臺灣博碩士論文加值系統

近年來由於塑膠製品污染嚴重,回收再利用已為環保之重點,藉此僅以廢棄
聚苯乙烯或稱保力龍試作回收再利用，使其成為高附加價值的反應性染料
或苯唑物，以期解決部分公害環保問題。即將聚苯乙烯為原料,以濃硝
酸與濃硫酸之混酸硝化為硝化程度不同之硝基聚苯乙烯(
Nitropolystyrene,NPS)，進而以混酸用量來控制硝化度,因NPS不溶於水,
為其成為水溶性所以將NPS再經磺化得硝基聚苯乙烯-磺酸(NPS-SA,
Nitropolystyrene-Sulfonic acid，NPS-SA),於水溶液中再以低亞硫酸鈉
（Na2S2O4)還原成胺基聚苯乙烯-磺酸（Aminopolystyrene-Sulfonic
acid，AMPS-SA)。其胺基與三氯三聚氰（Cyanuric chloride)第一個氯結
合後與偶氮染料或苯唑物上之胺基結合第二個氯,剩餘一個氯就與棉纖
維上之氫氧基反應成為反應性染料,並以染色及螢光光度計的測試來了解
反應性高分子偶氮染料或苯唑物之性質。

The reuse waste foaming polystyrene(PS) have received
considerable attention for years . In order to resolve the
pollution of PS , we try to sythetize reactive-dyes or
benzoxazole compounds from PS .We are going to use a recycle
waste polystyrene , porilon , such as some process of nitration
、sulfonation and then reduction to get active amino and water
soluable sulfonic group on the phenyl of polystyrene .The amino
function will be reacted with first chloro of trichlorotriazine
, then send chloro with dyes or benzoxazole , to give a reactive
dye or reacive fluoresence . The last active chloro on the dye
can react with the hydroxy group on cotton . Dyeing test and
fluoresent quantitative analysis are used to understand the
properties of dye .