臺灣博碩士論文加值系統

本實驗使用一套可變體積-附視窗暨影像處理系統的高壓相平衡分析裝置，以合成法量取乙基乙炔+ DMF、乙基乙炔+ NMP、1,3-丁二烯+ DMF及1,3-丁二烯+ NMP等四組雙成分系統與1,3-丁二烯+ [NMP/water = 2.09/1（莫耳比)]一組三成分系統的汽液相平衡實驗數據，量測溫度介於298.15 K ~ 348.15 K之間，平衡壓力則介於1 bar ~ 10 bar之間。實驗所量取的雙成分及三成分系統之汽液相平衡數據均分別使用NRTL-HOC及UNIQUAC-HOC模式關聯，同時也求取最適化的二元參數值。

With a synthetic method, a high-pressure phase equilibrium analyzer (PEA) with a visual-variable volume cell was used to measure the vapor-liquid phase equilibrium data for ethyl acetylene + DMF, ethyl acetylene + NMP, 1,3-butadiene + DMF, 1,3-butadiene + NMP, and 1,3-butadiene + [NMP/water = 2.09/1 (in molar ratio)] at temperatures from 298.15 K to 348.15 K and pressures from 1 bar to 10 bar. All the phase equilibrium data of binary and ternary systems were correlated with the NRTL-HOC and the UNIQUAC-HOC models, respectively, and simultaneously determined the optimal values of the binary parameters.

摘要 I
Abstract II
誌謝 III
目錄 V
表目錄 VII
圖目錄 IX
第一章 緒論 1
1-1 前言 1
1-2 研究動機與目的 2
1-3 丁二烯萃取工場 3
1-3-1 丁二烯萃取溶劑DMF –以Zeon公司為例 5
1-3-2 丁二烯萃取溶劑NMP –以BASF公司為例 5
1-3-3 丁二烯工場聚合物生成之探討 6
1-4 汽液相平衡量測裝置 7
1-5 汽液相平衡量測方法 9
1-6 汽液相平衡數據之關聯與探討 10
1-7 文獻回顧 12
1-8 本文各章重點 13
第二章 汽液相平衡量測 18
2-1 實驗裝置 18
2-1-1 可變體積高壓相平衡分析儀 18
2-1-2 汽液平衡量測裝置之主要設備 21
2-2 實驗操作步驟 22
2-3 實驗藥品 24
2-4 實驗結果與討論 24
2-4-1 C4H6與DMF或NMP之汽液相平衡觀測 25
2-4-2 1,3-Butadiene + [NMP/water = 2.09/1]之汽液相平衡觀測 27
第三章 汽液相平衡數據之關聯 49
3-1 汽液相平衡之計算 49
3-2 實驗數據之關聯 51
第四章 結論與建議 72
4-1 結論 72
4-2 建議 74
參考文獻 76
符號說明 81
附錄A 藥品之分子式與結構式 84
附錄B Q&;A 85

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