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研究生:鄭郁勳
論文名稱:自組裝單層衍生全程濕式銅金屬化在直通矽穿孔之應用
論文名稱(外文):Feasibility of Using Self-assembled Monolayers to Derive All-wet Copper Metallization for Through-Silicon Vias (TSVs)
指導教授:陳錦山
口試委員:陳錦山黃敏男李文錦張佑祥
口試日期:2015-07-17
學位類別:碩士
校院名稱:逢甲大學
系所名稱:材料科學與工程學系
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:2015
畢業學年度:103
語文別:中文
論文頁數:58
中文關鍵詞:直通矽穿孔(TSV)TSV填充三維積體電路無電鍍金屬阻障層無電鍍晶種層無電鍍銅導線自組裝單層
相關次數:
  • 被引用被引用:3
  • 點閱點閱:297
  • 評分評分:
  • 下載下載:23
  • 收藏至我的研究室書目清單書目收藏:0
專利申請中,暫不公開
專利申請中,暫不公開
誌謝 I
中文摘要 II
Abstract III
總目錄 IV
圖目錄 VI
表目錄 IX
第一章 緒論 1
第二章 研究背景與動機及目的 4
2.1直通矽穿孔(TSV)之銅金屬化填充 4
2.2銅金屬化薄膜之製程與材料發展 8
2.2.1金屬擴散阻障層 8
2.2.2無電鍍暨銅薄膜導線 10
2.3晶種技術之發展 11
2.4自組裝單層之晶種固定化技術發展 12
2.5研究動機及目的 16
第三章 實驗步驟與分析原理 19
3.1試片製作實驗整體流程 19
3.2 OTS-SAM薄膜之實驗流程(參閱圖3.2及表3.3) 20
3.3 APTMS-SAM薄膜之實驗流程(參閱圖3.3及表3.3) 21
3.4 個別步驟說明 21
3.4.1 SiO2介電層基材準備 21
3.4.2化學溶液表面改質步驟 21
3.4.3自組裝單層生長及後續官能基化 22
3.4.4晶種吸附化學溶液之處理步驟 22
3.4.5無電鍍鈷合金及銅薄膜沉積步驟 22
3.4.6 TSV金屬化填充 23
3.5試片相關分析 26
第四章 結果與討論 27
4.1自組裝單層生長行為分析 27
4.1.1水接觸角分析 27
4.1.2表面鍵結分析(APTMS-SAM) 30
4.2 APTMS-SAM之晶種吸附機制 35
4.3無電鍍催化晶種與鈷合金薄膜生長分析 39
4.4 Co-P阻障層之退火效應分析 43
4.5無電鍍銅薄膜生長及分析 46
4.6 TSV金屬化填充 47
第五章 結論 49
5.1重點結果 49
5.2未來展望 50
參考文獻 51
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