臺灣博碩士論文加值系統

本論文主要是使用溴甲苯(benzyl bromide)做為alkylation 反應的試劑，與N-confused porphyrin反應生成2-NCH2C6H5NCTPPH，以Mn, Ni, Pd, Ag做為金屬試劑，生成Mn (2-NCH2C6H5NCTPP)Br; Ni(2-NCH2C6H5NCTPP); Pd(2-NCH2C6H5NCTPPH); [ Ag2(2-NCH2C6H5NCTPP)2]2+∙[Ag2(O2CCF3)4]2- 和 Ag(2- NCH2C6H5 -3-O-NCTPP) 等五種金屬錯化物。
再藉由X-ray 單晶繞射和核磁共振光譜儀與電子順磁共振光譜儀等儀器來鑑定錯化物的晶體結構與分子物理現象等研究加以探討。

We use benzyl bromide to proceed N-alkylation with N-confused porphyrin that synthesis 2-NCH2C6H5NCTPPH, and using Mn, Ni, Pd and Ag as metal reagent to get five complexes Mn (2-NCH2C6H5NCTPP)Br; Ni(2-NCH2C6H5NCTPP); Pd(2-NCH2C6H5NCTPPH); [ Ag2(2-NCH2C6H5NCTPP)2]2+∙[Ag2(O2CCF3)4]2-and Ag(2- NCH2C6H5 -3-O-NCTPP).
Then we use X-ray Single-Crystal Diffeactometer, NMR spectroscopy and EPR spectroscopy, etc., to determine the crystal structure and discuss their physics phenomenon.

摘要……………………………………………………………………i
圖目錄…………………………………………………………………v
表目錄…………………………………………………………………ix
第一章 緒論………………………………………………………… 1

第二章 空環2-NCH2C6H5NCTPPH及金屬化紫質，錳、鎳、鈀之porphyrin錯化物
Mn (2-NCH2C6H5NCTPP)Br; Ni(2-NCH2C6H5NCTPP); Pd(2-NCH2C6H5NCTPPH)的合成與分子探討
一、 實驗步驟……………………………………………………7
二、 X-Ray晶體結構分析……………………………………… 12
三、 分子結果討論………………………………………………36

第三章 逆磁金屬Ag(III)的錯化物([ Ag2(2-N-CH2C6H5NCTPP)2)]2+[Ag2(O2CCF3)4]2- )與 Ag(2- NCH2C6H5 -3-O-NCTPP)
的合成與分子結構探討
一、 實驗步驟……………………………………………………52
二、 X-Ray晶體結構分析……………………………………… 54
三、 分子結果討論………………………………………………71
參考文獻………………………………………………………………88
附錄
一、 實驗用藥品…………………………………………………90
二、 儀器之測定方式……………………………………………91
三、 晶體CIF Check 資料………………………………………93
四、 Pd(2-NCH2C6H5NCTPP) (5) ESI-MS………………………98
五、 ([ Ag2(2-N-CH2C6H5NCTPP)2)]2+[Ag2(O2CCF3)4]2-) (6)之正離子
ESI-MS………………………………………………………99
六、 ([ Ag2(2-N-CH2C6H5NCTPP)2)]2+[Ag2(O2CCF3)4]2- (6)之負離子
ESI-MS……………………………………………………100

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