臺灣博碩士論文加值系統

本研究分成兩部分：第一部份為2205雙相不銹鋼氫脆性研究，試片以不同的定電流密度、時間充氫及不同的應變率下拉伸，比較其差異和探討產生破裂的起始位置。第二部份為冷軋量對IF鋼氫敏感性之影響。
根據氫原子微印實驗之結果，發現氫原子在2205雙相不銹鋼內部擴散的方式為晶格擴散，且在肥粒鐵相中之氫滲透速率及擴散速率高於沃斯田鐵相。由預充氫的試片破斷面觀察，在肥粒鐵相和沃斯田鐵相中皆有脆性破斷的現象，且發現其破裂形式為穿晶破裂。
由金相組織及破斷面觀察發現，經過冷軋後的IF鋼，由於吸收氫原子進而助長穿晶破裂的發生。這些結果顯示經冷軋後的含鈦的IF鋼其對氫所造成的破壞是相當敏感的。

The first part of this study is hydrogen embrittlement of 2205 duplex stainless steel. The second part, the role of plastic deformation by cold work on the hydrogen susceptibility of Ti-bearing interstitial free steel.
Hydrogen embrittlement of 2205 duplex stainless steel has been evaluated using electrochemical permeation measurement, hydrogen microprint technique and tensile test in this study. Due to hydrogen transport in 2205 duplex stainless steel is mainly lattice diffusion in ferritic phase and was confirmed hydrogen microprint technique, more hydrogen distribution, higher permeation rate and diffusion in ferritic phase were detected. Brittle fracture was observed in both the ferritic and austenitic phases of hydrogen precharged specimen.
Permeation trapping and mechanical property effects were studied as a function of cold work for the interstitial free steel with extra-deep drawing quality. Metallographic and fractographic investigations revealed that hydrogen absorption promoted transgranular fracture in cold rolled specimen. These results show that the cold rolled interstitial free steel are susceptible to hydrogen embrittlement.

目錄……………………………………………………………………….Ⅰ
圖目錄…………………………………………………………………….Ⅱ
表目錄…………………………………………………………………….Ⅴ
中文摘要…………………………………………………………………..1
英文摘要…………………………………………………………………..2
第一章 文獻回顧………………………………………………………...3
1.1 氫脆化理論……………………………………………………3
1.2 電化學氫滲透理論…………………………………………..16
1.3 氫原子微印技術……………………………………………..20
1.4 參考文獻……………………………………………………..23
第二章 2205雙相不銹鋼氫脆性研究………………………………….44
2.1 文獻回顧…………………………………………………..44
2.2 實驗步驟…………………………………………………..55
2.3 結果與討論………………………………………………..59
2.4 結論………………………………………………………..67
2.5 參考文獻…………………………………………………..69
第三章 冷軋量對IF鋼氫敏感性之影響……………………………..101
3.1 文獻回顧…………………………………………………101
3.2 實驗步驟…………………………………………………103
3.3 結果與討論………………………………………………108
3.4 結論………………………………………………………111
3.5 參考文獻…………………………………………………112

