臺灣博碩士論文加值系統

　　在高溫高壓的水合熱裂條件下甲菲異構物已被證實可裂解生成菲，而部分異構物間也可以相互轉換，其中2-甲菲和9-甲菲間有相當高的互換比例。比較2-甲菲和9-甲菲在輕水及重水中的水合熱裂反應，發現2-甲菲及9-甲菲在280℃、3 天利用重水進行的水合熱裂條件中有顯著相互轉換的跡象，且至少有二個2-甲菲或9-甲菲分子內的氫被氘置換。而在較高溫度的條件下無論是在輕水或重水中，2-甲菲和9-甲菲互換比例明顯降低，反而菲及其他化合物如茀酮等有增加的趨勢，在350oC 時則無法偵測2-甲菲和9-甲菲互換的結果。2-甲菲與9-甲菲水合熱裂過程中可能的反應機制也在本文中一併被討論。

　Hydrous pyrolysis of methylphenanthrenes under high temperature and high pressure condition has been proof to generate phenanthrene and 9-fluorenone. In additon, an abnormal high isomerization interchange ratio was found in the cases of 2-methylphenanthrene and 9-methylphenanthrene.Thus Intensively studies of hydrous pyrolysis 2-methylphenanthrene and 9-methylphenanthrene were carried in
either light or heavy water. The results indicated that hydrous pyrolysis in heavy water at 280oC, for 3 days has the highest transformation ratio between 2 methylphenanthrene and 9-methylphenanthrene which in corporation with that two hydrogen atoms has been exchanged with deuterium atoms.
The isomerization ratio of methylphenanthrenes was decreased in higher pyrolysis temperature in contrast of that the yields of both phenanthrene and 9-fluorenone were increased. The mechanism of isomerization between 2-methylphenanthrene and
9-methylphenanthrene was also proposed.

目錄
中文摘要...............................................................i
Abstract..............................................................ii
圖目錄.................................................................v
表目錄................................................................vii
第一章 緒論.............................................................1
一、引言................................................................1
二、生物遺體在沉積埋藏中的變化..........................................3
三、有機富集度..........................................................4
四、油母質..............................................................5
五、熱成熟作用..........................................................8
六、熱成熟度參數.......................................................10
七、水合熱裂...........................................................17
八、研究目的...........................................................19
第二章 實驗............................................................23
一、實驗藥品...........................................................23
二、實驗儀器...........................................................24
三、儀器分析...........................................................25
四、實驗步驟...........................................................26
第三章 結果與討論......................................................29
一、2-甲菲的水合熱裂...................................................29
二、9-甲菲的水合熱裂...................................................31
三、利用水與重水進行水合熱裂的比較.....................................34
四、溫度對水合熱裂結果的影響...........................................38
五、於重水中進行水合熱裂的氘交換反應...................................41
第四章 參考文獻........................................................47
附錄...................................................................48

黃得時, 丁穌華, 洪長谷, 黃春鶯, 周次雄, 吳素慧, 陳德權, 台灣石油地質, 民國80 年, 第26 號, 第109-120 頁
盧廣郎, 石油季刊, 民國70年, 第17 卷, 第2 期, 第49-67 頁
Lewan M. D., Winter J. C. and Mc Donald J. H., Science, 1979, 203, 897-899
Mackenzie A. S. and Mckenzic D. Geological Magazine, 1983, 120, 417-428
Radke, M., Mar. Petrol. Geol., 1988, 5, 224-236
Radke, M., Helmut, W. and Welte, D. H. Anal. Chem., 1984, 56, 2538-2546
Radke, M., Helmut, W. and Welte, D. H. Geochim. Cosmochim. Acta, 1982, 46, 1-10
Radke M., Helmut, W. and Welte, D. H. Org. Geochem., 1986, 11, 51-63
Tissot B. P. and Welte D. H. Petroleum Formation and Occurrence.1978
Peters K. E. and Moldowan J. M., THE BIOMARKER GUIDE
Interpreting Molecular Fossils im Petroleum and Ancient Sediments, 1993