臺灣博碩士論文加值系統

本研究以薄膜太陽電池的彩色電極與矽晶太陽電池的彩色封裝為兩大研究主軸，設計矽晶太陽電池封裝用之高透光彩色玻璃；薄膜太陽電池用之彩色透明電極。
彩色薄膜太陽電池中反射式彩色電極結合透明介電膜與透明導電膜設計並製作出藍色、綠色、紅色三種彩色電極，其與鈣鈦礦太陽電池結合的最佳功率轉換效率為6.77 %；穿透式彩色電極以Ag-ITO-Ag共振腔結構創造色彩純度佳且色域寬廣，與有機太陽電池結合之最佳功率轉換效率為8.18 %。對於薄膜太陽電池封裝端，反射式彩色封裝以高透光基板與高透光彩色基板結合鈣鈦礦太陽電池提升整體效率並帶有色調；穿透式彩色封裝以高透光基板與共振腔結合提升半穿透有機太陽電池效率且擁有高純度穿透顏色。
矽晶太陽電池的彩色封裝，利用自行開發的彩色封裝模擬系統模擬比對其封裝前後之光性差異，對於400-1100nm波長之高透光彩色玻璃進行三種設計。設計A為封裝後效率大於一般玻璃封裝，平均穿透率為93.09~94.11 %且帶有彩色色調；設計B為封裝後效率為一般玻璃封裝±0.6 %，平均穿透率為90.06~92.85 %，顏色較鮮豔且穿透率與玻璃相近；設計C為封裝後效率小於一般玻璃封裝，其設計之平均穿透率為91.30~88.00 %，顏色鮮豔之彩色封裝。

In this study, the colored cathode of the thin-film solar cell and the colored package of the silicon solar cell were used as the two mains of the study, and the high transparent colored glass was designed for silicon solar cell package; the color transparent electrodes was designed for thin film solar cells.
Reflective colored electrode combined with transparent dielectric film and transparent conductive film which design and manufacture of blue, green, red three color electrodes, and its combination of perovskite solar cells with the best power conversion efficiency of 6.77%; transmission color electrode of Ag-ITO-Ag microcavity structure to create a high color purity and wide gamut, and its combination of organic solar cells, the best power conversion efficiency of 8.18%. For thin-film solar cell packaging, the reflective colored package combines a high-transmittance substrate with a high-transmittance color substrate combined with a perovskite solar cell to enhance the overall efficiency and color tone; the transmission colored package is combined with a microcavity enhance the overall semi-transparent organic photovoltaics efficiency and have high purity transmission color.
For Silicon solar cell color packaging, the use of self-developed color packaging simulation system simulation compared to its packaging before and after the difference of optical properties. And we designs the high-transparent colored glass for the wavelength of 400-1100 nm. Design A for the packaging efficiency is greater than glass package, the average transmission of 93.09 ~ 94.11% and with color tones; Design B for the packaging efficiency is equal to glass package of efficiency ± 0.6%, the average transmission of 90.06 ~ 92.85%, the color is more vivid, transmission similar to the glass; The design C for the packaging efficiency is less than glass package, the average transmission of 91.30 ~ 88.00%, bright colors of color packaging.

明志科技大學碩士學位論文指導教授推薦書 i
明志科技大學碩士學位論文口試委員審定書 ii
誌謝 iii
中文摘要 iv
ABSTRACT v
目錄 vii
圖目錄 ix
表目錄 xiii
第一章 緒論 1
1-1 前言 1
1-2 文獻回顧 2
1.3 研究動機與目的 4
第二章 理論介紹 5
2-1 薄膜光學理論 5
2-1-1 多光束干涉法 5
2-1-2 多光束干涉遞歸法 9
2-1-3多光束法 11
2-2色度座標與色彩空間 12
2-3薄膜太陽電池 14
2-4矽晶太陽電池 15
第三章 實驗介紹 16
3-1儀器設備 16
3-2實驗流程 19
3-3光學模擬工具 21
第四章 彩色透明電極 23
4.1 ITO薄膜光電特性 23
4.2穿透式彩色電極Ag-ITO-Ag 39
第五章 彩色薄膜太陽電池 41
5-1反射式PVSK彩色太陽電池 41
5-1-1反射式彩色電極 41
5-1-2高透光彩色基板 49
5.2 OPV彩色太陽電池 56
5-2-1 Ag-ITO-Ag穿透式彩色電極 56
5-2-2穿透式彩色封裝 61
第六章 矽晶太陽電池彩色封裝 67
6-1.封裝光性理論模擬 67
6-2.高透光彩色玻璃 75
6-2-1.設計A PCEA > PCE玻璃封裝 75
6-2-2.設計B PCEB = PCE玻璃封裝 ±0.6% 78
6-2-3.設計C PCEC < PCE玻璃封裝 81
6-3.矽晶太陽電池彩色封裝 84
第七章 結論 90
參考文獻 91

