H2O)]n
三維：NCKU-6,[Cd2(2,3-pdc)2(H2O)(μ-2,3-pdc)2]n、
NCKU-7,[Zn(2,3-pdc)(H2O)]n、
NCKU-15,{[Co(3,4-pdc)(H2O)2]．H2O}n；其中經氫鍵得出，NCKU-1與13(零維經分子間氫鍵形成三維)；二維及三維的結構均有孔徑的形成；所有的化合物，均用元素分析，固態IR及UV-vis光譜鑑定，也得單晶X光繞射決定有關的構造；其中3-pcH為3-口比啶羧酸，4-pcH為4-口比啶羧酸，2,3-pdcH2為2,3-口比啶雙羧酸，2,4-pdcH2為2,4-口比啶雙羧酸，2,5-pdcH2為2,5-口比啶雙羧酸，2,6-pdcH2為2,6-口比啶雙羧酸，3,4-pdcH2為3,4-口比啶雙羧酸，3,5-pdcH2為3,5-口比啶雙羧酸。

Transition-Metal compounds of CoCl2 , Zn(NO3)2, Pb(NO3)2, Ni(OAc)2, and Ni(NO3)2 reacted hydrothermally with pyridyl mono- or dicarboxylic acid of 3-pcH, 4-pcH, 2,3-pdcH2, 2,4-pdcH2, 2,5-pdcH2, 2,6-pdcH2, 3,4-pdcH2, and 3,5-pdcH2 in a autogenous stainless steel bomb under 110-190℃ to produce 0-, 1-, 2-, and 3-dimensional (0D, 1D, 2D, 3D) structures within 10-72 hours (3-pcH=3-pyridylcarboxylic acid,
4-pcH=4-pyridylcarboxylic acid,
2,3-pdcH2=pyridine-2,3-dicarboxylic acid,
2,4-pdcH2=pyridine-2,4-dicarboxylic acid,
2,5-pdcH2=pyridine-2,5-dicarboxylic acid,
2,6-pdcH2=pyridine-2,6-dicarboxylic acid,
3,4-pdcH2=pyridine-3,4-dicarboxylic acid,
3,5-pdcH2=pyridine-3,5-dicarboxylic acid)
0D：NCKU-1,[Co(4-pc)2(H2O)4]、
NCKU-13,[Co(2,6-pdc)2•2Co(H2O)6•2H2O]
1D：NCKU-9,[Ni(2,3-pdc)(H2O)3]n、
2D：NCKU-8,[Pb(2,3-pdc)]n、
NCKU-16,[Co(3,5-pdc)(H2O)2]n、
NCKU-18,
[Cd(2,3-pdc)(H2O)(μ-2,3-pdc)2Ni(2,3-pdc)(H2O)]n
3D：NCKU-6,[Cd2(2,3-pdc)2(H2O)(μ-2,3-pdc)2]n、
NCKU-7,[Zn(2,3-pdc)(H2O)]n、
NCKU-15,{[Co(3,4-pdc)(H2O)2]．H2O}n
With consideration of hydrogen bonding interactions, NCKU-1and -13 can be converted into 3D structures. All the 2D and 3D structures contain cavities which were also measured. The new structures have been characterized by elemental analysis, solid-state IR and UV-vis spectral measurement, and single-crystal structures via X-ray diffraction data.

中文摘要…………………………………………Ⅰ
Abstract…………………………………………Ⅲ
圖目錄……………………………………………Ⅶ
表目錄……………………………………………Ⅷ
第一章緒論……………………………………..1
第二章實驗………………………………………13
2-1 藥品………………………………………13
2-2 儀器/軟體……………………………….14
2-3 實驗前處理………………………………14
2-4 高分子化合物合成………………………15
第三章實驗結果………………………………..22
第四章討論與結論………………………………38
參考文獻…………………………………………48
附錄一：各結構鍵長附表..................50
附錄二：相關實驗結果…………………….….58
附錄三：晶體常數表……………………………94
附錄四：UV-vis光譜圖……………………….114
附錄五：IR光譜圖…………………………….124
附錄六：已發表論文………………………….144

1.Stuart L. James, Chem. Soc. Rev., 2003, 32,276
2.Susumu Kitagawa, Ryo Kitaura , Angew. Chem.Int.Ed., 2004,43,2334
3.Qiutian Liu, Eur. J. Inorg. Chem., 2004,1454
4.Jack Y. Lu, Inorg. Chem. Comm., 2001, 4,716
5.Ji-Qing Xu, J. Mol. Struct. , 2002, 641,23
6.Ji-Qing Xu , Inorg. Chem. Comm., 2002, 5,572
7.Lu Y. Jack, Chem. Comm., 2001,821
8.Ju-Hsiou Liao, Inorg. Chem. Comm., 2004, 7,402
9.Jun Peng , Inorg. Chem. Comm., 2003, 6,1429
10.Puddephatt J. Richard, Inorg. Chem., 2002,41,5174
11.Rene Faure, Polyhedron, 1996,15,2909
12.Nobuo Okabe, Acta Cryst. , 1996,C52, 1410
13.Nobuo Okabe, Acta Cryst. , 1996,C52, 1610
14.Storr Alan, Thompson C. Robert , Polyhedron , 2003,22,3025
15.Goher A. S. Mohamed, Polyhedron, 1993,12,1871
16.Soon W. Lee Inorg. Chim. Acta , 2001,324,293
17.Plater M. John , J. Chem. Research (S),1998,754
18.Parimal K. Bharadwaj , Inorg. Chem., 2004,43,2293
19.Parimal K. Bharadwaj , Inorg. Chem., 2003,42,8250
20.Enbo Wang, Inorg. Chem. , 2004,43,1850
21.Soon W. Lee, Inorg. Chem. Comm., 2002, 5,978
22.Soon W. Lee, Inorg. Chem. Comm., 2001, 4,297
23.Peng Cheng, J. Am. Chem. Soc., 2004,126,3012
24.Maochun Hong , Angew. Chem. Int. Ed., 2000,39,3304
25.O’Keeffe, M., Yaghi O. M., Nature , 1999,402,276
26.Yaghi O. M., Nature, 2003,423,705
27.Yaghi O. M., Science, 2001,291,1021
28.Yaghi O. M., Science, 2002,295,469
29.Yaghi O. M., Science, 2003,300,1127
30.Song Gao , Angew. Chem. Int. Ed., 2000,39,3644
31.Bibudhendra Sarkar , Inorg. Chem. ,2004,43,3338
32.Stuart R. Batten , Acta Cryst. , 2001,E57, m7
33.Rudy L. Luck , Acta Cryst. , 2002,C58, m152