臺灣博碩士論文加值系統

本研究透過實驗設計法(Design of Experiment, DOE)與變異數分析(Analysis of Variance, ANOVA)尋求高性能複合光觸媒，有機化合物之相對最佳化操作配比。五個控制因子包括光觸媒種類、光觸媒濃度、載體種類、熱處理溫度及攪拌轉速等，分別設定4個水準。本研究應用L16直交表實驗配置及ANOVA再驗證分析發現提高吸附與光分解的效率之參數。二組參數設定顯示相似的最佳組合，其中載體種類扮演最重要的貢獻，去影響吸附與光分解作用的能力。這被歸因於載體中巨大的毛孔結構，可能引導均質分散的光觸媒，因而促進光分解作用的能力。這ANOVA結果証實，實驗的可信度和合理的變異等二者信心水準區間落在99%內，指出穩健複合光觸媒的設計。基於經濟和穩健設計觀點，複合型光觸媒的製備中，變異參數組透過ANOVA和DOE方法學提供一個有效率方法，不僅在提升吸附和光分解能力亦是最佳控制因素。

The objective of this research is to obtain an optimal combination on improving the adsorption/photocatalysis capability of composite photocatalysts by means of design of experiments (DOE) and analysis of variance (ANOVA). Five control factors, including photocatalyst type, catalyst loading, support type, heat-treated temperature, and stirring speed, with four levels were considered to investigate the optimal parameter setting. The present work applied an L16 orthogonal array combined with ANOVA analysis to individually find out their improved parameters: adsorption and photocatalysis efficiencies. Two sets of parameter settings appeared a similar optimal combination, in which the type of support acts as the most crucial contribution to affect both of adsorption and photocatalysis capabilities. This can be attributed to the fact that vast pore structure of supports probably leads to uniform dispersion of catalysts, thus promoting the photocatalysis capability. The ANOVA result also confirmed that both the reliability of experiments and rationality of variances fall within a confidence level of 99%, indicating the robust design for these composite photocatalysts. The parameter settings via ANOVA and DOE methodologies provide an efficient approach not only in enhancing the adsorption/photocatalysis hybrid performance but also tuning the optimal controlling factors for preparation of the composite photocatalysts, based on economic and robust-design viewpoints.

第一章 緒論 1
1.1 研究背景 1
1.2 研究動機 3
1.3 研究目的 4
1.4 研究範圍 5
1.5 研究限制 5
1.6 研究方法 5
1.7 研究流程 7
第二章 奈米複合材吸附理論與應用之回顧 9
2.1奈米材料之特性 9
2.1.1奈米及複合材料之定義 9
2.1.2奈米材料與碳材吸附 10
2.2 吸附之定義與理論 10
2.2.1 吸附之定義 10
2.2.2 吸附原理 10
2.2.3 吸附理論 12
2.2.4吸附之種類 18
2.3碳材吸附之應用 19
2.3.1 液相吸附過程 20
2.3.2以奈米碳管為載體之製備技術 20
2.3.3以活性碳為載體之製備技術 22
2.3.4以氧化鋁為載體之製備技術 25
2.3.5 以竹炭為載體之製備技術 28
第三章 光觸媒光分解發展之應用 32
3.1奈米光觸媒之回顧 32
3.1.1光觸媒之定義 32
3.1.2 光觸媒反應之原理: 34
3.1.3 光觸媒基本特性 35
3.2 光觸媒應用範圍 36
3.3 建材導入光觸媒材料之應用現況及趨勢 38
3.4 小結 40
第四章 研究方法之分析 41
4.1 傳統實驗設計之分析 41
4.1.1實驗設計之概述 41
4.1.2實驗設計的意義及類型 41
4.1.3實驗設計法之分類 42
4.2 田口式品質工程之分析 44
4.2.1田口式品質工程基本概念 44
4.2.2傳統實驗設計與田口方法之比較 44
4.3實驗計畫法之選定分析 49
4.4田口式穩健設計與其他實驗設計法交叉驗證 53
4.4.1 信號雜音比 53
4.4.2 變異數分析 54
4.4.3再驗證實驗 56
第五章 實驗計畫 58
5.1 實驗目的 58
5.2 實驗計畫配置 58
5.2.1 理想機能品質特性、控制因子選定與因子水準設定 58
5.2.2 特性要因與實驗配置 61
5.2.3 實驗配置、直交表選定與水準設定 65
5.3 實驗儀器特性分析 66
5.3.1 實驗儀器 66
5.3.2 特性分析 70
5.4 實驗藥品 75
5.4.1藥品 75
5.4.2氣體 80
5.5 實驗方法與流程 82
5.5.1 實驗方法 82
5.5.2實驗流程 82
5.6實際操作 85
5.6.1複合型光觸媒的製備 85
5.6.2液相吸附和光分解 85
5.7 複合型光觸媒吸附與光分解量測與數據彙整 85
5.7.1複合型光觸媒光分解量測與數據彙整 85
5.7.2 複合型光觸媒吸附量測與數據彙整 88
5.7.3 複合型光觸媒吸附加光分解量測與數據彙整 90
第六章 實驗結果討論、分析與驗證 92
6.1複合型光觸媒的表面特性及光催化作用 92
6.1.1複合型光觸媒的表面特性 92
6.1.2 複合型光觸媒的光催化作用 95
6.2 複合型光觸媒吸附與光分解有機污染物質之結果討論 96
6.2.1 光分解有機污染物質之討論 96
6.2.2 吸附有機污染物質之討論 102
6.2.3 吸附與光分解有機污染物質之討論 107
6.3 預估最佳配比組合 112
6.3.1預估最佳配比之討論 112
6.3.2預估最佳配比之組合 114
6.4 變異數分析驗證 116
6.4.1 變異數分析光分解效率 116
6.4.2 變異數分析吸附效率 117
6.4.3 變異數分析光分解加吸附效率 118
6.5 再驗證實驗 119
6.6最佳參數建立之結論 121
6.7工程應用的意義 122
第七章 結論、建議與貢獻 124
7.1 結論 124
7.2 建議 126
7.3 貢獻 126
參考文獻 127
附錄：本研究相關之學術論文 136

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