圖目錄
圖2. 5有機太陽能電池發電機制示意圖 14
圖2. 6 P-N接面示意圖 15
圖3. 6 彩色薄膜太陽電池實驗流程圖 19
圖3. 7矽晶太陽電池彩色封裝實驗流程圖 20
圖4. 1不同氧流量的單層ITO基板真空熱處理前光性量測結果 24
圖4. 2不同氧流量的單層ITO基板真空熱處理後光性量測結果 26
圖4. 3不同氧流量的單層ITO基板氬氣熱處理前光性量測結果。 28
圖4. 4不同氧流量的單層ITO基板氬氣熱處理後光性量測結果。 30
圖4. 5真空退火前後之片電阻比較結果 31
圖4. 6氬氣退火前後之片電阻比較結果 31
圖4. 7真空退火與氬氣退火之片電阻比較結果 32
圖4. 8真空退火與氬氣退火之電阻率比較結果 32
圖4. 9 DC100W鍍製ITO薄膜的光性圖譜模擬比對及表面形貌量測結果 33
圖4. 10 DC50W鍍製ITO薄膜的光性圖譜模擬比對及表面形貌量測結果 34
圖4. 11 RF100W鍍製ITO薄膜光性圖譜模擬比對及表面形貌量測結果 35
圖4. 12 DC電源鍍製ITO薄膜的光性圖譜模擬比對結果 36
圖4. 13 DC電源鍍製ITO薄膜的表面形貌量測結果 36
圖4. 14 RF電源鍍製ITO薄膜的光性圖譜模擬比對結果 38
圖4. 15 RF電源鍍製ITO薄膜的表面形貌量測結果 38
圖4. 16 穿透式彩色電極膜層結構示意圖 39
圖4. 17 AG/ITO/AG彩色電極穿透光譜與樣品照片 40
圖4. 18 AG/ITO/AG彩色電極穿透光所對應之色度座標 40
圖5. 5鈣鈦礦反射式太陽電池膜層示意圖 45
圖5. 6鈣鈦礦反射式太陽電池模擬反射圖譜及對應之CIE色度座標 46
圖5. 7鈣鈦礦反射式太陽電池模擬反射圖譜及對應之CIE色度座標 47
圖5. 8鈣鈦礦反射式彩色太陽電池電壓電流密度特性曲線 48
圖5. 9 鈣鈦礦太陽電池膜層結構示意圖 49
圖5. 10 高透光基板結合PVSK太陽電池示意圖 49
圖5. 11 (A)高透光基板(95)與(B)高透光基板(E)貼合鈣鈦礦太陽電池之電壓電流密度特性曲線 50
圖5. 13高透光彩色基板之(A)光性圖譜與(B)膜層結構示意圖 52
圖5. 14高透光彩色基板反射率所對應之(A)色彩空間與(B)色度座標 53
圖5. 15 高透光基板樣品照片與所對應可見光波段之平均穿透率 53
圖5. 16 (A)綠色高透光基板與(B)紫色高透光基板貼合量測之電壓電流密度特性曲線 54
圖5. 18 OPV穿透式彩色太陽電池示意圖 56
圖5. 19 OPV穿透式彩色太陽電池穿透光譜模擬比對 57
圖5. 20穿透式彩色太陽電池(A)穿透光性圖譜，插圖為其樣品照片拍攝背景為明志LOGO、(B)穿透光譜所對應之色度座標 58
圖5. 21穿透式彩色太陽電池實景拍攝圖 58
圖5. 22穿透式彩色太陽電池電壓電流密度特性曲線 59
圖5. 23穿透式彩色封裝之結構示意圖 61
圖5. 24 高透光基板之光性圖譜 62
圖5. 25(A)綠色共振腔與(B)紅色共振腔結構之光性圖譜 62
圖5. 26 元件一之四種不同情況電壓電流密度特性曲線 63
圖5. 28元件二之(A)EQE量測曲線圖 (B)由圖(A)放大觀察縮圖為共振腔光譜 65
圖5. 29四種不同情況之(A)效率統計圖與(B)閉路電流密度統計圖 66
圖6. 1矽晶太陽電池表面形貌之SEM圖 68
圖6. 3矽晶太陽電池封裝之金字塔結構反射率運算示意圖 70
圖6. 4一般封裝反射率量測之封裝樣品照片 70
圖6. 5市售 4BUS-BAR 矽晶太陽電池規格 71
圖6. 6封裝後的銀線反射產生全反射之示意圖 72
圖6. 7封裝後介面全反射條件模擬 72
圖6. 8裸晶片、一般封裝與抗反射封裝之示意圖 73
圖6. 9 裸晶片、一般封裝、抗反射封裝模擬與實驗比對反射光譜 74
圖6. 10設計A高透光彩色玻璃膜層示意圖 75
圖6. 11設計A高透光彩色玻璃之光性圖譜 76
圖6. 12設計A之光性圖譜及其反射率所對應之(A)色度座標與(B)色彩空間 77
圖6. 13設計B高透光彩色玻璃膜層示意圖 78
圖6. 14設計B高透光彩色玻璃之光性圖譜 79
圖6. 15設計B反射率所對應之(A)色度座標與(B)色彩空間 80
圖6. 16設計C高透光彩色玻璃膜層示意圖 81
圖6. 17設計C高透光彩色玻璃之光性圖譜 82
圖6. 18設計B反射率所對應之(A)色度座標與(B)色彩空間 83
圖6. 19 設計A之彩色封裝反射光譜模擬 84
圖6. 20設計B之彩色封裝反射光譜模擬 85
圖6. 21設計C之彩色封裝反射光譜模擬 85
圖6. 22彩色封裝反射率所對應之(A)色度座標與(B)色彩空間 86
圖6. 23不同反射率下之對應效率 87
圖6. 24 設計B之電壓電流密度特性曲線 88
圖6. 25設計A,C與玻璃封裝之電壓電流密度特性曲線 88
圖6. 26彩色封裝量測樣品之照片 89


