臺灣博碩士論文加值系統

　　本實驗採用固體消失法量測多種混合物的固液相平衡數據，第一部份的研究主要探討的為酚、碳酸二甲酯、碳酸二苯酯所組成之雙成分系統和三成份系統，而第二部份的研究對象為間甲基苯甲酸與鄰甲基苯甲酸以及與兩種分離助劑─1,4丁二醇與特丁醇的雙成分系統。
　　第一部分的研究與先前本研究室的量測結果相當一致，而第二部份使用NRTL模式關聯無合熔點之雙成分系統的固液相平衡數據；至於含有合熔點之雙成分系統，則採用理想化學模式(ideal-chemical model，ICM)來關聯。結果顯示，NRTL模式可合理關聯固液平衡數據；而針對間甲基苯甲酸/特丁醇以及鄰甲基苯甲酸/特丁醇二組含有一個合熔點的系統，以ICM模式關聯，結果顯示在共熔點附近均關聯良好，但在間甲基苯甲酸以及鄰甲基苯甲酸結晶區的計算結果明顯偏離實驗點。

　Solid-liquid equilibrium (SLE) data were measured with solid-disappearance method for various mixtures.The first part of this study investigated the binary and the ternary systems containing dimethyl carbonate, diphenyl　carbonate, and phenol. The second part studied the binary mixture containing o-toluic acid, m-toluic acid, 1,4-butanediol and tert-butanol.
　The experimental results of the first part were consistent with our pervious study. The NRTL model was used to correlate the SLE data of the binary system that is not form congruent compound. And the ideal chemical model(ICM) were used to correlated the SLE data for complex formation system. The result showed that the NRTL modle was capable of representing the SLE behavior of the binary system. For the o-toluic acid + tert-butanol system and the m-toluic acid + tert-butanol system, we used ICM to correlate. The result showed that the ICM can be used to predict the two binary systems.

中文摘要 Ⅰ
英文摘要 Ⅱ
致謝 III
目錄 Ⅴ
圖表索引 Ⅶ

第一章 緒論　1
1-1 前言　1
1-2 基本固液平衡相圖及分析　3
1-2-1 含單一共熔點之相圖　4
1-2-2 含二共熔點及一合熔點之相圖　5
1-2-3 無合熔物之三成分系統固液相圖　6
1-3 本文各章重點　7

第二章 固液相平衡量測　11
2-1 儀器設備　11
2-2 實驗設備配置說明　12
2-3 熔點量測步驟　13
2-3-1 雙成份樣品配製　14
2-3-2 三成份樣品配製　14
2-3-3 長晶技術之探討　15
2-3-4 熔點之量測　16

第三章 含碳酸二甲酯、碳酸二苯酯、酚混合物的固液相平衡研究　18
3-1 前言　18
3-2 藥品　18
3-3 雙成分系統的量測結果　19
3-4 三成分系統的量測結果　20

第四章 沸點相近之共熔物與分離助劑之固液相平衡研究　36

4-1 前言　36
4-2 藥品　36
4-3 雙成分系統之固液相平衡量測結果　37
4-4 固液相平衡理論計算　39
4-4-1 固液相平衡法則　40
4-4-2 不含合熔點之雙成分系統固液相平衡計算　42
4-4-3 含一個合熔點之雙成分系統固液相平衡計算　44
　
第五章 結論與建議　72
5-1 結論　72
5-2 建議　74

參考文獻　75
符號說明　81
作者簡介　83

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