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研究生:梁啟嵩
研究生(外文):ChiSung Liang
論文名稱:亞洲沙塵暴對台灣都會區氣膠特性之研究
論文名稱(外文):Source Apportionment of Submicron Particle Size Distribution and PM2.5 Composition during an Asian Dust Storm Period in Two Urban Atmospheres
指導教授:林文印林文印引用關係
指導教授(外文):WenYinn Lin
口試委員:章裕民余泰毅張艮輝陳志傑
口試日期:2016-04-12
學位類別:博士
校院名稱:國立臺北科技大學
系所名稱:工程學院工程科技博士班
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:2016
畢業學年度:104
語文別:英文
中文關鍵詞:亞洲沙塵暴、主成份分析、氣膠粒徑分佈
外文關鍵詞:Asian dust storm; principal component analysis; aerosol size distribution
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  • 被引用被引用:1
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亞洲沙塵暴從大陸及蒙古的沙漠地區吹來台灣,是造成台灣地區空氣品質惡化之原因之一,尤其大陸沙塵常隨東北季風並夾帶城市中的污染物傳輸至台灣,並與台灣當地的污染物混合,造成空氣中懸浮微粒濃度遽升,對於人體呼吸道影響很大。本研究將針對台北及高雄都會區來探討亞洲沙塵暴對於都會氣膠特性的影響。於2009年亞洲沙塵暴期間台北及高雄PM10的小時平均值分別遽升至800 μg m-3、400 μg m-3,濃度為一般事件日的五倍,是歷年來沙塵暴較嚴重事件日。
本研究以主成份分析方法(Principal component analysis)確認亞洲沙塵暴期間及非沙塵暴期間可能的污染源,分析的項目包含微粒數目濃度、粒徑分佈、氣體污染物及PM2.5化學成份。分析結果發現次微米以下的粒徑分佈約可區分為nucleation mode (10-30 nm)、Aitken mode (30-100 nm)和accumulation mode (0.1-1μm),可提供作為可能污染源的特性參考。並使用Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT)軌跡模式分析結果發現,此次亞洲沙塵暴從蒙古地區沿中國沿海工業地區傳送至台灣。沙塵暴期間台北及高雄都會區的主要污染源有移動污染源、nucleation及沙塵微粒。非沙塵及高污染事件日期間台北及高雄都會區的主要污染源有移動污染源及道路揚塵。
研究結果也顯示Aitken mode和accumulation mode與沙塵暴的相關性並不顯著。nucleation mode於沙塵暴及飛沙塵暴期間皆有出現,可能的污染源還是以當地露天燃燒或移動污染源排放為主。主成份分析結果結合氣象資料及逆軌跡模式判定,可有效地確認沙塵暴期間可能污染物的來源。
Chapter 1 Introduction................................1
1.1 Background......................................1
1.2 Objectives and Scope............................4
Chapter 2 Literature Review...........................6
2.1 Properties of Asian dust storm....................6
2.1.1 Causes of Asian dust storm......................7
2.1.2 Sources and Composition of Asian dust storm.... 8
2.1.3 The effect of Asian dust storm on health....... 13
2.2 Properties of urban aerosol.......................16
2.2.1 Sources of urban aerosol........................17
2.2.2 Composition of urban aerosol....................18
2.2.3 Size distribution of urban aerosol..............19
2.3 Principal component analysis......................22
2.3.1 Principal component analysis (non-rotation).....22
2.3.2 Factor analysis.................................25
2.4 Application of HYSPLIT Trajectory Model...........28
Chapter 3 Experimental Methods........................30
3.1 Supersites database...............................30
3.1.1 Supersites Locations............................31
3.1.2 Supersites measurement and Instruments..........32
3.2 Data analysis.....................................34
3.3 HYSPLIT back trajectory analysis..................37
Chapter 4 Results and Discussion......................41
4.1 Data description..................................41
4.2 Sources Apportionment during ADS periods..........46
4.3 Sources Apportionment during non-ADS periods......55
4.4 Sources Apportionment during PM episode...........56
Chapter 5 Conclusions.................................60
References..............................................62
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