臺灣博碩士論文加值系統

本研究採用一套靜態式液相循環的相平衡裝置，量測乙酸甲酯＋丙酸甲酯、乙酸甲酯＋丁酸甲酯，以及丙酸甲酯＋丁酸甲酯三組雙成分混合物溫度範圍為353.15 K ∼ 413.15 K之汽液平衡數據，實驗結果顯示每組雙成分系統皆無共沸物產生，且均為正偏差。純質成分之飽和蒸氣壓數據用Antoine方程式回歸，其平均絕對誤差皆在1％內。所量取的雙成分汽液平衡數據均可使用NRTL-HOC、UNIQUAC -HOC與Wilson-HOC模式準確地關聯。

A static-type apparatus with a liquid-phase circulation loop was used to measure isothermal vapor-liquid equilibrium (VLE) data for the binary systems of methyl acetate + methyl propionate, methyl acetate + methyl butyrate, and methyl propionate + methyl butyrate at temperatures from 353.15 K to 453.15 K. The experimental results exhibited no azeotrope formation and positive deviation in each binary system. The Antoine equation fitted the vapor pressure data of pure components to within an average absolute percentage deviations of 1％. Binary VLE data were correlated satisfactorily with the NRTL-HOC, the UNIQUAC-HOC and the Wilson-HOC models.

中文摘要
英文摘要
誌謝
目錄
圖表索引

第一章 緒論
1-1 前言
1-2 反應性蒸餾法
1-3 研究動機與目的
1-4 汽液相平衡量測
1-5 本文各章的重點

第二章 汽液相平衡量測
2-1 汽液相平衡量測裝置之主要設備
2-2 實驗裝置
2-2-1 除氣與進料系統
2-2-2 平衡系統
2-2-3 取樣與組成分析系統
2-3 待測系統與藥品
2-4 實驗程序
2-4-1 樣品進料操作步驟
2-4-2 汽相取樣分析步驟
2-4-3 液相取樣分析步驟
2-5 量測系統之測試
2-6 飽和蒸氣壓之量測
2-7 氣相層析儀之校正曲線
2-8 雙成分混合物系統之量測結果

第三章 相平衡研究之模式關聯
3-1 熱力學一致性測試
3-1-1 Gibbs-Duhem 方程式
3-1-2 熱力學一致性測試法
3-2 汽液相平衡之計算
3-2-1 實驗數據之關聯

第四章 結論與建議
4-1 結論
4-2 建議

參考文獻
符號說明
附錄A 藥品之分子式與結構式
作者簡介

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