參考文獻
1. R. A. Meyn, Hydrogen Damage, edited by C. D. Beachem, p. 319, (1977).
2. R. A. Oriani, Hydrogen in Metal, Proc. Symp. Stress Corrosion Cracking, p. 32, (1967).
3. I. M. Bernstein, Mater. Sci. Eng., Vol. 6, p. 1, (1976).
4. J. D. Fast, “Interaction of Metals and Gases”, Philips Technical Library, Vol. 1. p. 128, （1965）.
5. G. M. Pressouyre, Met. Trans. A, Vol. 14A, p. 2189, （1983）.
6. G. M. Pressouyre, Acta Met., Vol.28. p. 895,（1980）.
7. Zapffe, C., Sims, C., Trans. AIME, Vol. 145, p. 225, (1941).
8. Troiano, A. R. Trans. ASM, Vol. 52, p. 54,（1960）.
9. Beachem, C. D., Met. Trans., Vol. 3, p. 437,（1972）.
10. Petch, N. J., Stables, P., Nature, Vol. 169, p. 842,（1952）.
11. S. W. Ciaraldi, Corrosion, Vol. 40, p. 77（1984）.
12. D. R. Westlake, Trans. ASM, Vol. 62, p. 1000（1969）.
13. H. G. Vaughn and M. E. Demodton British Welding Journal, Vol. 4, p. 40 (1957).
14. A. N. Stroh, Adv. In Physics, Vol. 6, p. 418（1957）.
15. C. C. Chen and R. J. Arsenault, Acta Metall., Vol. 23, p. 225（1975）.
16. C. D. Beachem, Metall. Trans., Vol. 3A, p. 437（1972）.
17. H. Jianhong and T. Xiangyun, Chin. J. Met. Sci. Technol., Vol. 6, p.173, (1990).
18. V. J. Gadgil, S. Mandziej and B. H. Kolster, The Minerals, Metals ＆ Materials Society, p. 357,（1990）.
19. Ikeda, A. Kaneko, T., Terasaki, F., Laboratory for the Study of Environmental Degradation of Engineering Materials, p. 203.
20. Thompson, A. W., “Environment-Sensitive Fracture of Engineering Materials” ed. Foroulis, Z. A., T.M.S. of AIME, p. 379,（1979）.
21. 陳春霖，國立台灣海洋大學碩士論文，1993.
22. 莊智欽，國立台灣海洋大學碩士論文，1994.
23. Mars. G. Fontana, Corrosion Engineering, third edition, McGraw-Hill, New York, p. 146, (1987).
24. A. Sieverts, W. Krumbhaar and E. Jurisch, Z. Physik. Chem., Vol. 77, p. 591, (1911).
25. 歐克勤，國立台灣海洋大學碩士論文，1996.
26. D. A. Jones, Principles and Prevention of Corrosion, Chap. 10, p. 341, (1992).
27. J. P. Hirth and H. H. Johnson, Corrosion, Vol. 32, p. 3, (1976).
28. C. L. Chen, P. Y. Lee, D. J. Chiou, C. Y. Chu, J. Y. Lin and J. K. Wu, Corrosion Prevention and Control, Vol. 40, p. 71, (1993).
29. ibid., J. Materials Sci. Letter, Vol. 12, p. 205, (1993).
30. B. E. Wild and T. Shimada, Chinese J. Materials Science, Vol. 19, p. 107, (1987).
31. L. H. Chiu, T. I. Wu and J. K. Wu, J. Material Sci. Letter, Vol. 12, p. 1582, (1993).
32. Y. C. Wu, W. Y. Wei, J. M. Chen and J. K. Wu, Tatung Journal, Vol. 19, p. 194, (1989).
33. J. M. Chen and J. K. Wu, Corrosion Sci., Vol. 33, p. 657, (1992).
34. J. M. Chen and J. K. Wu, Plating and Surface Finishing, Vol. 79, p. 74, (1992).
35. S. L. I. Chan, H. L. Lee and J. R. Yang, Hydrogen Effects on Materials Behavior, edited by N. R. Moody and A. W. Thompson, TMS, p. 145, (1990).
36. I. M. Bernstein and A. W. Tomphson, Hydrogen Embrittlement and Stress Corrosion Cracking, edited by R. Gibala and R. F. Hehemann, ASM, p. 135, (1984).
37. S. X. Xie and J. P. Hirth, Corrosion, Vol. 38, No. 9, p. 486.
38. Y. Kikuta and T. Araki, Hydrogen Effects in Metals, edited by I. M. Bernstein and A. W. Thompson, AIME, p. 309, (1981).
