臺灣博碩士論文加值系統

超分子聚合物由次級交互作用力結合而成，運用在聚合物材料上，可控制聚合物基質中的超分子自組裝。由於這種材料具有獨特的物理性質，使它們在許多領域的應用上備受重視。本論文利用互補多點式氫鍵，成功合成出一種新型、具熱可逆性的低分子量聚脲材料。這種在溫和條件下以熱壓法製成的新材料，可自組裝形成類似物理性交聯聚合物的薄膜，並具有良好的機械性質（楊氏模數= 14.9 MPa，斷裂伸展率= 386.93 %）。更重要的是，變溫流變性質證實動態交聯導致穩定、可逆性網絡的形成，使它在再循環/再加工過程中，可以快速的重新鍵結/分解，因此具有高度利用性。此外它具有獨特的自癒性質，在室溫下即可顯現優秀的自癒能力，恢復材料原本的機械性質。因此這種新開發的材料，在以自組裝動態網絡為基礎的次世代超分子彈性體產業發展上，將貢獻卓著。

Supramolecular polymer, the combination of secondary interaction and polymer material can be used to control supramolecular self-assembly in polymeric matrix, which materials exhibit unique physical properties that make them attractive for applications in various fields.In this thesis, a novel low-molecular-weight polyurea with thermoreversible ability was successfully prepared through the complementary multiple hydrogen bonds. This new material is able to self-assemble to form a physically crosslinked polymer-like membrane with good mechanical properties (Young’smodulus= 14.9MPa, elongation= 386.93 %) through hot pressing under mild conditions.More importantly, the temperature-dependent rheological characteristics demonstrated that dynamic cross-linking leads to formation of stably reversible networks, making it highly appealing for fast re-bonding/dissociation in recycling/reprocessing procedures. In addition, this offers a unique opportunity towards efficient self-healing ability, which shows excellent self-healingcapability to restore the mechanicalproperty at room temperature.Thus, this newly developed material provides a significant contribution to industrial development of next-generation supramolecular elastomerbased on self-assembling dynamicnetworks.

目錄
中文摘要i
英文摘要iii
誌謝I
目錄vii
表目錄xi
圖目錄xii
第一章緒論1
1.1 超分子化學（Supramolecular chemistry）1
1.1.1 超分子化學的定義與發展1
1.1.2分子識別（molecular recognition)4
1.1.3分子自組裝（molecular self-assembly)8
1.1.4氫鍵（Hydrogen bond）11
1.2　聚胺基甲酸酯（Polyurethane，PU)17
1.2.1　定義與研究發展17
1.2.2　PU的特性19
1.2.3　合成與製備23
1.2.4　含多重氫鍵官能基的PU與其它材料之比較29
1.2.5　醫學上的應用 31
1.3　胞嘧啶模組(Cytosine modulus)34
1.4　自癒性聚合物 38
1.5　研究動機43
第二章　實驗部份44
2.1　反應溶劑的除水過程44
2.2　藥品 44
2.3　儀器設備46
2.3.1　凝膠滲透層析儀(Gel Permeation Chromatography，GPC)46
2.3.2　核磁共振光譜(Nuclear magnetic resonance，NMR)46
2.3.3　傅立葉轉換紅外線光譜儀(Fourier Transform Infrared Spectrometer，FT-IR)47
2.3.4　熱重分析儀(Thermal Gravimetric Analyzer，TGA)47
2.3.5　微差掃描熱卡計(Differential Scanning Calorimeter，DSC)48
2.3.6　動態機械分析儀(Dynamic Mechanical Analyzer，DMA)48
2.3.7　拉伸強度測試(Tensile Strength)48
2.3.8　廣角X光繞射分析儀（wide-angle X-ray diffraction，WAXD)49
2.3.9　小角X光繞射儀(Small-Angle x-ray scattering，SAXS)49
2.3.10　掃描式電子顯微鏡(Scanning Electron Microscope，SEM)49
2.3.11　原子力顯微鏡(Atomic force microscope，AFM)50
2.3.12　流變儀(Rheometer)50
2.4 合成步驟50
2.4.1 PU-Cy之合成路徑50
2.4.2 PU-NH2的合成路徑52
第三章結果與討論54
3.1 合成物鑑定54
3.2 變溫1H NMR分析59
3.3 變溫FTIR分析62
3.4　熱重分析66
3.5　微差掃描熱卡計分析67
3.6　廣角X光繞射儀分析70
3.7　小角度X光散射71
3.8　動態機械分析73
3.9　流變性質分析76
3.10　拉伸機械性質77
3.11 掃描式電子顯微鏡分析82
3.12 原子力顯微鏡 84
3.13 細胞存活率測試87
第四章　結論90
參考資料93

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