臺灣博碩士論文加值系統

本研究碳討碳煙微粒的特性、產生率穩定性，及在不同環境下與氣態
污染物間的反應。實驗採用乙炔為燃料，利用燃燒的方式產生碳煙微粒，
微粒經採樣後分析其含碳量及水溶性離子物種含量。 結果顯示所產生
的碳煙微粒以元素碳為主，沒有硫酸鹽離子的存在，但可測到硝酸鹽離子
，微粒產生率並不穩定。在碳煙微粒與二氧化硫之間的反應，當有二氧化
硫存在時，微粒可量測到硫酸鹽離子，顯示二氧化硫會與碳煙發生反應；
比較微粒中硫酸鹽離子與硝酸鹽離子吸附量的結果，顯示在碳煙微粒上硫
氧化物與氮氧化物的吸附，彼此間可能會互相影響。

This work investgated the characterisitics of the generated
soot particles,the stability of the formation rate, and the
products from the reactions of gaseous species. Actylene was
chosen as the fuel burned to generate soot particles. The
carbonaceous and water-soluble contents of the collected samples
were analyzed off-line. The results show that the majior
composition of soot particles is elementalcarbon, no sulfate was
detected but nitrate was in a minor fraction. The formation
rate of the soot particles was not stable. For the reaction
between SO2 and soot particles, sulfate was detected in the
collected samples which implies that SO2 reacted with soot
particles. From the comparison of sulfate and nitrate measured
in the collected samples, it is inferred that a competition
might exist between SO2 and NOx for the reaction with the soot
particles.