臺灣博碩士論文加值系統

利用核磁共振光譜儀及X光單晶繞射儀探討金屬大環錯化合物，M(Por)(L)n之分子結構，其中 M = 鋅、鉈、鎵、鎘、汞、鎂 Por = (N-p-NSO2C6H4tBu-tpp)及(p-Br)4tpp

Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Zn, Tl, Ga, Cd, Hg and Mg, Por = (N-p-NSO2C6H4tBu-tpp) and (p-Br)4tpp

目錄
表目錄
圖目錄
引言
試藥及溶劑
儀器設備
儀器之測定方式

第一章 金屬鋅、鉈、鎵之porphyrin錯化合物
一、前言-------------------------------------------------------2
二、實驗步驟---------------------------------------------------3
三、核磁共振光譜之測定-----------------------------------------19
四、晶體的培養及X光單晶繞射儀測定結構------------------------75
五、X-ray結構分析---------------------------------------------78
六、結果與討論-----------------------------------------------102
七、總結-----------------------------------------------------109
參考文獻-----------------------------------------------------111


第二章 金屬鎘、汞、鎂之porphyrin錯化合物
一、前言------------------------------------------------------114
二、實驗步驟--------------------------------------------------115
三、核磁共振光譜之測定----------------------------------------122
四、晶體的培養及X光單晶繞射儀測定結構-----------------------149
五、X-ray結構分析--------------------------------------------150
六、結果比較-------------------------------------------------168
七、總結------------------------------------------------------169
參考文獻-----------------------------------------------------170
附錄一、Zn (N-p-NSO2C6H4tBu-tpp)．0.7MeOH的晶體數據
附錄二、Tl (N-p-NSO2C6H4tBu-tpp)(OAc)的晶體數據
附錄三、Tl (N-p-NSO2C6H4tBu-tpp)(O2CCF3)的晶體數據
附錄四、Ga (N-p-NSO2C6H4tBu-tpp)(OH)的晶體數據
附錄五、Cd(p-Br)4tpp(py)的晶體數據
附錄六、Hg(p-Br)4tpp(py)的晶體數據
附錄七、Mg(p-Br)4tpp(DMF)的晶體數據

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