臺灣博碩士論文加值系統

本實驗係利用吸附法，將模擬苯甲酸廢水以及有機酸性染料廢水(苯甲酸和酸性染料-正黃)中的苯甲酸移除，吸附劑為未改質的5A zeolite。實驗中，改變的參數有實驗溫度、水溶液pH值、溶質濃度等。並且做了吸附動力學實驗以及等溫吸附實驗。將單成份動力學實驗數據帶入擬一階、擬二階、與Elovich 模式；在不同溫度下，苯甲酸的單成份動力學實驗數據皆較符合擬一階模式。且在pH 3和pH 11下，苯甲酸與其他分子會有競爭吸附的效果，使苯甲酸的吸附量較低。酸性染料-正黃在5A分子篩上的吸附量較苯甲酸高，但酸性染料-正黃需要較長的吸附時間。

In this study, adsorption method was used to remove benzoic acid in the simulated benzoic acid wastewater and simulated organic acid dye wastewater, including benzoic acid and acid dye-yellow. The adsorbent used is unmodified 5A zeolite. In the experiment, the experimental variables are the experimental temperature, the pH of aqueous solution, and the concentrations of solutes. Both adsorption kinetics experiments and adsorption isotherm experiments were conducted. The single component adsorption kinetic data were fitted by the pseudo first-order model, pseudo second-order model, and the Elovich model. The benzoic acid adsorption kinetic data were suitable for the pseudo first-order model at different temperatures. At pH 3 and pH 11, the competitive adsorption of dye reduced the adsorption amounts of benzoic acid. The adsorption capacity of Acid dye-yellow by 5A zeolite is greater than that of benzoic acid, but the required adsorption time of acid dye-yellow is longer.

誌 謝i
ABSTRACTii
摘 要iii
目 錄iv
表目錄vii
圖目錄ix
第一章 前言1
1.1 研究背景1
1.2 研究目的2
第二章 文獻回顧3
2.1 苯甲酸3
2.1.1 苯甲酸簡介3
2.1.2 苯甲酸用途6
2.2 酸性染料11
2.2.1 酸性染料定義11
2.2.2 酸性染料用途14
2.3 有機染料廢水處理方法14
2.4 分子篩22
2.4.1 分子篩介紹22
2.4.2 分子篩分類25
2.4.3 分子篩的選擇25
2.5 吸附動力學29
2.6 等溫吸附平衡31
2.7改變實驗參數對吸附的影響36
2.8 相關專利38
2.8.1 一種吸附分離工業廢水中芳香酸的方法38
第三章 實 驗40
3.1 實驗藥品與儀器40
3.1.1 實驗藥品40
3.1.2 實驗儀器40
3.2 溶液配製41
3.3 分子篩前處理42
3.4 實驗步驟42
3.4.1 單成份吸附動力學實驗42
3.4.2 單成份吸附平衡實驗43

3.4.3 雙成份吸附動力學實驗44
3.4.4 雙成份吸附平衡實驗45
3.5 檢量線測定46
3.5.1 單成份UV/Vis檢量線之測定46
3.5.2 雙成份UV/Vis檢量線之測定55
第四章 結果與討論67
4.1單成份吸附動力學實驗67
4.1.1 溫度對BA吸附之影響67
4.1.2 pH對BA吸附之影響76
4.1.3 濃度對BA吸附之影響81
4.1.4 酸性染料之動力學實驗86
4.2單成份吸附平衡實驗89
4.3雙成份吸附動力學實驗96
4.3.1 溫度對雙成份吸附之影響96
4.3.2 酸性染料濃度對BA吸附之影響102
4.4雙成份吸附平衡實驗104
第五章 結論與建議107
5.1 結 論107
5.2 建 議108
參考文獻109

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