臺灣博碩士論文加值系統

本論文以Hummers’ method法來製備氧化石墨烯及clear solution method製備FAU型沸石，讓二者在超音波震盪下進行混合,並直接利用FAU的合成鹼液來做石墨烯的還原劑，同時達到完成還原和複合交疊的目的。製備所得的石墨烯可以利用FT-IR、UV、XRD觀察出結構內官能基變化。結果顯示:沸石鹼液可以有效進行還原,同時在複合材料中殘餘含N化合物。
將石墨烯跟沸石依比例混溶的懸浮液，再以本實驗室的氣霧沉積方式，可有效進行石墨烯/沸石複合薄膜製備。沸石一般需要高溫鍛燒方式去除膜板，本實驗室的氣霧沉積方式可以在渡膜同時去除模板，也可以避免溶劑揮發造成團聚問題，再藉由TEM、XRD、CV等儀器進行結構、表面組態和官能基分析。
為增進石墨烯複合材料的效能, 本論文進一步利用不同離子交換來提升電容量及穩定氧化還原行為。透過獨特離子交換能力沸石將其內部的鈉離子換成高導電性的銀、鐵、鈰、鉑、銅金屬離子，並利用CV量測來了解其電容大小及氧化還原的差異性。結果顯示:離子交換樣品大幅增加電容值且平滑CV圖讓其更矩形化。

In this thesis ,we prepare two suspension solutions, first is graphene oxide suspension solution ,was synthesized following “Hummers’ method” from graphite flakes; second is FAU suspension solution ,was synthesized following an improved ”clear solution method” from Si, Al source and TMAOH; and let two solution comix under ultrasonic oscilllation , and directly use the synthetic alkali liquor of FAU to reduce the graphene oxide, and achieve the purpose of one-step reduction and also composite overlap. From the data of FTIR,XRD,UV show that zeolite alkai solution can be effectively reduced graphene oxide(GO) to graphene(RGO) while residual N compound exist in the composite samples.
In this thesis, a simple fabrication of zeolite nanocomposite thin films, deposited by vaporizing a mixing FAU and graphene suspension to a set ratio were prepared by our self-designed liquid spray system. Investigated the effects of the operating parameters such as the heating temperature on substrate, the rates of the main air, auxiliary air flow and deposition time, could prepared the good quality graphene/zeolite composite films.
In order to improve the performance of the graphene composite samples, this thesis further loading metal ion to composite samples by utilizing the unique ion exchange capacity of zeolite to increase the capacitance and stabilize the redox behavior. The sodium ions in the fresh zeolite are exchanged to conducing metal ions such as silver, iron, bismuth, platinum, copper under water bath. From the CV curve show that metal- exchage samples improve the specific electron capacity(F/g) and make CV curve smoother to rectange.

摘要 i
Abstract ii
致謝 iv
總目錄 v
圖目錄 vii
表目錄 viii
第一章、緒論 1
1-1 前言 1
1-2-1石墨烯特性 3
1-2-2石墨烯Hummers’ method製備 4
1-3沸石介紹 7
1-3-1 Faujasite (FAU)介紹 11
1.3-2 Faujasite( FAU) clear solution法製備 11
1-4複合材料 12
1-4-1 石墨烯薄膜 13
1-4-2 沸石薄膜 14
1-4-3 複合薄膜 15
1-5　研究動機 16
第二章 文獻回顧 17
2-1 石墨烯研究及發展 17
2-1-1　製備石墨烯 19
2-1-2　石墨超音波處理法 21
2-1-3 光譜分析文獻 22
2-2 利用沸石製備石墨烯的文獻 24
2-3 利用沸石製備石墨烯的文獻 24
2-4石墨烯成為電催化劑的遠景 25
第三章 材料合成與薄膜製備 27
3-1　藥品與設備 27
3-1-1　藥品 27
3-1-2　設備 28
3-2　材料合成 29
3-2-1　製備石墨烯 29
3-3鍍膜方式 29
3-3-2 烘乾塗佈法 31
3-4　氣霧沉積法之參數 33
第四章 材料與性質鑑定 34
4-1石墨烯鑑定 34
4-1-1 FT-IR 36
4-1-2XRD 38
4-1-3 TEM 39
4-2 Faujasite（FAU沸石） 41
4-2-1 製備Faujasite（FAU） 41
4-2-2 FT-IR 42
4-3複合膜鑑定 43
第五章 結論 53
參考文獻 54

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