臺灣博碩士論文加值系統

本研究以己二酸﹝adipic acid﹞與乙二胺﹝ethylenediamine﹞，二乙基三胺﹝diethylenetriamine﹞，三乙基四胺﹝triethylenetetraamine﹞，四乙基五胺﹝tetraethylenepentamine﹞，為原料合成含有不同合體數乙烯胺之Polyamide高分子聚合物，而高分子聚合物構造分別經由紅外線光譜儀，元素分析，酸價測試，粘度測試加以確認其基本性質。
將所合成之Polyamide合成物分別應用醞醌型分散染料與偶氮型酸性染料，探討其與染料間之相互作用，結果發現醞醌型分散染料有藍移的現象而偶氮型酸性染料有紅移的現象。另外亦將其應用於特多龍纖維與耐隆纖維探討其與纖維間之吸附行為，結果發現Polyamide高分子聚合物對特多龍纖維與耐龍纖維之吸附皆為Freundlich types等溫吸著曲線。
所合成之Polyamide高分子聚合物，同時對聚酯超細纖維染色加工布進行固色加工，加工方法有浸漬法與壓吸法，結果發現經固色加工之聚酯超細纖維染色加工布其K/S值及耐水洗、耐磨擦、耐昇華堅牢度多有上升的趨勢，其中以1H1D藥劑為最佳。

The principal aim of this study was used adipic acid、 ethyelenediamine、diethyelenetriamine、triethyelenetetraamine
and tetraethylenepentamine to synthsis different composition ethyleneamine Polyamides. The structure and quality of these polymer was confirmed by Infra-Red、Elemental Analysis 、
Acid Value and Viscosity.
These Polyamide were applied to theanthraquinone disperse
dyes and the azo acid dyes；therefore the anthraquinone disperse
dyes interacted with Polyamides were shown to blue shift and the
azo acid dyes indicated red shift .Besides including the effect on
polyster fiber and nylon fiber by adsorption with Polyamides，the
resules were shown to all of Freundlich types.
There were two method of immersed and padded to fix with
Polyamides fix agent after PET microfiber dye.It were found that
fixtion wuld increase of K/S value、durability finish、durability
coeffcient、durability sublimation of dyed PET microfiber fabric.

目 錄
中文摘要
英文摘要
目錄
一、前言
1-1動機
1-2過去研究
1-2-1 纖維染色性改善相關研究
1-2-1-1 特多龍超細纖維染色性改善相關研究
1-2-1-2 其他纖維牢度改善相關研究
1-2-2 Polyamide之合成與應用
1-3本研究目的
二、實驗方法
2-1實驗材料
2-2實驗設備與儀器
2-3 Polyamide合成物之合成與鑑定
2-3-1合成
2-3-2酸價鑑定
2-3-3紅外線吸收光譜分析
2-3-4黏度測試
2-4 Polyamide合成物與染料相互作用試驗
2-5 Polyamide合成物與纖維相互作用試驗
2-6特多龍纖維染色性改善試驗
2-7染色及固色加工布之物性測試
2-7-1加工布耐昇華堅牢度測試
2-7-2加工布耐水洗堅牢度測試
2-7-3加工布耐摩擦堅牢度測試
三、結果與討論
3-1 Polyamide合成物之合成與鑑定
3-2 Polyamide合成物與染料間之相互作用
3-3 Polyamide合成物與纖維間之相互作用
3-4 Polyamide合成物種類與濃度對特多龍超細纖維染色物K/S值及堅牢度之影響
四、結論
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