39. C. F. Merlone, A. J. Funes, J. Ovejero-Garcia, Mem' Etud. Sci. Rev. Metall., Vol. 82, p. 337, (1985).
40. G. M. Pressouyre, J. Dollet and B. Vieillard-Baron, Met. Sci. Rev., Vol. 79, p. 161, (1982).
41. K. N. Akhurst and P. H. Pumphrey, Second International Congress on Hydrogen in Metals, 3B1, Paris-France, (1977).
42. J. P. Hirth and H. H. Johnson, Corrosion, Vol. 32, p. 3, (1976).
43. M. Martinez-Madrid, S. L. I. Chan and J. A. Charles, Met. Sci. and Tech., Vol. 1, p. 454, (1985).
44. L. S. Darken and R. P. Smith, Corrosion, Vol. 5, p. 1, (1949).
45. A. J. Kumnick and H. H. Johnson, Met. Trans., Vol. 5, p. 1199, (1974).
46. J. A. Marquez, I. Matsushima and H. H. Uhlig, Corrosion, Vol. 26, p. 215, (1970).
47. E. Miyoshi, T. Tanaka, F. Terasaki and A. Ikeda, J. of Eng. For Industry, Nov., p. 1221, (1976).
48. M. Hashimoto and R. M. Latanision, Met. Trans. A, Vol. 19A, p. 2789, 1988.
49. M. H Ashimoto and R. M. Latanision, Met. Trans. A, Vol. 19A, p. 2799, (1988).
50. R. D. McCright, “Effects of Environmental Species and Metallurgical Structure on the Hydrogen Entry into Steel” in Stress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys, edited by R. W. Staehle, J. Hochmann, R. D. McCright and J. E. Slater, NACE, Huston, Texas, p. 306, (1977).
51. M. A. V. Davanathan and Z. Stachurski, J. Electrochem. Soc. Vol. 110, p. 886, (1963).
52. J. O’M Bockris, J. McBreen and L. Nanis, J. Electrochem. Soc. Vol. 112, p. 1025, (1965).
53. K. Kiuchi and R. B. McLellan, Acta Metal. Vol. 31, p. 961, (1983).
54. J. P. Laurent and G. Lapasset, Int. J. Appl. Rad. Isot. Vol. 24, p. 213, (1973).
55. M. Aucouturier, G. Lapasset and T. Asaoka, Metallurgy, Vol. 11, p. 5, (1978).
56. J. Chene, J. Ovejero-Garcia, C. Paesde Oliveira, M. Aucouturier and P. Lacombe, J. Micros. Sp. Electr., Vol. 4, p. 37, (1979).
57. T. Asaoka, C. Dagbert, M. Aucouturier and J. Galland, Scripta Metall., Vol. 11, p. 467, (1977).
58. T. E. P'erez and J. Ovejero-Garcia, Scripta Metall., Vol. 16, p. 161, (1982).
59. W. C. Luu and J. K. Wu, Mater. Lett., Vol. 24, p. 175, (1995).
60. W. C. Luu and J. K. Wu, Corr. Sci., Vol. 38, p. 239, (1996).
61. W. C. Luu, H. S. Kuo and J. K. Wu, Corr. Sci., Vol. 39, p. 1051, (1997).
62. J. Ovejero-Garcia, J. Mater. Sci., Vol. 20, p. 2623, (1985).
63. 魯萬鈞，國立台灣海洋大學碩士論文，1994.
64. 嚴拱平，國立中興大學碩士論文，1995.
