臺灣博碩士論文加值系統

本篇論文合成出一系列之 Imidazol 衍生物，與銥金屬配位，形成一系列的銥金屬錯合物，改變銥金屬錯合物放光顏色且進行光物理性質探討。
有機發光二極體(OLED)探討當中，Imidazol 衍生物的吸收光譜範圍從250-420 nm，放光光譜從300-500 nm 放出的螢光大部份在藍光。配位基與銥金屬配位後，所形成一系列的銥金屬錯合物，放射波長從450-750 nm，放光範圍黃到紅色的磷光。

This study synthesizes a series of Imidazol derivative, and it coordinate with the iridium metal to form a series of iridium metal complexes. change the iridium metal complexes emission color and carry on discussions of physical optics property to the iridium metal complexes.
The absorption spectra of these compounds showed intense bands appearing in the ultraviolet or near ultraviolet part of the spectrum between 250 and 420 nm, emission spectra show from 300 nm to 500 nm, colors of emission are from blue.After the ligands and metals coordinate to form iridium metal complexes, their color of emission from Yellow to red, emission spectra show from 450 nm to 750 nm.

中文摘要--------------------------------------------------I
英文摘要-------------------------------------------------II
目錄 ---------------------------------------------------III
第一節、緒論----------------------------------------------1
1-1、前言-------------------------------------------------1
1-2、有機發光二極體發光原理-------------------------------1
1-3、有機電機發光二極體材料-------------------------------3
1-4、螢光與磷光-------------------------------------------8
1-5、磷光發光理論----------------------------------------10
1-6、研究動機--------------------------------------------11
第二節、實驗部分-----------------------------------------12
2-1 實驗儀器---------------------------------------------12
2-2 實驗藥品及溶劑---------------------------------------15
2-3化合物結構及代號--------------------------------------17
2-4 合成步驟---------------------------------------------22
第三節、結果與討論---------------------------------------51
3-1 合成討論---------------------------------------------51
3-1-1 Imidazol衍生物的合成-------------------------------51
3-1-2 配位基的合成---------------------------------------51
3-1-3 銥金屬錯合物的合成---------------------------------52
3-2 光學性質討論-----------------------------------------54
3-2-1 紫外光吸收光譜（Uv-vis）與放光光譜（PL）-----------54
第四節、結論--------------------------------------------171
參考文獻------------------------------------------------172
附錄----------------------------------------------------175

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