臺灣博碩士論文加值系統

本論文主旨是設計以二苯并[a, c]二氮蒽為中心結構經由將酸基的置換形成醯胺進而使得盤型分子具備氫鍵作用力。藉由偏光顯微鏡、微差掃描熱卡計以及X光粉末繞射儀對該系列分子進行鑑定，並探討氫鍵作用力的有無對盤形液晶分子排列上的差異。
此外也設計以二苯并[a, c]二氮蒽酸與胺類形成離子液晶，探討離子鍵是否會對盤型液晶分子造成排列堆疊上的影響。

We have synthesized the derivative of dibenzo[a,c]phenazine acid as a exchange form acid to amide. In order to discuss the difference between the presence of the hydrogen bonding interaction, POM, DSC, and XRD are used to confirm the self-assembly packing of the derivatives.
In addition, we make use of dibenzo[a,c]phenazine acid and some certain kinds of amine to form ionic liquid cyrstal, and the properties of ionic bonds that influence self-assemble packing are also mentioned in this thesis as well.

目錄
審定書 i
謝誌 ii
中文摘要 iv
英文摘要 v
圖目錄 viii
表目錄 xiv
第一章 1
1-1 前言 1
1-2 液晶簡介 2
1-3 分子形成液晶相須具備的條件 4
1-4 液晶的種類 5
1-5 盤狀液晶論文回顧 15
1-6 氫鍵對液晶排列的影響 25
1-7 盤狀液晶的應用與價值 28
第二章 實驗儀器及其原理 31
2-1 實驗儀器及藥品 31
2-2 液晶向的鑑定以及儀器的原理 33
2-3 以X光粉末繞射鑑定管柱液晶相 37
第三章 研究與結果(amide series) 41
3-1 研究動機 41
3-4-1 C6-C12+amide 51
3-4-2 C6-C12+methyl 60
3-4-3 C6-C12+butyl 65
3-4-3 C6-C12+hexyl 70
3-4-4 C6-C12+octyl 75
3-4-5 C6-C12+isopropyl 79
3-4-7 C6-C12+diisopropyl 84
3-5 綜合討論 89
第四章 研究與結果討論 92
4-1 研究動機 92
4-2 合成策略 92
4-3 實驗流程 93
4-4 性質探討 95
4-4-1 C6-C10+methyl(salt) 95
4-4-2 C6-C10+butyl(salt) 100
4-4-3 C6-C10+isopropyl(salt) 105
4-4-4 C6-C10+diisopropyl(salt) 110
4-5 綜合討論 116
第五章 實驗步驟 119
5-1 儀器設備 119
5-2 藥品與溶劑 120
5-3 過程 120
5-4 實驗步驟 121
第六章 附錄 151
參考資料 191

1.F. Reinizerr, Monatshefte fur Chemie. 1888, 9, 421.
2.Lehmann, Physik. Chem. 1889, 7, 486.
3.S. Chandrasekhar, B. K. Sadashiva, K. A. Suresh, Pramana, 1977, 9,
471.
4.M. Levelut, J. Physique Lett.,1979, 40, 81-84.
5.R. J. Bushby, O. R. Lozman, Current Opinion in Colloid &; Interface Science , 2002, 7, 343-354.
6.S. Kumar, Chem. Soc. Rev., 2006, 35, 83-109
7.Kirill V. Axenov * and Sabine Laschat *, Materials., 2011, 4, 206-259
8.S. Kumar, Chem. Soc. Rev., 2006, 35, 83-109.
9.J. Billard, J. C. Dubois, N. H. Tinh and A. Zann, Nouv. J. Chim., 1978,
2, 535.
10.S. Kumar, Liq. Cryst., 2004, 31, 1037-1059.
11.S. J. Cross, J. W. Goodby, A. W. Hall, M. Hird , S. M. Kelly, K. J. Toyne, C. Wu, Liq. Cryst., 1998, 25, 1-11.
12.(a) V. E. Williams, E. J. Foster, J. Babuin, N. Nguyen, Chem. Commun., 2004, 18, 2052-2053.(b) V. E. Williams, E. J. Foster, C. Lavigueur, Y. C. Ke, J. Mater. Chem., 2005, 15, 4062-4068.
13.(a)C. W. Ong, C. Y. Hwang, M. C. Tzeng, S. C. Liao, H. F. Hsu, T. H. Chang, J. Mater. Chem, 2007,17, 1785-1790.(b) C. W. Ong, C. Y. Hwang, S. C. Liao, C. H. Pan, T. H. Chang, J. Mater. Chem., 2009, 19, 5149 -5154.
14.國立中山大學化學研究所中華民國九十五年黃嘉瑜之碩士論文
15.T. Kato, J. M. J. Frchet, J. Am. Chem. Soc., 1989, 111, 8533 –8534.
16.M.-J. Brienne, J. Gabard, J.-M. Lehn, I. Stibor, J. Chem. Soc.Chem. Commun. 1989, 1868 – 1870.
17.M.-J. Brienne, J. Gabard, J.-M. Lehn, I. Stibor, J. Chem. Soc.Chem. Commun. 1989, 1868–1870.
18.R. Kleppinger, C. P. Lillya, C. Yang, Angew. Chem. 1995, 107,1762 – 1764; Angew. Chem. Int. Ed. Engl. 1995, 34, 1637 – 1638.
19.M. SuTrez, J.-M. Lehn, S. C. Zimmerman, A. Skoulios, B.
Heinrich, J. Am. Chem. Soc. 1998, 120, 9526 – 9532.
20.Foster, E. J.; Babuin, J.; Nguyen, N. and Williams,V.E.,Chem .Commun., 2004,2052–2053
21.Voisin,E.; Foster,E. J.; Rakotomalala,M. and Williams,V. E.Chem. Mater.2009, 21, 3251–3261
22.L. Zhou, Z. L.; Weber, E.; Keana, J. F. W. Tetrahedron Lett., 1995, 36, l7583-7586.
23.B. Mohr, V. Enkelmann, G. Wegner. J. Org. Chem.,1994, 59, 635
24.B. Halton, A. I. Maidment, D. L. Officer, J. M. Warnes, Aust. J. Chem.,1984, 37, 2119.
25.Ma, J. C.; Dougherty, D. Chem. Rev. 1997, 97, 1303.
26.Elmsley, J. Chem. Soc. Rev. 1980, 9, 91.
27.Hunter, C. A.; Sanders, J. K. M. J. Am. Chem. Soc. 1990, 112,5525.
28.Kim, E.; Paliwal, S.; Wilcox, C. S. J. Am. Chem. Soc. 1998, 120,11192.
29.Duncan W. Bruce, J. Am. Chem. Soc. 2004, 126, 15258