參考文獻
1. M. Scheil, O. Zmeskal, J. Waber and F. Stockhausen, Weld. J., Res. Supplement, Vol. 22, p. 493（1943）.
2. R. T. Newberg and H. H. Uhlig, J. Electrochem. Soc., Vol. 119, p. 981, (1972).
3. C. Aslund, Scand. J. Met., Vol. 5, p. 200,（1976）.
4. A. P. Bond and H. J. Dundas, Corrosion, Vol. 24, p. 344,（1968）.
5. V. Cihal, Stainless Steel, Vol. 77, p. 227,（1977）.
6. M. Barteri, F. Mancia and A. Tamba, Corrosion, p. 518（1987）.
7. T. Suzuki, H. Hasegawa and M. Watanabe, J. Jpn. Inst. Met., Vol. 32, p. 1171,(1968)(in Japanese).
8. M. Kowaka, H. Nagano, T. Kudo and K. Yamanaka, Boshoku Gijiutsu (Corrosion Engineering), Vol. 30, p. 218,（1981）.
9. W. Wessling and H. E. Bock, Stainless Steel, Vol. 77, p. 217,（1977）
10. K. Harada, Boshoku Gijiutsu（Corrosion Engineering）, Vol. 26, p. 721, (1977).
11. M. Kowaka, H. Nagano, T. Kobayashi and M. Harada, Sumitomo Kinzoku (Sumitomo Metals), Vol. 28, p. 40,（1976）.
12. T. G. Gooch, Welding in the world, Vol. 24, p. 148, (1986).
13. S. Bernhardsson: Proceeding Conference “Duplex stainless steel”, p. 185, (1991).
14. E. E. Denhard and R. R. Gaugh, Stress Corrosion Testing, ASTM, STP-425, P. 41, (1967).
15. K. Takizawa, Y. Shimizu, E. Yoneda and I. Tamura, Transactions ISIJ, p. 325, (1982).
16. S. Shimodaira, M. Takano, T. Takizawa and H. Kamide, “Proceedings of Internation Conference on Stress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys”, NACE, Houston, Texas, p. 1003, ( 1977).
17. H. D. Solomon and T. M. Devine, Jr., “Duplex Stainless Steel-A tale of Two Phases”, Duplex Stainless Steels, 1982, (proc. Conf.) edt. R. A. Lula, Out. 25-28, St. Louis, Missouri, ASM (1983).
18. H. W. Schlapfer and J. Weber, Material and Technik, Vol. 2, p. 60, (1986).
19. Y. Ishizawa, T. Shimada and M. Tanimura, “SCC Behavior of a Duplex Stainless Steel in Sour Gas Environments”, Corrosion／83, Paper No. 167, NACE, Houston, Texas, (1983).
20. A. J. Sedriks, Corrosion of Stainless Steels, p. 88, John Wiley ＆ Sons, New York, (1979).
21. E. A. Lizlovs, ASTM, STP-516, p. 201, (1972).
22. M. Kowaka and H. Nagano, Tetsu to Hagane (J. Iron Steel Inst. Jpn), Vol. 61, p. 302, (1975).
23. J. Foct and N. Akdut, Scripta Metallugrical et Materialia, Vol. 29, p. 153 (1993).
24. W. T. Tsai, B. Reynders, M. Stratmann and H. J. Grabke, Corrosion. Sci. Vol. 34, p. 1647, (1993).
25. G. J. Theus and R. W. Staehl, Stress Corrosion Cracking and Hydrogen Embrittlement of Fe-Bases Alloys, p. 845, NACE, Houston (1978).
26. C. R. Clayton, L. Rosenzweig, M. Oversluizen and Y. C. Lu, Proc. 170th Meeting of the Electrochemical Society, San Diego, CA., U. S. A. p. 323(19-24 October 1986).
27. Y. C. Lu, R. Bandy, C. R. Clayton and R. C. Newman, J. Electrochem. Soc., Vol. 130, p. 1774,（1983）.
28. M. Fujikura, K. Takada and K. Ishida, Trans. ISIJ 15, p. 464（1975）.
29. V. G. Gavriljuk, V. A. Duz’ and S. P. Jephimenko, Proc. 2nd Int. Conf. High Nitrogen Steels. HNS 90. Aachen, Germany, p. 100,（10-12 October 1990）.
30. H. Ogawa, I. Itoh, M. Nakada, Y. Hosoi and H. Oksda, Tetsu to Hagane（J. Iron Steel Inst. Jpn）, Vol. 63, p. 605,（1977）.
31. M. Kowaka, H. Nagano, K. Yamanaka and T. Kudoh, Boshoku Gijutsu (Corrosion Engineering), Vol. 30, p. 218,（1981）.
32. J. W. Pugh and J. O. Nisbet, Trans. AIME, 188, p. 268,（1950）.
33. R. J. Brigham, Materials Performance, Vol. 13, p. 29,（1974）.
34. J. Hochmann, A. Desestret, P. Jolly and R. Mayoud, Stress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys, NACE-5, ed. R. W. Staehle, J. Hochmann, R. D. McCright and J. E. Slater（Houston, TX: National Assocition Corrosion Engineers, 1977）, p. 956.
35. A. Desestret and R. Oltra, Corros. Sci., Vol. 20, p. 799,（1980）.
36. T. Magnin, J. Le Coze and A. Desestret, Duplex stainless steels, ed. R. A. Lula, (Metals Park, OH: ASM International, 1983), p. 535.
