臺灣博碩士論文加值系統

本研究採用靜態式液相循環的相平衡裝置，量測乙酸乙酯+ 碳酸二乙酯、乙酸乙酯 + 碳酸二苯酯、碳酸二乙酯 + 碳酸二苯酯、乙酸苯酯 + 碳酸二苯酯在373.15 K、413.15 K及453.15 K溫度下的雙成分混合物之汽液相平衡，以及乙酸乙酯 + 乙酸苯酯、碳酸二乙酯 + 乙酸苯酯在373.15K溫度下的雙成分混合物之汽液相平衡，實驗結果顯示每組雙成分系統皆無共沸物產生，且均是正偏差。所量取之雙成分汽液相平衡數據的熱力學一致性均分別以逐點法、面積法與無限稀釋法確認。本實驗所測得之系統分別以Wilson-HOC，NRTL-HOC以及UNIQUAC-HOC模式關聯，每一種模式均能獲得令人滿意的結果。

A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of ethyl acetate + diethyl carbonate, ethyl acetate + diphenyl carbonate, diethyl carbonate + diphenyl carbonate and phenyl acetate + diphenyl carbonate at 373.15 K, 413.15 K, and 453.15 K. And also measured the binary systems of ethyl acetate + phenyl acetate, and diethyl carbonate + phenyl acetate at 373.15K.The experimental results exhibit no azeotropic behavior and positive deviations from Raoult’s lawfor each binary system. The thermodynamic consistency of the new binary VLE data has been confirmed by the point, area, and infinite dilution tests. The Wilson-HOC, the NRTL-HOC, and the UNIQUAC-HOC models were used to correlate each binary system measured in this work.Each model yielded satisfactory results.

摘要 I
Abstract II
誌謝 III
目錄 V
表目錄 VIII
圖目錄 XI
第一章 緒論 1
1-1 前言 1
1-2 研究動機與背景 2
1-3 研究目的 8
1-4 相平衡 10
1-5 汽液相平衡量測 12
1-6 本文各章的重點 14
第二章 汽液相平衡量測 17
2-1 汽液相平衡量測裝置之主要設備 17
2-2 實驗裝置 20
2-2-1 主要裝置之除氣與進料系統 21
2-2-2 主要裝置之平衡系統 22
2-2-3 主要裝置之取樣與組成分析系統 22
2-2-4 簡易裝置之除氣與進料系統 23
2-2-5 簡易裝置之平衡系統 23
2-3 待測系統與藥品 24
2-4 實驗程序 26
2-4-1 主要裝置之樣品及系統前置操作步驟 26
2-4-2 主要裝置之樣品進料操作步驟 26
2-4-3 主要裝置之汽相取樣分析步驟 27
2-4-4 主要裝置之液相取樣分析步驟 28
2-4-5 簡易裝置之操作步驟 29
2-5 量測系統之測試 30
2-6 氣相層析儀之校正曲線 30
2-7 飽和蒸汽壓之量測 31
2-8 雙成分混合物系統之量測結果 31
第三章 相平衡研究之模式關聯 81
3-1 熱力學一致性測試 81
3-1-1 Gibbs-Duhem 方程式 83
3-1-2 熱力學一致性測試法 84
3-1-3 熱力學一致性測試結果 87
3-2 汽液相平衡之計算 87
3-3 實驗數據之關聯 88
第四章 結論與建議 139
4-1 結論 139
4-2 建議 141
參考文獻 143
附錄A 符號說明 147
附錄B 藥品之分子式與結構式 151
附錄C 程式之計算示意圖 152

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