表目錄
表4. 1ITO氧流量變化之光性量測結果 23
表4. 2 ITO氧流量變化之電性量測結果 23
表4. 3 ITO氧流量變化熱處理後之光性量測結果 25
表4. 4 ITO氧流量變化熱處理後之電性量測結果 25
表4. 5 ITO氧流量變化之光性量測結果(氬氣退火前) 27
表4. 6 ITO氧流量變化之電性量測結果(氬氣退火前) 27
表4. 7 ITO氧流量變化之光性量測結果(氬氣退火後) 29
表4. 8 ITO氧流量變化之電性量測結果(氬氣退火後) 29
表4. 9 DC100W鍍製ITO薄膜的光、電性量測結果 33
表4. 10 DC50W鍍製ITO薄膜的光、電性量測結果 34
表4. 11RF100W鍍製ITO薄膜的光、電性量測結果 35
表4. 12 DC電源鍍製ITO薄膜的製程參數及光性量測結果 37
表4. 13 DC電源鍍製ITO薄膜的製程參數及光性量測結果 37
表4. 14 RF電源鍍製ITO薄膜的製程參數及光性量測結果 38
表4. 15 RF電源鍍製ITO薄膜的製程參數及光性量測結果 38
表4. 16穿透式彩色電極各膜層厚度參數 39
表5. 6鈣鈦礦反射式太陽電池膜層厚度及其CIE色度座標參數 46
表5. 7鈣鈦礦反射式太陽電池膜層厚度及其CIE色度座標參數 47
表5. 8鈣鈦礦反射式太陽電池光性及電極電性 47
表5. 9鈣鈦礦反射式彩色太陽電池膜層厚度及其CIE色度座標參數 48
表5. 10不同高透光基板之電壓電流密度特性曲線參數 51
表5. 11不同高透光彩色基板之電壓電流密度特性曲線參數 55
表5. 12 OPV穿透式彩色太陽電池膜層厚度參數 57
表5. 13穿透式彩色太陽電池電壓電流密度特性曲線參數 59
表5. 14元件一之四種不同情況電壓電流密度特性曲線參數 64
表5. 16元件二之EQE積分之閉路電流值 65
表6. 1裸晶片、一般封裝與抗反射封裝於波長400-1100奈米的平均反射率 74
表6. 2設計A高透光彩色玻璃之膜層結構、厚度與對應之平均穿透率 76
表6. 3設計A之色度座標與色彩空間參數 77
表6. 4設計B高透光彩色玻璃之膜層結構、厚度與對應之平均穿透率 78
表6. 5設計B之色度座標與色彩空間參數 80
表6. 6設計C高透光彩色玻璃之膜層結構、厚度與對應之平均穿透率 81
表6. 7設計C之色度座標與色彩空間參數 83
表6. 8設計A,B,C之彩色封裝效率推估 87
表6. 9玻璃封裝與設計A,B,C之效率量測參數 89

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