37. A. Laitinen and H. Hänninen, Corrosion, Vol. 52, p. 295, (1996).
38. R. F. A. Jargelius, R. Blom, S. Hertzman and J. Linder, “Chloride-Induced Stress Corrosion Cracking of Powder Metallurgy Duplex Stainless Steels in Concentrated Chloride Environments”, in ‘Duplex Stainless Steel ´91’, ed. By J. Charles and S. Bernhardson, Les Editions de Physique, Vol. Ι, p. 211, (1992).
39. W. J. Nisbet, G. W. Lorimer and R. C. Newman, Corrosion Science, Vol. 35, p. 457, （1993）.
40. J. Sakai, I. Matsushima, Y. Kamemura, M. Tanimura and T. Osuka, “Effects of Metallurgical Factors on Service Performance of Duplex Stainless for Deep Sour Gas Wells”, Journal of Materials for Energy Systems, Vol. 5, p. 105,（1983）.
41. H. Kwon, Scripta Metallurgical et Materialia, Vol. 29, p. 423,（1993）.
42. F. H. Meyer, O. L. Riggs, R. L. McGlasson and J. D. Sudbury, Corrosion, Vol. 14, p. 109（1958）.
43. G. I. Ogundele and W.E. White, Corrosion, p. 43,（1987）.
44. R. L. Martin, Materials Performance, Vol. 13, p. 19,（1974）.
45. R. Oltra and A. Desestret, EICM Proceedings, p. 207.
46. V. J. Gadgil, S. Mandziej and B. H. Kolster, The Minerals, Metals ＆ Materials Society, p. 357,（1990）.
47. Thompson, A. W., “Environment-Sensitive Fracture of Engineering Materials” ed. Foroulis, Z. A., T.M.S. of AIME, p. 379,（1979）.
48. Burns, D. S., Materials Performance, January, p. 21,（1976）.
49. A. Troiano, Trans. Amer. Soc. Metals, Vol. 52, p. 54（1960）.
50. J. Marquez, I. Matsushima and H. Uhlig, Corrosion, Vol. 26, p. 215, (1970).
51. J. R. Valdez-Vallejo, R. C. Newman and R. P. M. Procter, The Minerals, Metals ＆ Materials Society, p. 1003,（1990）.
52. C. H. Tzeng, W. Y. Wei and J. K. Wu, Mater. Sci. Technol., Vol. 5, p. 1236, (1989).
53. T. P. Perng and C. J. Altstetter, Acta Matell., Vol. 34, p. 1771,（1986）.
54. T. P. Perng and C. J. Altstetter, Acta Matell., Vol. 35, p. 1251,（1988）.
55. T. P. Perng and C. J. Altstetter, Metall. Trans., Vol. 19A, p. 145,（1988）.
56. 周賢亮，國立成功大學博士論文，1999.
57. H. Spähn, G. H. Wagner and U. Steinhoff, “Stress Corrosion Cracking and Cathodic Hydrogen Embrittlement in the Chemical Industry”, in ‘Stress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys’, ed. By R. W. Staehle, J. Hochmann, R. D. McCright and J. E. Slater, NACE, p. 80, (1977).
58. A. P. Bond and H. J. Dundas, “Stress Corrosion Cracking of Ferritic Stainless Steel”, in ‘Stress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys’, ed. By R. W. Staehle, J. Hochmann, R. D. McCright and J. E. Slater, NACE, p. 1136, (1977).
59. R. F. A. Jargelius and Fan Cun-Gan, “The Influence of Hydrogen on the Mechanical Properties and Microstuucture of Stainless Steels”, in ‘Proceeding of International Conference on Stainless Steels, 1991’, Chiba, ISIJ, p. 692, （1991）.
60. A. Turnbull and R. B. Hutchings, Materials Science and Engineering, Vol. A177, p. 161,（1994）.
61. F. Iacoviello, M. Habashi and M. Cavallini, Materials Science and Engineering, Vol. A224, p. 116,（1997）.
62. P. Sentence, “Hydrogen Embrittlement of Cold Worked Duplex and Super Duplex Stainless Steel Oilfield Tubulars”, in ‘Duplex Stainless Steel′91’, ed. By J. Charles and S. Bernhardsson, Les Editions de Physique, Vol. Ⅱ, p. 895,（1992）.
