臺灣博碩士論文加值系統

氫能與燃料電池屬於新興淨潔能源領域，一般公認其適用於行動載具或定置型發電系統中，更進一步可取代目前所用的汽柴油引擎和燃煤火力發電廠，以創造更潔淨的生活環境。
本論文主要是研究利用氫能與燃料電池技術產生電力。利用美國Argonne 國家實驗室所發展出的GCtool能源系統模擬軟體，來模擬氣渦輪機發電、1kWe整合氫氣重組器和質子交換膜燃料電池發電、及複合式發電系統、建構自己的發電系統模型。同時建造一個簡單的1kWe質子交換膜燃料電池發電裝置，把所模擬出的參數來和實驗數據進行確認；來驗證所撰寫的程式及想法，從中學習GCtool操作及氫能與燃料電池的特性，累積實務經驗。
本論文在利用GCtool所建立的發電系統模型，大抵可以和實作的系統互相印證。所以，藉由本研究的探討，在未來在建造大型或是分散式發電系統時，可以做為放大的設計工具(Design Tool for Scaleup)和理論的參考值。

The hydrogen and fuel cell technologies belong to the field of new clean energy. In general, it is well-known that they are suitable for vehicles or stationary power generation systems. Future more, they can replace gasoline and diesel combustion engines, and coal-fired power generation at the present time for a cleaner environment.
The major research of this thesis is to utilize hydrogen and fuel cell technologies to produce electricity. By using Argonne National Laboratory’s(ANL’s) simulation software, GCtool, a simulation model of the electrical power generation system is built and established; they include gas turbine electrical power system, 1-kWe combine hydrogen production and fuel cell power system, and hybrid of fuel cell and gas turbine power system. In the meantime, a simple 1-kWe fuel cell power system is built and installed. The simulation parameters and result are validated by the experimental data. This would validate our proof-of-concepts and gain our learning experience from GCtool operations, model simulation, H2/Fuel Cell characteristics.
The results of this research that utilizes GCtool models generally have a good agreement with experiment data. Thus, the models from the research could be used as a scale-up tool and theoretical basis for building a large power plant in the future.

封面內頁
簽名頁
授權書………………………………………………………………iii
中文摘要……………………………………………………………iv
ABSTRACT……………………………………………………………v
誌謝…………………………………………………………………vi
目錄…………………………………………………………………vii
圖目錄…………………………………………………………………x
表目錄………………………………………………………………xii

第一章 序論…………………………………………………………1
1.1 前言…………………………………………………………1
1.2 研究動機……………………………………………………2
1.3 論文架構……………………………………………………2
第二章 文獻回顧……………………………………………………4
2.1 產氫技術……………………………………………………4
2.1.1 水電解產氫…………………………………………4
2.1.2 石化原料重組產氫………………………………6
2.1.3 生物產氫……………………………………………6
2.1.4 電漿產氫……………………………………………9
2.1.5 熱電漿產氫…………………………………………10
2.2 燃料電池…………………………………………………11
2.2.1 燃料電池的發展演進………………………………11
2.2.2 燃料電池基本發電原理……………………………13
2.2.3 燃料電池的分類……………………………………15
2.2.4 燃料電池的優缺點…………………………………18
2.3 國內外GCtool使用情形…………………………………19
第三章 各式發電模擬結果………………………………………21
3.1 GCtool 簡介………………………………………………21
3.1.1 泵(Pump)……………………………………21
3.1.2 熱交換器 (Heat Exchangers)………………………22
3.1.3 質子交換膜燃料電池 ( PEMFC )…………………23
3.1.4 混合器………………………………………………24
3.1.5 分流器………………………………………………24
3.1.6 加熱器………………………………………………25
3.2 建構自己的發電模擬模型 (GCtool模擬實例)…………25
3.2.1 渦輪機發電…………………………………………25
3.2.2 1kW PEMFC產氫發電系統………………………29
3.2.3 固態氧化物燃料電池加上氣渦輪機發電…………30
3.2.4 1kW PEMFC發電…………………………………33
第四章 實驗方法與實驗結果討論………………………………37
4.1 燃料電池發電系統實作…………………………………37
4.1.1 實驗儀器設備………………………………………37
4.1.2 實驗架設……………………………………………39
4.1.3 實驗變因……………………………………………41
4.1.4 實驗步驟……………………………………………42
4.2 實驗結果與討論……………………………………………42
第五章 結論與未來展望…………………………………………48
5.1 結論………………………………………………………48
5.2 未來工作…………………………………………………50
參考文獻……………………………………………………………52

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