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研究生:蔡政宏
研究生(外文):TSAI, CHEN-HUNG
論文名稱:氧化鋁/鎳鋁複合材料之機械性質研究
論文名稱(外文):Mechanical properties of Al2O3/NiAl composite
指導教授:單秋成單秋成引用關係
指導教授(外文):BIN-JUINE HUANG
學位類別:碩士
校院名稱:國立臺灣大學
系所名稱:機械工程學系
學門:工程學門
學類:機械工程學類
論文種類:學術論文
論文出版年:1997
畢業學年度:85
語文別:中文
論文頁數:94
中文關鍵詞:機械性質彎曲強度斷裂韌性
外文關鍵詞:Al2O3/NiAlmetallic compounds
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結構陶瓷(又稱工程陶瓷)是一種新興的材料,與結構用金屬材料比較
,結構陶瓷具有許多較佳的物理性質與機械性質,包括低密度、低的熱膨
脹係數、低熱傳導係數,與極高的楊氏係數、高硬度、高壓縮強度、耐腐
蝕、抗氧化及潛變等等。但是,陶瓷材料的高脆性,也降低了其在工程上
的實用性。 氧化鋁是典型的陶瓷材料,它擁有高強度、耐腐蝕、抗氧
化等優點,但也存在低韌性之缺點,添加第二相韌化劑可同時改善其強度
與韌性。例如加入金屬顆粒可提高其斷裂韌性,但卻會降低其原有之抗氧
化能力與質輕的優點。因此,如何選擇一種第二相成份的加入,能夠改善
材料缺點,而又不失原有之優點,成為研究材料者努力的目標。 有鑑
於NiAl介金屬化合物有著低密度,高熱傳導性與優異之抗氧化能力,所以
在本研究中,選擇以NiAl做為第二相韌化劑。試樣之製備是以不同體積比
例之NiAl顆粒,均勻加入氧化鋁粉末中,以乾壓法壓製生胚,並在常壓Ar
氣氛下將生胚以1500℃進行燒結。 燒結完成後的試樣,經研磨加工後
,用以進行以下實驗,包括:XRD相鑑定、室溫機械性質與物理性質測試(
密度測試、彎曲強度、斷裂韌性)、不同溫度與時間對不同體積比例試樣
進行高溫氧化後,材料之強度與韌性、以及不同體積比例的複合材料之熱
衝擊特性等,並由觀察試樣之微結構,來探討影響其強度與韌性的原因。
同時,由於陶瓷材料的製程繁瑣,加工耗時,故我們想出利用試驗過後的
剩餘材料,兩端黏上其他材料,使能重新做測試的方法,期能用最少的加
工,使陶瓷材料得以反覆進行測試。並將測試結果與標準試片之測試結果
做一比較。 關鍵詞:斷裂韌性,NiAl介金屬化合物,機械性質

Structural ceramic (also named Engineering ceramic) is a
newly developedmaterial. Compared with metal for structure, it
demonstrates manyexcellent physical and mechanical properties.
Such as low density, lowcoefficient of expansion,low heat
transfer coefficient, high Young'smodulus, high hardness, high
compress strength, and good corrosion, oxidization,and creep
resistance. Howrver, extreme brittleness is the primany
obstacleto its application in engineering. Alumina is the
typical material of ceramic. It is execellent for its high
srengthand good ability to resist corrosion and oxidization.
However,alumina alsopossess the weakness of low toughness.By
adding reinforcement, its strengthand toughness can be improved.
For example, the fracturetoughness can be increased by adding
the metallic reinforcement. However, theoxidization resistance
and the property of low density will be sacrificed.Therefore, it
will be a target for researchers to choose areinforcement that
will improve the weaknesses of the material and keep
itselementary properties at the same time. Owing to its low
density,easy to conduct heat, and excellent oxidization
resistance,NiAl is chosen as a reinforcement in this study. To
make a sample, we add NiAl particleinto alumina matrix evenly,
from the mixed powder into the initial sample bydie-pressing
method, and then sinter it in argon atmosphere at 1500℃.
After sintering and milling, we proceed the following
experiments: phase identificatinoby X-ray, measurement of
mechanical and physical properties (including density,flexural
strength, and fracture toughness)in room temperature, strength
and toughnessof the samples after oxidization, and properties of
the composite after thermalshock. By observing the
microstructure of the samples, We tempt to find out thecauses
that effect strength and toughness of the composit. Because
of the complexity of making ceramic materials and time
consumingprocess, we try to use the remaining material with
other materials glued toboth ends to reduced the processing time
and procedure.Thus, we can reusethe material and conduct the
experiments repeatedly. Meanwhile, we comparethe data with that
we got from experiment by standard sample. key words:fracture
toughness, NiAl metallic compound ,methanical properties,

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