臺灣博碩士論文加值系統

摘 要
本文探討九種不同化學結構與分子量之壓克力樹脂型抗收縮劑對低收縮不飽和聚酯(UP)樹脂系統(順丁烯二酸-1,2丙二醇-鄰苯二甲酸酐)，其在聚合固化後之體積收縮性、內部染色性及機械性質的影響。實驗結果，吾人將以苯乙烯/不飽和聚酯/抗收縮劑三成份之相特性、樣品破壞面之微觀結構及聚合固化過程中所產生之微孔洞體積分率等因素加以解釋之。

Abstract
The effect of nine acrylate-based low profile additives (LPA) with different chemical structure and molecular weight on the volume shrinkage characteristic and internal pigmentability and mechanical properties for the low-shrink unsaturated polyester resin (UP) after the cure were investigated .The experimental results have been explained by phase characteristics of the ternary styrene/UP/LPA system , cured sample morphology , and the volume fraction of microvoid formation during the cure .
(Keywords : low-profile additives (LPA) ; unsaturated polyester resin (UP) ; volume shrinkage;pigmentability ; mechanical properties)

目 錄
中文摘要………………………………………………………I
英文摘要…………………………………….………………..II
感謝…………………………………….…………………….III
圖表索引………………………………..…………………….IV
第一章 緒論…………………………………………………1
第二章 文獻回顧……………………………………………3
2-1 不飽和聚酯樹脂與苯乙烯
之交聯共聚合反應3
2-2 低收縮不飽聚酯樹脂
之抗收縮補償機構6
2-3 低收縮不飽和聚酯樹脂系統
聚合固化時之微觀結構研究9
2-4 抗收縮劑對UP樹脂硬化後
體積收縮影響之研究11
2-5 抗收縮劑對UP樹脂硬化後
內部染色性影響之研究 13
2-6 不飽和聚酯硬化後
的機械性質研究………………….…………..15
　2-6-1 純粹不飽和聚酯樹脂
系統之機械性質…………………..……15
　2-6-2 加入LPA之聚酯樹脂
系統的機械性質………………….…….16
第三章 實驗方法與設備……………………..……..19
3-1 原料…………………………………………….19
3-2 實驗儀器……………………………………….21
3-3 實驗步驟……………………………………….28
3-3-1 體積變化之量測………………………..28
3-3-2 內部染色性之量測……………………..33
3-3-3 光學顯微鏡及影像分析
微孔洞體積分率……………………….33
3-3-4 機械性質之量測………………………..34
第四章 結果與討論…………………………………..36
4-1 UP與LPA之分子極性……………………………36
4-2 體積收縮特性……………………………………….38
4-3 內部染色性………………………………………….67
4-5 SEM下之微觀結構…………………………………. 42
4-5 苯乙烯/不飽和聚酯/抗收縮劑之相溶性、
反應動力、微觀結構、體積收縮
與內部染色性之相互關係…………..………..87
4-6 耐衝擊強度………………………………………….100
4-7 抗張性質………………………………………….. ..104
4-8 動態機械性質……………………………………. ..112
第五章 結論……………………………………………..…130
參考文獻……………..………………………………………174