63. A. Turnbull, E. Lembach-Beylegaard and R. B. Hutchings, “Hydrogen Transport in Duplex Stainless Steels”, in ‘Forth International Conference Duplex Stainless Steels’, Glasgow, Scotland, Vol. Ⅲ, paper80, （1994）.
64. R. B. Hutchings, A. Turnbull and A. T. May, Scripta Metallurgica et Materialia, Vol. 25, p. 2657,（1991）.
65. X. J. Li, M. H. Wang, C. M. Hsiao, Z. Z. Tien and X. R. Chang, Scripta Metallurgica, Vol. 22, p. 815, （1988）.
66. R. A. Walker and T. G. Gooch, “Hydrogen Cracking of Welds in Duplex Stainless Steel”, in ‘Duplex Stainless Steel´91’, ed. by J. Charles and S. Bernhardsson, Les Editions de Physique, Vol. Ⅱ, p. 1053,（1992）.
67. 嚴拱平，國立中興大學碩士論文，1995.
68. A. M. Brass and J. R. Collet-Lacoste, Acta Mater., Vol. 46, No. 3, p. 869-879,（1998）.
參考文獻
1. J. A. Elias and R. E. Hook, Mechanical Working and Steel Processing IX, AIME, New York, p. 348-368, （1970）.
2. J. A. Elias and R. E. Hook, “Interstitial-Free Sheet Steel-Applications and Performance”, Automotive Engineering Congress, Detroit, Mich., Jan. 10-14, （1972）, SAE Paper No. 720018.
3. Mott N. F and F. R. N Nabarro, “Reports on Conference on the Strength of Solids” Phys. Soc., London, p. 1,（1984）.
4. Dieter G. E. in “Mechanical Metallurgy”., Mc Graw-Hill International book Company, 2nd ed, p. 221,（1976）.
5. 陳煌泉，中鋼研究報告ST80006，80年2月。
6. M. T. Milan, D. Spinelli and W. W. Bose Filho, International Journal of Fatigue, Vol. 23, p. 129,（2001）.
7. V. J. Martinez, J. I. Verdeja and J. A. Pero-Sanz, Materials Charactterization, Vol. 46, p. 45,（2001）.
8. S. Hinotani and Y. Ohmori, Transactions of the Japan Institure of Metals, Vol. 26, p. 622,（1985）.
9. S. L. I. Chan, Journal of Chinese Institute of Engineers, Vol. 22, p. 43, ( 1999 ).
10. T. Y. Zhang and Y. P. Zhang, Acta Mater., Vol. 46, p. 5023,（1998）.
11. A. M. Brass J. R. Collet-Lacoste, Acta Mater., Vol. 46, p. 869,（1998）.
12. D. L. Johnson and J. K. Wu, Journal Materials for Energy System,Vol. 8, p. 402,（1987）.
13. R. D. McCright, Ph. D Thesis, The Ohio State Univ. Columbus, OH, (1971).
14. J. P. Laurent and G. Lapasset, Int. J. Appl. Rad. Isot. Vol. 24, p. 213, (1973).
15. M. Aucouturier, G. Lapasset and T. Asaoka, Metallurgy, Vol. 11, p. 1978.
16. 魯萬鈞，國立台灣海洋大學碩士論文，1994。
17. S. X. Xie and J. P. Hirth, Corrosion-NACE, Vol. 38, p. 486,（1982）.
18. A. J. Kumnick and H. H. Johnson, Metall. Trans., Vol. 5, p. 1199, (1974).
19. D. Tseng, Q. Y. Long and K. Tangri, Sci. Met., Vol. 22, p. 649,（1988）.
20. S. M. Lee and J. Y. Lee, Metall. Trans. A, Vol. 17, p. 181,（1986）.
21. G. S. Frankel and R. M. Latanision, Metall. Trans., Vol. 17, p. 861, (1986).