臺灣博碩士論文加值系統

傳統玻璃產品越來越普及使 售價無法提高， 而成本也都上升，為了提
高利潤所以需要提高產品附加價值， 此次使用玻璃釉藥 提高產品附加價值，
而希望可以讓玻璃釉藥得烤花溫度與物理強化玻璃強化相同，可以讓未來
製成可以整合在一起。
研究以磷酸鹽玻璃為主體，改變P 2 O 5 與 SiO 2 比例 探討其系列玻璃基
本性質與結構， 使用 NMR 發現 玻璃基材隨 SiO 2 的添加使 Al 從修試劑轉
變為形成劑，用 XRD 可以發現隨 SiO 2 的添加 也出現了高方石英的結晶，
也因為有了這個結晶使添加 SiO 2 玻璃不適合用於釉藥開發。 使用低 Tg 玻
璃當作黏著劑，讓色素可以在窗玻璃強化溫度下 黏附於 璃基板上 ，配成釉
藥燒附後情況是否有附著於玻璃基板上，最後進行耐候測試檢測是否還黏
附於玻璃基板上。

Traditional window glass come down in price and various costs rise that
declining industry profits. To increase revenue should enhance their quality and
Increase added value. This study hopes to make a glaze that t empered
decoration firing and thermal at the same time.
This study exp
lores optics, physics, and structure in phosphate glass , witch
c ha nge the composition ratio of SiO 2 and P 2 O 5 The SiO2 addition c onverted A l
from glass network modifier to glass network former by NMR. Discover using
XRD i t makes the glass have the crystal of c ristobalite that the glass suitable
for use as glaze material Low Tg glass an adhesive to the pigment can adhere
to the glass at the enhanced temperature of the glazing . Colorant mixes
different proportions of low Tg glass and pigment . The Cross cut tester and
pencil hardness to confirm the condition of the glaze after the glass is fired.
Finally , t he Cross cut tester and pencil hardness to confirm the condition of the glaze after weathering test.

中文摘要 I
Abstract II
目錄 III
圖目錄 VI
表目錄 IX
第一章 緒論 1
1-1 前言 1
1-2 研究目的 2
第二章 文獻回顧 3
2-1 玻璃理論 3
2-1-1 玻璃定義 3
2-1-2 玻璃的構成要素 7
2-2 玻璃的結構分析 9
2-2-1 氧化物玻璃中的複合氧化物鍵強 9
2-2-2 氧化物玻璃中的氧角色 12
2-2-3 Raman 12
2-2-4 NMR 14
2-3磷酸鹽玻璃 15
2-3-1 磷酸鹽玻璃分類 15
2-3-2 磷酸鹽玻璃單元 16
2-3-2 NMR磷酸鹽 18
2-4矽酸鹽玻璃 22
2-3-1 鹼(土)金屬矽酸鹽 22
2-3-2 矽酸鹽玻璃結構 23
2-5 強化玻璃玻璃 25
2-5-1強化玻璃原理 25
2-5-2化學強化玻璃 25
2-5-3 物理強化玻璃 25
2-5-4 物理強化與化學強化 26
2-6分散劑 28
2-6-1分散定義 28
2-6-2分散原理 29
2-6-3分散劑結構與用量 29
第三章 實驗方法 31
3-1 實驗流程 31
3-2 實驗備製 32
3-2-1 玻璃製成 32
3-2-2 玻璃片清洗 34
3-2-3 玻璃粉與色素試片製作 35
3-2-4 色釉製作 36
3-3 色料遮蓋 38
3-4 玻璃物性實驗 39
3-4-1 TMA(熱機械性質) 39
3-4-2 DSC(差示掃描量熱法) 40
3-4-3 XRD 41
3-4-4 玻璃黏度 41
3-4-5 稜鏡耦合儀 42
3-4-6 UV-Vis 42
3-5 玻璃結構分析 43
3-5-1 NMR 43
3-5-2 Raman 43
3-6色釉試片測試 44
3-6-1 色差計 44
3-6-2 鉛筆硬度機 44
3-6-3 百格測試 44
3-6-4 耐候測試 45
第四章結果與討論 46
4-1玻璃性質結果 46
4-1-1玻璃塊材外觀 46
4-1-2玻璃結構分析 48
4-1-3玻璃折射率分析 55
4-1-4玻璃熱分析 56
4-1-5 XRD結晶分析 60
4-1-6 玻璃黏度 62
4-2色料測試結果與討論 63
4-2-1 玻璃選用 63
4-2-2 色素比例選用 66
4-3玻璃色釉燒製之結果與討論 69
4-3-1色釉附著與耐候測試 69
4 -3-1色釉顏色 71
第五章結論 74
參考文獻 75

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