臺灣博碩士論文加值系統

專利開放日110.01.20

專利開放日110.01.20

目錄 I
圖目錄 V
表目錄 VIII
式目錄 X
摘要 1
ABSTRACT 3
第一章 緒論 5
1.1前言 5
1.2可應用於催化ɛ-己內酯開環聚合之催化劑探討 8
1.3含氮雜環碳烯N-Heterocyclic Carbene (NHC) 17
1.3.1 NHC與鋅金屬錯化合物之應用探討 20
1.3.2 NHC與鎳金屬錯化合物之C-CN鍵斷裂應用探討 24
1.4研究動機 27
第二章 配位基與鎳、鋅化合物之合成、鑑定與應用 29
2.1四氫咔唑配位基的合成 29
2.2四氫咔唑配位基鎳金屬錯化合物的合成與鑑定 36
2.2.1四氫咔唑配位基鎳金屬錯化合物的固態結構 39
2.2.2四氫咔唑配位基鎳金屬錯化合物的活性測試 42
2.3四氫咔唑配位基鋅金屬錯化合物的合成與鑑定 43
2.3.1四氫咔唑配位基鋅金屬錯化合物的固態結構 46
2.3.2四氫咔唑配位基鋅金屬錯化合物與ɛ-caprolactone聚合反應 51
2.4其他咔唑配位基合成與鑑定 59
2.5 結論 62
第三章 實驗部分 63
3.1一般實驗 63
3.2聚合方法 63
3.3物理性質測量 64
3.4實驗步驟 65
(2-bromo-4-methylphenyl)hydrazine (1)47 65
8-bromo-6-methyl-1,2,3,4-tetrahydrocarbazole (2) (4H-L-Br)47 66
8-(1H-imidazol-1-yl)-6-methyl-1,2,3,4-tetrahydrocarbazole (3) (4H-L-imidazole)47 67
8-(3-methylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazole iodide (4) (4H-L-Me-I)47 68
8-(3-benzylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazole bromide (5) (4H-L-Bn-Br)47 69
8-(3-diphenylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazole bromide (6) (4H-L-Diph-Br) 70
8-(3-butylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazole bromide (7) (4H-L-Bu-Br) 72
Bis[8-(3-methylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazolide]-Ni (4a) (4H-L-Me-Ni) 73
Bis[8-(3-benzylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazolide]-Ni (5a) (4H-L-Bn-Ni) 74
Bis[8-(3-diphenylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazolide]-Ni (6a) (4H-L-Diph-Ni) 75
Bis[8-(3-methylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazolide]-Zn (4b) (4H-L-Me-Zn) 76
Bis[8-(3-benzylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazolide]-Zn (5b) (4H-L-Bn-Zn) 78
Bis[8-(3-diphenylimidazolium-1-yl)-6-methyl-1,2,3,4- tetrahydrocarbazolide]-Zn (6b) (4H-L-Diph-Zn) 80
7-bromo-5-methyl-1,2,3-trihydrocarbazole (8) 81
7-(1H-imidazol-1-yl)-5-methyl-1,2,3,-trihydrocarbazole (9) 82
9-bromo-7-methyl-1,2,3,4,5-pentahydrocarbazole (10) 83
9-(1H-imidazol-1-yl)-7-methyl-1,2,3,4,5-pentahydrocarbazole (11) 84
8-bromo-6-methyl-9,10-dihydroindeno-indole (12) 86
8-(1H-imidazol-1-yl)-6-methyl-9,10-dihydroindeno-indole (13) 87
6-bromo-8-methyl-5,10-dihydroindeno-indole (14) 88
6-(1H-imidazol-1-yl)-8-methyl-5,10-dihydroindeno-indole (15) 89
6-(3-methylimidazolium-1-yl)-8-methyl-5,10-dihydroindeno-indole iodide (16) 90
第四章參考文獻 91
附錄一藥品廠牌 95
附錄二X-ray Data 97
附錄三Elemental Analysis Data 101
附錄四 NMR Data 102

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