臺灣博碩士論文加值系統

本研究嘗試以電弧離子鍍技術(Arc Ion Plating, AIP)將類鑽碳(Diamond-like Carbon, DLC)鍍製於聚間苯二甲醯間苯二胺(商標名Nomex)之纖維布料，藉此開發具高比表面積之新型陽極薄膜電極，並探討其在處理染料廢水之可行性評估。研究中分別通入150與250sccm乙炔流量，製備出具有碳源差異之類鑽碳薄膜電極，並以掃描式電子顯微鏡(SEM)、四點探針、雷射顯微拉曼光譜儀(UniRAM-Raman)分析不同薄膜電極特性。降解實驗分別進行背景與降解試驗，以探討薄膜電極對降解染料色度與COD之反應控制參數及成效。
薄膜特性分析得乙炔流量250比150sccm之電阻率高14倍，原因為纖維布料以交織編成，使鍍膜過程無法達到完全披覆效果，且因控制乙炔流量導致薄膜碳源比例不同，其sp2與sp3鍵結比例也不同。
由背景試驗得知染料AB113在不同pH值與溫度下之COD檢測結果皆無明顯差異，但在60℃或酸性環境其色度已分別有10%與50%降解成效，故後續試驗須扣除背景影響得到真正色度去除成效。降解試驗中兩類薄膜在控制電流密度為25mA/cm2皆有40%與80%最大COD與色度去除率，但考量製膜成本則以150sccm作為較佳乙炔控制流量；在酸性環境下分別有62%與93%之更佳COD與色度處理成效，但在鹼性環境其COD與色度去除效率有不降反升的情況，經電解超純水驗證後得知電極薄膜在反應過程會釋放額外碳源且於酸性環境影響較小；在具處理成效之條件下，此新型Nomex/Ti/DLC薄膜電極是具有處理染料廢水之潛力。

In this study, an arc ion plating (AIP) technique was used to deposit diamond-like carbon (DLC) film on a Nomex substrate (Poly(m-phenyleneisophthalamide)), which develop a high specific surface area of the anode electrode film and test the feasibility of dye wastewater treatment. Two differences of carbon sources film electrode are prepared by using the C2H2 flow rate 150 and 250 sccm respectively. By scanning electron microscopy (SEM), four-point probe and laser Raman microscope (UniRAM-Raman) analysis, the electrochemical characteristics of the film electrode are detected. The degradation of color and COD and the effectiveness of the control parameters. Acid Blue 113 are processed.
Resistance of film C2H2 flow rate was 250sccm higher than 150sccm 14 times, the reason for the woven fiber cloth with interwoven that the coating process not be completely drape, and the C2H2 flow control resulting in different proportions carbon film, its sp2 and sp3 bonding different proportions.
In background test of AB113 COD test results in different pH and temperature are no significant difference, but chromaticity has 10% and 50% respectively degradation in 60℃ or acidic environment, so the real influence color removal should be deducted from Background subtraction affected. In degradation tests, two types of films in the current density of 25mA/cm2 have maximum of 40% and 80% COD and color removal, but considering the cost of the membrane as the preferred 150sccm acetylene flow control, and in the acidic environment there are better COD and color treatment performance of 62% and 93%, but in an alkaline environment and its COD and color removal are rise. Ultrapure water electrolysis by the electrode film that has released additional carbon source, and less affected in acidic environment.
Thus, Nomex/Ti/DLC is able to mineralize the dye wastewater and has a potential to further develop a novel AEOP electrode.

誌謝 i
中文摘要 ii
Abstract iii
目錄 v
圖目錄 vii
表目錄 ix
第一章 前言 1
1.1 研究緣起 1
1.2 研究動機與目的 2
第二章 文獻回顧 3
2.1 染料概述 3
2.1.1 染料基本結構與性質 3
2.1.2 偶氮與酸性藍染料特性 7
2.2 染整廢水概述 9
2.2.1染整廢水來源及污染源特性 9
2.2.2 染整廢水影響與管制標準 12
2.2.3染整廢水電化學處理方法 14
2.3電化學氧化概述與應用 18
2.3.1 電化學氧化程序機制與介紹 18
2.3.2各類電極比較 20
2.4類鑽碳膜介紹與製備 24
2.4.1類鑽碳組成 24
2.4.2類鑽碳應用 26
2.4.3電弧離子鍍 29
第三章 研究內容與方法 32
3.1內容與架構 32
3.2電弧離子鍍製備類鑽碳膜 34
3.2.1氣體轟擊 35
3.2.2 Nomex纖維布基材之鈦中介層被覆 35
3.2.3類鑽碳鍍膜之被覆 36
3.3 電化學降解試驗 37
3.3.1背景試驗 37
3.3.2實驗設備 37
3.3.3參數控制 39
3.4分析項目與方法 40
3.4.1薄膜特性分析 40
3.4.2水樣分析 43
第四章 結果與討論 45
4.1類鑽碳薄膜特性分析 45
4.1.1表面特性分析 45
4.1.2電性分析與評估 48
4.1.3化學鍵結分析 49
4.2背景試驗 52
4.2.1薄膜應用於系統之條件測試 52
4.2.2染料溫度影響 54
4.2.3染料酸鹼度影響 56
4.3電化學降解試驗 58
4.3.1電流密度之影響 58
4.3.2鍍膜碳源比例之影響 62
4.3.3酸鹼度之影響 65
4.3.4薄膜電解超純水情況 69
第五章 結論與建議 73
5.1結論 73
5.2建議 75
第六章 文獻回顧 76

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