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研究生:邱垂泓
研究生(外文):Chiou, Chwei-Horng
論文名稱:Al-11%Si-0.2∼0.3%Mg合金及Al-11%Si-0.3%Mg/SiCp複合材料微結構與性質之研究
論文名稱(外文):The Microstructures and Properties of Al-11%Si-0.2~0.3%Mg Alloys and SiC particulates Reinforced Al-11%Si-0.3%Mg Composites
指導教授:楊智富楊智富引用關係
指導教授(外文):Yang Chiu-Fu
學位類別:碩士
校院名稱:大同工學院
系所名稱:材料工程學系
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:1996
畢業學年度:84
語文別:中文
論文頁數:103
中文關鍵詞:高矽鋁輪圈非熱處理型調質處理共晶矽金屬基複合材料界面潤濕劑
外文關鍵詞:High silicon aluminum alloyNon-heat-treatableModificationEutectic siliconMetal matrix compositeWetting Promoter
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本研究第一部份探討引進非熱處理(Non-heat-treatable)高矽鋁合
金輪圈材 於國內鋁輪圈鑄造廠,研究方法包括合金選擇、試棒澆鑄,
比較其與傳統A356.2鋁合金輪 圈材料機械性質、顯微結構及品質指數(
Quality Index) 差異,並探討非熱處理型高矽 鋁輪圈之調質(
Modification)控制,最後進行生產線之試製。實驗結果顯示,適當之高
矽鋁輪圈材料之組成為 Al-11%Si-0.2∼0.3%Mg, 對此合金而言,適當之
Sr調質劑用量為 0.03%,其共晶矽(Eutectic silicon)之長短軸比(
Aspect ratio ) 約為 3:1;當使 用 0.16∼ 0.32%Sb 調質時,其鑄造
狀態 (As Cast)下共晶矽之長短軸比約為 14:1∼ 6:1,其調質效果
與鑄件機械性質遠遜於Sr調質者,故Sb不適用於非熱處理型高矽鋁輪圈
材料之調質處理。由生產線鋁輪圈試製結果顯示,以0.03%Sr 調質之非熱
處理型高矽鋁輪 圈鑄件具有 4∼5級的調質效果,輪環(Rim)位置實體
取樣之拉伸強度、延伸率及品質指 數分別為184MPa、4.8%與286MPa,其
機械性質與顯微結構均與歐美地區之高矽鋁輪圈相符 。

本研究第二部份討論高矽含量鋁合金加入陶瓷強化顆粒而成之金屬基複合
材料之性質 ,並探討添加Sr、Ca與Mg對複合材料之界面行為、顯微組織
機械性質之影響。實驗結果顯 示,添加Sr、Ca、Mg,可明顯改善 Al-11%
Si-0.3%Mg/SiCp 複合材料之耐磨耗性質,其中 尤以添加Ca者最為明顯,
因其伴隨耐磨耗氧化物CaO之生成;而添加Mg者則有MgO生成增加 其耐磨
耗特性,Sr則可改善複合材料內之共晶矽形態,並且使之分佈均勻,亦能
大幅提升 磨耗性質,且延伸率亦獲致明顯之改善。此外由 XRD 及 SEM/
EDAX分析顯示,高矽含量之 Ai-11%Si-0.3%Mg/SiCp 複合材料於850C高
溫長時間靜置並無發現Al4C3相生成。
The first half of this work concerns a study on the
feasibility of introducing non-heat-treatable high silicon
aluminum alloy wheel materials to domestic aluminum alloy
wheel foundries. The Al-11% Si alloys containing 0.2 ∼0.3%
Mg were selected as candidates in this study and subjected to a
series of in-lab evaluations and production-line trials. The
results showed that the Al-11% Si-0.2∼0.3% Mg Alloy
specimens can be best modified through an ad- dition of
0.03% Sr which gave rise to a modification rating of class
4∼5. A water quench procedure of the castings right after
their removal from mould was found beneficial to the
mechanical properties. In comparison with the Sr- modified
specimens, the Al-11% Si-0.2∼0.3% Mg alloys modified by
0.16∼0.32% Sb exhibit poor modification rating with aspect
ratios of eutectic silicon rating from 14:1∼6:1. Analysis
of trial-cast Sr-modified high-silicon Al alloy wheels shows
satisfactory microstructural characteristics with tensile
strength , elongation and quality index of 184 MPa, 4.8%
and 286MPa, respectivety, which were similar to those
obtained from imported commerical non-heat- treatable high-
silicon aluminum alloy wheels.

The second half of this aims to investigate the effects of
wetting pro- moters Ca and Mg and the modifier Sr on the
Al-11% Si-0.3% Mg/SiCp composites. The microstructures of the
composite and the interphases at reinforcing par- ticles/Al
alloy matrix interfaces of the composites were investigated by
OM, SEM/EDAX and XRD. Mechanical properties of the
composites were examined by tensile tests and bending test.
The results showed that the bonding strength of SiC
particulate to the aluminum alloy matrix can be greatly
enhanced by the wetting prometer Ca and that the modifier
Sr helps to produce desirable silicon morphology in aluminum
alloy matrix for improved properties.
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