臺灣博碩士論文加值系統

本研究之目的為以光解氧化法(UVC/ H2O2)處理石化業丙烯腈(AN)廢
水之可行性探討及了解處理後之生物抑制性及生物可利用性。
本研究以紫外可見光(UV-Visible)光譜分析(波長254nm 之紫外光
(UVC 光))、溶氧(DO)、氧化還原電位(ORP)、酸鹼值(pH)和溫度(℃)等現
象進行反應變動的即時監測，再以Microtox 生物抑光性、BOD5/COD 等
分析比較光解氧化後，過氧化氫(H2O2)之劑量、UV 光功率之強度及遮蔽
效應等的影響。
UV-Visible 光譜分析結果顯示AN 廢水中以乙腈及有機腈類為其最
主要之成份，其中乙腈為造成生物抑制性之關鍵因子。經過1% H2O2 的
添加劑量及UVC 光功率9W 的處理條件下，光解時間60min 後即對乙腈
有37%之去除率、對有機腈類則為30%，並在處理後腈類降解為酰氨基
後生成有機酸，其增加率分別為10%及60%。而在相同的H2O2 劑量下，
將UVC 光能量增強為36W，反應時間可縮短至40min，其對於乙腈之去
除率增為41%、有機腈類為33%，酰氨基及有機酸之增加率則仍分別為
10%及60%。然而同樣以36W 的UVC 光照射，若將H2O2 添加劑量調整
為0.1%，反應時間則延長至60min，其對於乙腈之去除率仍有35%、有
機腈類則為25%，酰氨基之增加率則增至12%，有機酸則僅有30%的增
加率。Microtox 之分析結果顯示過量H2O2殘留於水中亦會造成高生物抑制
性，故實驗之最佳操作條件為以36W 功率強度之UVC，添加0.1% H2O2
劑量之進行光解氧化處理60min，經處理後原水之Microtox 生物抑光性
(生物毒性)由92%降低至35%，且由BOD5/COD 分析之結果為0.4，亦
顯示經處理後之廢水已具生物可利用性。
綜論研究結果為；(1) H2O2 添加劑量對乙腈之去除率無明顯效果，而
對於有機酸的生成則有明顯的影響。(2)廢水中乙腈之去除率與UVC 光之
能量增強有關，故與直接光解機制有關聯。(3)腈類降解之副產物與H2O2
添加劑量有直接的關聯，過量H2O2 之添加劑量僅對酰氨基生成有機酸
有影響，因此有機酸之生成與間接光解之關係較大。本研究結果證實
AN 廢水經UVC/ H2O2 光解氧化預處理後，有助於去除有機腈類，且已
降低生物毒性，具有生物可利用性。

致謝··················································· i
中文摘要··············································· ii
英文摘要··············································· iv
目錄··················································· vi
圖目錄················································· ix
表目錄················································· xiii
第一章緒論············································· 1
1-1 研究源起·········································· 1
1-2 研究目的·········································· 3
第二章文獻回顧········································· 4
2-1 丙烯腈之簡介······································· 4
2-1-1 台灣石油化學工業······························· 4
2-1-2 丙烯腈之基本特性及用途························· 5
2-2 高級氧化處理程序··································· 7
2-2-1 高級氧化處理技術之簡介························· 7
2-2-2 UV/H2O2 光解氧化法····························· 9
2-2-3 UV/H2O2 法之相關應用··························· 12
2-3 紫外/可見光譜分析·································· 17
2-3-1 光譜分析原理··································· 17
2-3-2 光譜分析之應用································ 19
2-4 水中生物毒性檢測··································· 20
2-5 生物毒性檢測之方式及種類··························· 21
2-5-1Microtox 之原理································ 23
2-5-2Microtox 之特性································ 25
第三章材料與方法······································· 27
3-1 研究流程及架構····································· 27
3-2 UV/H2O2 反應裝置·································· 31
3-3 實驗操作條件及步驟································· 32
3-3-1 原水水質······································· 32
3-3-2 H2O2 氧化實驗·································· 32
3-3-3 UV/H2O2 光解實驗······························· 33
3-4 實驗藥品及儀器····································· 34
3-5 各項水質分析項目及檢測方法························· 36
第四章結果與討論······································· 45
4-1AN 廢水原水特性··································· 45
4-1-1 原水特性······································· 45
4-1-2 生物分解性····································· 47
4-2 UV/H2O2 法處理之結果與討論························ 50
4-2-1 過氧化氫(H2O2)氧化條件分析····················· 50
4-2-2 UVC 光功率9W 含光罩之H2O2 添加劑量實驗······· 53
4-2-3 UVC 光源玻璃光罩遮蔽實驗······················· 62
4-2-4 光解氧化之能量影響實驗························· 67
4-2-5 UVC 光功率36W 無光罩之H2O2 添加劑量實驗······· 74
4-3Microtox 生物抑光性分析····························· 80
4-3-1 殘留之H2O2 對於生物之抑光性···················· 80
4-3-2 UVC 光功率36W 光解氧化後AN 廢水之生物抑光性·· 81
4-5 綜合效能評估······································· 84
4-5-1 UVC/H2O2 條件比較及可行性評估·················· 84
4-5-2 成本效益······································· 87
第五章結論與建議······································· 89
5-1 結論············································ 89
5-2 建議············································ 91
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