臺灣博碩士論文加值系統

以溴乙酸苯甲酯烷化修飾N-confused紫質2-N位置，生成2-NCH2COOCH2C6H5NCTPPH (2)，將其與Ni、Pd、Pt、Mn、Co之金屬試劑反應，以獲得六種金屬錯合物：Ni(2-NCH2COOCH2C6H5NCTPP) (3)、Pd(2-NCH2COOCH2C6H5NCTPP) (4)、Pt(2-NCH2COOCH2C6H5NCTPP) (5)、Mn(2-NCH2COOCH2C6H5NCTPP)Br (6)、Co(2-NCH2COOCH2C6H5-21-CH2C6H5NCTPP)Cl (7)、Co(2-NCH2COOCH2C6H5-21-CH2C6H4CH3NCTPP)Cl (8)。藉由X-ray單晶繞射儀、核磁共振光譜儀、電子順磁共振光譜儀、超導量子干涉儀等儀器，來鑑定金屬錯合物各種微觀物理化學現象，並加以研究探討。

We use benzyl bromoacetate as 2-N substituted alkylation to react with N-confused porphyrin to afford 2-aza-2-benzyloxycarbonylmethyl-5,10,15,20-tetraphenyl-21-carbaporphyrin (2-NCH2COOCH2C6H5NCTPPH) (2). After 2-N substituted alkylation, we use Ni(OAc)2∙4H2O, PdCl2, PtCl2, MnBr2 and CoCl2∙6H2O to react seperately with 2-NCH2COOCH2C6H5NCTPPH (2) to get six NCP metal complexes, Ni(2-NCH2COOCH2C6H5NCTPP) (3), Pd(2-NCH2COOCH2C6H5NCTPP) (4), Pt(2-NCH2COOCH2C6H5NCTPP) (5), Mn(2-NCH2COOCH2C6H5NCTPP)Br (6), Co(2-NCH2COOCH2C6H5-21-CH2C6H5NCTPP)Cl (7) and Co(2-NCH2COOCH2C6H5-21-CH2C6H4CH3NCTPP)Cl (8). Appling X-ray single-crystal diffractometer, NMR spectrometer, EPR spectrometer, superconducting quantum interference device and et cetera to study the crystal structures of NCP metal complexes and various microcosmic physical chemistry property.

第一章 序論 1
一. N-confused紫質的發現與命名 2
二. N-confused紫質的合成研究 4
三. N-confused紫質異構型態的發現 5
四. N-confused紫質2-N位置的烷化修飾 7
五. N-confused紫質的實驗室研究與發展 8

第二章 實驗部分 10
一. N-confused tetraphenylporphyrin (1)之合成 11
二. 2-NCH2COOCH2C6H5NCTPPH (2)之合成 13
三. Ni(2-NCH2COOCH2C6H5NCTPP) (3)之合成 15
四. Pd(2-NCH2COOCH2C6H5NCTPP) (4)之合成 17
五. Pt(2-NCH2COOCH2C6H5NCTPP) (5)之合成 19
六. Mn(2-NCH2COOCH2C6H5NCTPP)Br (6)之合成 21
七. Co(2-NCH2COOCH2C6H5-21-CH2C6H5NCTPP)Cl (7)
之合成 23
八. Co(2-NCH2COOCH2C6H5-21-CH2C6H4CH3NCTPP)Cl (8)
之合成 25
九. 實驗用藥品 29
十. 儀器與測定方式 31

第三章 結果與討論 34
一. X-ray單晶結構分析 35
二. NMR光譜數據 51
三. 1H NMR受195Pt影響之衛星訊號討論 67
四. Iminium ion pairs討論 70
五. Co NCP錯合物特殊的環內21-C烷化反應 77
六. 結論 80

參考資料 81

附錄 83
一. 化合物1 ~ 8簡寫與全名對照 84
二. 化合物2 ~ 8質譜圖 85
三. 化合物2 ~ 8元素分析數據 99
四. 化合物2 ~ 8 UV-vis與UV-vis-NIR光譜圖 102
五. 化合物2 ~ 8 X-ray晶體數據CIF full publication check 108

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