臺灣博碩士論文加值系統

本論文分成兩個部分：第一部份主要利用釕金屬錯合物催化碳-碳參鍵的斷裂反應；第二部分則是研究相同釕金屬錯合物可催化α,β-環氧酮類化合物重排至1,2-二酮類化合物。
第一部份利用釕金屬錯合物作為碳-碳鍵斷裂反應的催化劑，尤其是催化碳-碳三鍵斷裂反應，可以提供有效且又快速的方法，並可改善以往文獻中，其反應是劑量反應，或者是必須加入有機促進劑才可以進行碳-碳三鍵的斷裂反應。
第二部分我們以相同的釕金屬錯合物TpRu(PPh3)(CH3CN)2PF6催化α, β-環氧酮類化合物，發現該催化劑具有好的路徑選擇性，只獲得唯一的1,2-二酮類化合物，並且也有極佳的官能基容忍性，能容忍不同官能基同時存在，更重要的是利用此方法來合成1,2-二酮化合物具有極高的原子經濟效益，因為在合成的過程中，沒有任何的原子損耗，且又是利用催化的系統，因此在合成的應用上具有研究的價值。

摘 要 I
謝 誌 II
目 錄 III
圖 目 錄 VII
附表目錄 X
附錄目錄 XI
縮寫對照表 XVII

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