臺灣博碩士論文加值系統

本篇論文主要是以p-(trifluoromethyl)benzyl bromide做為alkylation reagent和N-confused prophyin進行反應，得到2-aza-2-
[p-(trifluoromethyl)benzyl]-5,10,15,20-tetraphenyl N-confused prophyin，2-NCH2-p-C6H4CF3NCTPPH(2)。
以Ni、Pd、Pt與Cu作為金屬試劑，生成Ni(2-NCH2-p-C6H4CF3NCTPP)(3)；Pd(2-NCH2-p-C6H4CF3NCTPP)(4)；Pt(2-NCH2-p-C6H4CF3NCTPP)(5)和Cu(2-NCH2-p-C6H4CF3NCTPP O)(6)等四種金屬錯化物。
接著藉由X-ray單晶繞射、核磁共振光譜儀及電子順磁共振光譜儀等儀器，鑑定錯化合物的晶體結構與分析分子特性。

We use p-(trifluoromethyl)benzyl bromide to proceed N-alkylation with N-confused prophyrin that synthesis 2-aza-2-[ p-(trifluoromethyl)benzyl]-5,10,15,20-tetraphenyl N-confused prophyin,we called as 2-NCH2-p-C6H4CF3NCTPPH(2).
Secondly ,we use Ni ,Pd ,Pt and Cu as metal reagent to get four complexes: Ni(2-NCH2-p-C6H4CF3NCTPP)(3)；Pd(2-NCH2-p-C6H4CF3NCTPP)(4)；Pt(2-NCH2-p-C6H4CF3NCTPP)(5) and Cu(2-NCH2-p-C6H4CF3NCTPP O)(6).
Then we use X-ray Single-Crystal Diffractometer ,NMR spectroscopy and EPR spectroscopy ,etc. ,to determine the crystal structure and to analyze the molecular characteristics.

摘 要 iii
Abstract iv
圖目錄 vii
表目錄 x
第一章 緒論 1
一、Porphyrin與N-confused Porphyrin的介紹 2
二、N-confused porphyrin之異構形態 4
三、N-Confused Porphyrin之合成研究 6
四、N-Confused Porphyrin之2-N位置alkylation反應 7
第二章
Free base 2-NCH2-p-C6H4CF3NCTPPH及鎳、鈀、鉑之porphyrin錯化合物M(2-NCH2-p-C6H4CF3NCTPP) (M=Ni2+,Pd2+,Pt2+)的合成與分子結構探討 9
一、實驗步驟 10
二、X-Ray晶體資料及1H NMR 光譜數據 15
三、結果與討論 42


第三章
N-confused porphyrin inner C-oxide之銅錯化物Cu(2-NCH2-p-C6H4CF3NCTPPO)(6) 的合成與分子結構探討 50
一、實驗步驟 51
二、X-Ray晶體資料及EPR光譜數據 52
三、結果與討論 58
總結 62
參考文獻 64
附錄 66
附錄一 實驗藥品與溶劑 67
附錄二、儀器之測定方式 69
附錄三、晶體CIFCheck資料 71
附錄四、晶體APCI-MS與ESI-MS資料 76
附錄五、晶體UV/Vis圖 81
附錄六、元素分析報告 86
附錄七、氟譜19F NMR 88
附錄八、碳譜13C NMR 92

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