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This investigation was to study the response of thermoluminescent material CaF2:Tm phosphor (TLD-300) to protons. The sourse of proton beam was produced by a Van de Graaff accelerator with an energy range between 0.7 to 3.0 MeV. There are two kinds of anneal- ing procedures for TLD-300: one is 830 ℃ or 90 min, the other 400 ℃ for 90 min. There are two glow peaks for the high temperature treatment and three for the low temperature treatment. The peaks' positions ( Tm ) of the glow curve depend on proton energy. The proton energy was investigated by studying the peak height ratio (Hi/Hf) of the glow curve, and the thermolum- inescent efficiency (Hi/TL) of the glow-peak as well. The thermoluminescent parameters of the glow peaks for CaF2:Tm dosimeters were analyzed experimentally by using initial rise and glow curve shape analysis (GCS) methods. The following are the results: 1. The glow-curve distribution can be distinguished between proton and gamma radiation. 2. The proton energy can be determined by the calibration curves of the Hi/Hf or Hi/TL. 3. The activation energies of Co(60) gamma-ray irradiated TLD-300 were 1.09 and 1.86 eV. The kinetic orders were 1 and 2 for the third and fifth peak respectively, which were determined by the GCS method. When the GCS method was applied in the proton- irradiated TLD-300, the fifth peak only could be determined with an activation energy of 1.78 eV and kinetic order of 2. The use of initial rise method for the determination of activation energies for the three main peaks, one can obtain the three energies as 1.95, 2.38 and 2.75 eV.
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