臺灣博碩士論文加值系統

　　本研究係將還原碴、水洗焚化飛灰、石灰石污泥、石材污泥和煤灰礦泥拌合料等資材，根據水泥配料之石灰飽和度 (L.S.F)、水硬係數 (H.M.)、矽氧係數 (S.M.)和鋁鐵係數 (I.M.)等水泥係數為邊界條件，以電腦程式配料系統求解聯立方程式來配置七種不同型別之環保水泥，並探討環保水泥漿體之水化特性。實驗結果顯示：所燒製之環保水泥的符合CNS61之規範。而各組環保水泥熟料之單礦物組成皆含有C3S、C2S、C3A及C4AF等晶相物種與波特蘭水泥相當。環保水泥漿體之抗壓強度以EcoA為最佳，添加1%之還原碴有助於提升漿體之早期強度且EcoB水泥漿體於養護齡期為1及3天時，其抗壓強度分別為13.6及21.5 MPa，符合CSN61中輸氣第IIIA型水泥漿體之抗壓強度規範，由凝結試驗結果得知，還原碴中MgO會導致水泥於早期時水化速率增加，使得凝結時間減少進而縮短工作時間，而水洗灰系列因其α-C2S性質的影響使得其水泥漿體凝結時間減緩的現象。
　　由TG-DTA 分析結果顯示，實驗所燒製之七型別環保水泥水化反應皆會生成Ca(OH)2及C-S-H膠體。由MIP分析結果顯示，實驗所燒製之環保水泥漿體孔隙皆有隨養護齡期而有緻密化之趨勢。由SEM觀察結果顯示，隨著養護齡期之增加，環保水泥漿體水化反應所生成之C-S-H膠體逐漸形成絨毛狀態，進而填充孔隙，以提昇其抗壓強度。

The purpose of this study is to co-sinter electric arc furnace reduction slag, washed-fly ash, limestone sludge, stone sludge, and iron-oxide sludge to fabricate 7 types of eco-cement clinkers. The compound raw materials were burned for 2 hours at 1400 °C to form the eco-cement clinkers, all of which met the toxicity characteristic leaching procedure requirements. The results show that the major components of ordinary Portland cement (OPC), C3S, C2S, C3A, and C4AF, were present in the eco-cement clinkers. The strength of EcoA cement paste was similar to that of OPC paste. The compressive strength of EcoB cement paste at the age of 1 and 3 days, are 13.6 MPa and 21.5 MPa, respectively. EcoB cement compliance with CNS 61 air- entrainment cement Type IIIA requirements. Two endothermic peaks, corresponding to weight loss caused by the dehydration of paste and decomposition of C-S-H gel, were observed at 40– 105 °C and 105– 440 °C. The strong endotherm at 440–580 °C was because of the decomposition of Ca(OH)2. According to the MIP results, the total pore size distribution of the pores in the pastes decreased gradually as the ages of curing days increased. The result shows the fact that the dense pastes have been filled by the hydration products. This study shows the possibility that electric arc furnace reduction slag, washed-fly ash, limestone sludge, stone sludge, and iron-oxide sludge can be used. Furthermore, electric arc furnace reduction slag, washed-fly ash, limestone sludge, stone sludge, and iron-oxide sludge have the potential to 100% replace meals as eco-cement materials, and to exhibit favorable mechanical characteristics.

摘要
圖目錄
表目錄
第一章　前言
1-1研究緣起
1-2 研究內容及目的
第二章　文獻回顧
2-1還原碴之來源與特性
2-2 焚化飛灰之來源與特性
2-3 石灰石污泥之來源與特性
2-4 石材污泥之來源與特性
2-5 煤灰礦泥拌合料之來源與特性
2-6 環保水泥
2-7 水泥之製程
2-8 水泥水化反應
2-9廢棄物添加於水泥熟料中對於水泥燒製之影響
第三章　實驗材料與方法
3-1 實驗流程
3-2 實驗材料
3-3 實驗配置
3-4 實驗設備與方法
第四章　結果與討論
4-1 替代性生料之基本性質分析
4-2 生料配比與燒製方法
4-3 熟料基本特性分析
4-4 水泥規範品管檢驗分析
4-5 凝結行為
4-6 抗壓強度發展
4-7各型別環保水泥漿體之DTA/TGA分析
4-8各型別環保水泥漿體之MIP分析
4-9各型別環保水泥漿體之SEM觀察
4-10 綜合討論
4-11 CO2減量評估
第五章 結論與建議
5-1 結論
5-2 建議
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