臺灣博碩士論文加值系統

本篇論文主要是以3-phenoxypropyl bromide做為alkylation reagent和N-confused prophyrin進行反應，得到2-aza-2-(3’-phenoxypropyl)-5,10,15,20- tetraphenyl N-confused porphyrin，2-NCH2CH2CH2-O-C6H5NCTPPH (2)。再以Ni(OAc)2及Cu(OAc)2這兩種金屬試劑分別與2-NCH2CH2CH2-O-C6H5NCTPPH (2)進行反應便可得到Ni(2-NCH2CH2CH2OC6H5NCTPP)(3)及Cu(2-NCH2CH2CH2OC6H5NCTPPO)(4)兩種不同的金屬錯化合物。再以X-ray單晶繞射儀、核磁共振光譜儀、電子順磁共振光譜儀等儀器來鑑定金屬錯化合物的結構及分析比較分子的特性。

We use 3-phenoxypropyl bromide as alkylation reagent to react with N-confused porphyrin to get 2-aza-2-(3’-phenoxypropyl)-5,10,15,20- tetraphenyl N-confused porphyrin，2-NCH2CH2CH2-O-C6H5NCTPPH (2)。And we use Ni(OAc)2、Cu(OAc)2 to react separately with 2-NCH2CH2CH2-O-C6H5NCTPPH (2) to get two different complexes，Ni(2-NCH2CH2CH2OC6H5NCTPP) (3) and Cu(2-NCH2CH2CH2OC6H5NCTPPO)(4). Then we use X-ray Single-Crystal Diffeactometer、NMR spectroscopy and EPR spectroscopy，etc.，to determine the crtstal structure of complexes and to compare and analyze the molecular characteristics.

目錄
摘要 i
圖目錄 v
表目錄 viii
第一章 緒論
一、引言 2
二、N-confused porphyrin 的形式 4
三、合成N-confused porphyrin 6
四、N-confused porphyrin 之alkylation反應 7
五、實驗室研究發展 8
第二章 free base 2-NCH2CH2CH2OC6H5NCTPPH(2)及金屬鎳之porphyrin錯化合物 Ni(2-NCH2CH2CH2OC6H5NCTPP) (3)的合成與分子結構探討
一、實驗步驟 10
二、X-Ray晶體結構資料及1H NMR 光譜數據 14
三、結果與討論 30
第三章 N-confused porphyrin inner C-oxide之銅及銠金屬錯化物Cu(2-NCH2CH2CH2OC6H5NCTPPO)(4)、Rh(2-NCH2C6H5NCTPPO)Cl (6)的合成與分子結構探討
一、實驗步驟 37
二、X-Ray晶體資料及UV/Vis、ESR、NMR光譜資料 39
三、結果與討論 51
總結 60
參考文獻 62
附錄
附錄一、試藥及溶劑 65
附錄二、儀器設備 66
附錄三、儀器之測定方式 67
附錄四、晶體CIF Check 資料 69
附錄五、晶體之元素分析數據 73
附錄六、晶體數據資料 79

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