臺灣博碩士論文加值系統

過度使用化石燃料除了造成環境污染亦面臨能源危機，促使再生能源發展趨勢。而根據室內空氣品質標準規定CO2濃度八小時平均不得超過1000 ppm ，超過1000 ppm會使人感到疲倦、昏沉。沸石具有吸附空氣污染物之用途，而沸石主要由矽、鋁所組成，因此本研究蒐集廢棄玻璃及二次鋁渣，將廢玻璃及鋁渣回收再利用，將能降低其環境潛在威脅，以達到廢棄物資源高質化之目的，故本研究為發展一套快速且低成本的微波再生技術合成沸石。為提高吸附CO2之吸附量，本研究使用胺附著於沸石上，使得CO2的吸附能力提高。研究結果發現合成沸石以固液比10 mg/ml、微波加熱溫度200°C及微波時間4小時，可達到最佳合成效果，其比表面積為56.7 m2/g，而經XRD分析顯示合成沸石主要物質為羥基沸石(Hydroxycancrinite)。再將合成沸石進行胺基改質，其條件為AMP + MEA基底液為甲醇與沸石之重量百分比68%、浸泡時間2.5 hr及浸泡溫度70°C，於80°C下吸附CO2，進行管柱內二氧化碳吸附驗試驗，二氧化碳濃度為1500 ± 5% ppm，於40min時吸附達平衡，吸附量可以達到32.5 mg/g。並經反覆吸脫附試驗，經10次循環，吸附指標下降至78.1%。

In addition to causing environmental pollution, excessive use of fossil fuels is also facing an energy crisis, prompting the development of renewable energy. According to the indoor air quality standards, the average CO2 concentration should not exceed 1000 ppm for eight hours. If it exceeds 1000 ppm, people will feel tired and faint. Zeolite has the purpose of adsorbing air pollutants, and zeolite is mainly composed of bismuth and aluminum. Therefore, this study collects waste glass and secondary aluminum slag, and recycles waste glass and aluminum slag, which will reduce potential environmental threats. In order to achieve the goal of high quality waste resources, this study developed a fast and low-cost microwave regeneration technology to synthesize zeolite. In order to increase the adsorption amount of adsorbed CO2, this study used an amine attached to the zeolite to improve the adsorption capacity of CO2. The results show that the synthetic zeolite can achieve the best synthesis effect with a solid-liquid ratio of 10 mg/ml, microwave heating temperature of 200 ° C and microwave time of 4 hours, and its specific surface area is 56.7 m2 /g. The XRD synthesized zeolite evidenced that Hydroxycancrinite. The synthetic zeolite is further subjected to amine-based modification under the condition that the AMP + MEA base liquid is 68% by zeolite weight of methanol, 2.5 hrs of the soaking time, and the soaking temperature at 70 ° C, and CO2 is adsorbed at 80 ° C to carry out the column. The internal carbon dioxide adsorption test has a carbon dioxide concentration of 1500 ±5% ppm, and the adsorption reaches equilibrium in 40 min, and the adsorption amount can reached 32.5 mg/g. After repeated adsorption and desorption experiments, for 10 cycles, the adsorption capacity decreased to 78.1%.

論文審定書 i
論文公開授權書 ii
摘要 iii
英文摘要 iv
目錄 v
圖目錄 viii
表目錄 xi
第一章 前言 1
1.1 研究緣起 1
1.2 研究目的 3
第二章 文獻探討 4
2.1 廢玻璃 4
2.2 鋁渣 5
2.3 沸石 6
2.3.1 廢棄物再生沸石 9
2.4 二氧化碳捕捉技術 11
2.5 胺類處理二氧化碳之技術 14
2.5.1不同胺類比較 14
2.5.2胺類與複合材料之合成方法 15
2.5.3 胺類去除二氧化碳反應機制 16
2.5.4 胺基改質吸附材吸附二氧化碳之研究 17
第三章 研究方法與實驗方法 19
3.1 研究流程 19
3.2實驗設計法 21
3.3 實驗步驟 22
3.3.1 廢棄玻璃前處理 22
3.3.2 矽酸鈉溶出 22
3.3.3 鋁渣前處理 23
3.3.4 微波合成沸石 23
3.3.5 胺官能基改質 24
3.3.6再生載體去除二氧化碳之試驗 25
3.3.6.1 吸附量之計算 26
3.4 分析方法與材料設備 28
3.4.1 儀器設備 28
3.4.2 藥品耗材 29
3.4.3合成沸石所使用之儀器 30
3.4.5合成沸石分析與鑑定 32
第四章 結果與討論 38
4.1 吸附材之基礎鑑定及分析 39
4.1.1 鋁渣及吸附材之氮氣等溫吸附/脫附測量 39
4.1.2 鋁渣及合成沸石之結構排列鑑定 42
4.1.3環境掃描式顯微鏡分析鋁渣及合成沸石 44
4.1.4能量分散式光譜儀分析鋁渣 47
4.1.5感應偶合電漿光譜分析鋁渣及合成沸石 50
4.1.6 紅外線光譜儀分析表面胺官能基合成沸石 53
4.1.7 TGA熱重分析儀分析表面胺官能基合成沸石 54
4.2探討廢玻璃之溶解率 56
4.2.1以DOE探討廢玻璃溶解 56
4.2.2 廢玻璃在不同條件之溶解率最佳應用 60
4.2.3 以CCD探討廢玻璃最佳溶解率趨勢 63
4.3 利用鋁渣與廢玻璃合成沸石 68
4.3.1以DOE探討鋁渣與矽酸鈉溶液合成沸石之最佳比表面積 68
4.3.2鋁渣與矽酸鈉溶液合成沸石在不同條件之最佳比表面積應用 70
4.3.3 以CCD探討鋁渣與矽酸鈉合成沸石最佳比表面積趨勢 73
4.4 胺基改質合成沸石吸附二氧化碳試驗 76
4.4.1 以DOE探討胺基改質合成沸石吸附二氧化碳試驗 76
4.4.2 胺基改質合成沸石在不同條件之吸附二氧化碳試驗最佳應用 80
4.4.3 以CCD探討胺基改質合成沸石最佳吸附量趨勢 84
4.4.4 單次吸附實驗測試 88
4.4.5 二氧化碳反覆吸脫附試驗 89
4.4.6 胺基改質沸石與商用沸石之比較 90
4.5 成本效益分析 91
五、結果與建議 93
六、參考文獻 96

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