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研究生:洪妙珠
論文名稱:陽性澱粉添加量與辦公室回收廢紙漿含量對中性造紙及紙張性質之影響
論文名稱(外文):Effect of cationic starches and mixed office wastepaper pulp contents on the retention and the handsheet properties in the neutral papermaking system
指導教授:王秀華王秀華引用關係
學位類別:碩士
校院名稱:國立屏東科技大學
系所名稱:森林系
學門:農業科學學門
學類:林業學類
論文種類:學術論文
論文出版年:2003
畢業學年度:91
語文別:中文
論文頁數:129
中文關鍵詞:陽性澱粉中性抄紙留存紙張性質上膠度
外文關鍵詞:cationic starchneutral papermakingretentionpaper propertiessize fastness
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回收纖維之使用為部分漿料早已成為漿紙工業之大勢所趨。為改善回收纖維在回收處理過程中不可避免地有所降低纖維強度,常藉澱粉之添加以改善之,其中又以陽性澱粉最佔優勢。於現今主流的中鹼性抄紙系統中,如何使用部分辦公室回收廢紙漿,在不同的上膠劑量下檢視其與陽性澱粉添加量對漿料纖細物留存及紙品性質之影響如何,為本研究之主要目的。
實驗結果顯示,原生漿與含有辦公室回收廢紙漿者之上膠度隨AKD上膠劑與陽性澱粉之增量而增加。不論AKD之添加量若干,陽性馬鈴薯澱粉之上膠效果皆優於陽性樹薯澱粉者。上膠度之優劣及陽性澱粉用量受AKD之添加量支配。辦公室回收廢紙漿含量愈多,上膠度愈差。
抄紙前,辦公室回收廢紙漿先經打漿處理,可得較佳之紙張強度性質。紙張之破裂指數與抗張指數皆隨澱粉之增量而改善。由於辦公室回收廢紙漿之長度分佈優於LBKP者,紙力隨辦公室回收廢紙漿之增量反而增加。
添加陽性馬鈴薯澱粉時漿料之總留存率與纖細物留存率分別在97%與90%以上;自行轉化陽性樹薯澱粉之效果則分別為90%與70%以上。隨著陽性澱粉添加量之增加,留存反差。添加陽性馬鈴薯澱粉時,漿料之比電荷密度隨陽性澱粉添加量之增加而有較敏銳之變化,本研究設計之添加系統使抄紙前之紙料電荷量近等電點,顯示添加順序之正確性。
Using recycled fiber as part of the stuff for papermaking has been a necessity. The application of recycled fiber, however, would affect the final strength properties of the products due to the drying and rewetting of the fibers. Starch, especially cationic starch was thus used to mitigate the defect. The objectives of this study are to evaluate the effect of the cationic starch dosage and the adoption of recycled mixed office waste (MOW) fiber on the retention and handsheet properties in the currently mainstreamed neutral papermaking system.
The results showed that the size fastness increased with increasing AKD and cationic starch dosages no matter MOW fibers were added or not. The cationic potato starch showed better size fastness than that of cationic tapioca starch. The size fastness was controlled by AKD and cationic starch dosage, and decreased with increasing charge of MOW pulp.
The strength of MOW recycled fiber was improved by an appropriate beating to a CSF of 280ml. The burst and tensile indices of the handsheet were improved with the addition of cationic starch. The strength of handsheet increased with the increasing application of MOW recycled fiber mainly due to its better fiber length distribution than that of the LBKP’s.
The overall first pass retention and first pass fines retention were more than 97% and 90% respectively, with the addition of cationic potato starch. The figures were 90% and 70% respectively for the laboratory modified cationic tapioca starch. The first pass retention decreased with increasing cationic starch dosage, due to over cationic demand. The specific charge density of the stock changed sensitively with the addition of potato starch. The ultimate potential of the stock reached to a near isoelectric point after all the designed additives were applied, showing that the sequence of addition is applicable in the neutral papermaking system.
第壹章、前言
第貳章、文獻回顧
第參章、陽性澱粉添加量與辦公室回收廢紙漿含量對留存及電荷密度之影響
第肆章、陽性澱粉添加量與辦公室回收廢紙漿含量對上膠度之影響
第伍章、陽性澱粉添加量與辦公室回收廢紙漿含量對手抄紙破裂與抗張指數之影響
第陸章、結論
參考文獻
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