參考文獻
1.E.J. Bartkus and C.H. Kroekel, Appl, Polym. Symp. ,15, 113 (1970)
2.K.E. Atkins, in”Sheet Molding Compound:Science and Technology”. Ed., H.G. Kia, Hanser Publishers, New York, 1993, Ch.4.
3.V.A. Pattison, R.R. Hindersinn and W.T. Schwartz, J. Appl. Polym. Sci., 18,2763 (1974)
4.V.A. Pattison, R.R. Hindersinn and W.T. Schwartz, J. Appl. Polym. Sci., 19,3045 (1975)
5.L. Suspene, D. Fourquier and Y.S. Yang, Polymer, 32,1593 (1991)
6.C.P. Hsu, M. Kinkelaar, P. Hu and L.J. Lee. Polym. Eng. Sci., 31,1450 (1991)
7.Y.J. Huang and C.M. Liang, Polymer, 37,401 (1996)
8.K.E. Atkins and G.C. Rex. 48th Annual Conference, Composite Institute. SPI, Session 6-D (Feb, 8-11, 1993)
9.K.E. Atkins and G.C. Rex, C.G. Reid, R.L. Seats and R.C. Candy, 47th Annual Conference, Composite Institute, SPI, Session 7-D (Feb, 3-6, 1992)
10.Y.J. Huang and C.C. Su, J. Appl. Polym, Sci., 55, 323 (1995)
11.P.W.K. Lam, Polym, Eng. Sci., 29, 609 (1989)
12.C.B. Bucknall, I.K. Partridge, and M.J. Phillips, Polymer, 32, 786 (1991)
13.M.B.C. Park and F.J. Mcgarry, 48th Annual Conference, Composite Institute, SPI, Session 10-B (Feb, 8-11, 1993)
14.盧天智，碩士論文，台灣工業技術學院，1991
15Y.S.Yang and L.J.Lee, Polymer, 29, 1793 (1988)
16.蘇進成，碩士論文，台灣工業技術學院，1992
17.林立翔，碩士論文，台灣工業技術學院，1992
18.K.E.Atkins, in “Polymer Blends” ed., D.R.Paul and S.Newman, Academic Press, New York, Vol.2.(1978)
19.Y.J.Huang and C.C.Su, J. Appl. Polym. Sci.,55,305(1995)
20.Y.J.Huang and C.C.Su, J. Appl. Polym. Sci.,55,323(1995)
21.Y.J.Huang and C.C.Su, Polymer, 35, 2397 (1994)
22.Y.J.Huang and T.J.Lu and W.Hwu, Polym. Eng. Sci., 33, 1, (1993)
23.T.Mitani, H.Shiraishi, K.Honda and G.E. Owen, 44th Annual Conference Composite Institute, SPI,Session 12-F (Feb.6-9,1989)
24.W.D.Cook and O.Delatycki, J. Polym. Sci., Polym. Phys. Ed., 12, 2111 (1974)
25.W.D.Cook and O.Delatycki, J. Polym. Sci., Polym. Phys. Ed., 12, 1925 (1974)
26.D.W.V. Krevelen, “Properties of Polymers,” 3rd Ed., Elsevier, London, 1990, P.198 and P.292
27.洪肇成，碩士論文，台灣工業技術學院，1994
28.A.W.Snow and J.P.Armi Stead, J.Appl.Polym.Sci., 52,401(1994)
29.L.H.Sperling,”Introduction to physicall Polymer Science”2nd ed.,Wiley, New York, 1992, p.337
30.T.A.Osswald, E.M.Sun, and S.C.Tseng, 49th Annual Conference, Composite Insititute, SPI Inc.,5B, 1994.
31.Perry and Chilion, ”Chemical Engineering’ Handbook”, 5th ed., McGraw Hill, New York, p.3-227(1973)
32.E.A.Grulke,”Polymer Process Engineering” Prentice Hall, Englewood Cliggs,(1994) P.613
33.陳立德，碩士論文，台灣工業技術學院，1996。
34.董志平，碩士論文，台灣工業技術學院，1997。
35.E.Riande and E.Saiz, in “Dipole Moments and Birefringena of Polymers”, Chap.2, Prentice Hall, Englewood Cliffs, New Jersey, 1992
36.D.W.Krevelen, in “Properties of Polymers” 3rd. Ed., Elsevier, London, Chap.11 P.323. and Chap.7, P.198
37.何慶春，碩士論文，台灣工業技術學院，1996。
38. Y. J. Huang and J. C. Horng, Polymer, 39, 3683 (1998)
39.朱正九，碩士論文，台灣工業技術學院，1997。
40.陳立德，碩士論文，台灣工業技術學院，1996。
41.Y. J. Huang and W. C. Jiang, Polymer, Accepted, 1998
42. Y. J. Huang and L. D. Jiang, Polymer, Accepted, 1998
43.S. Nonaka, K. Hamada, S. Tonogai and H. Yamada,”The Relationship between Diameter of Dispersed LPA Particles and Color-Uniformity”. International Composites Expo`98 Proceedings, Session 5-B (Jan.19~21,1998)