臺灣博碩士論文加值系統

本論文提出一種，低溫、全溶液製程、製程簡單、可大面積化之鉛鹵鈣鈦礦有機/無機混成太陽電池元件。其中本論文使用鉛鹵鈣鈦礦作為主動吸光層，藉由DMSO對於PbCl2的高溶解度特性，以提高precursor溶液之濃度，並建構有機/無機混成太陽電池元件。元件結構為ITO/PEDOT:PSS/Perovskite/PCBM/Al，屬於正式太陽電池結構，適當地選擇電洞和電子傳輸層，並透過旋轉塗佈最佳化陰乾條件，讓本論文之太陽電池元件表現更佳。本論文建構之太陽電池元件效率可達7.0 %，其短路電流18.1 mA/cm2有著優異的表現。本論文所提出之鉛鹵鈣鈦礦有機/無機混成太陽電池元件挾帶著良好的效率表現及其具有可大面積化之優勢，以利未來朝向大面積元件之製作發展。

This paper proposed a low temperature, solution process, simple process, a large area of the lead halide perovskite organic/inorganic hybrid solar cell. In this paper, in which the use of lead halide perovskite as the photoactive layer. With the high solubility PbCl2 in DMSO to increase the concentration of the precursor solution, and construct organic / inorganic hybrid solar cell. Our device configuration:Glass/ITO/PEDOT:PSS/Perovskite/PCBM/Al belong to normal structure. Suitably selected the hole and the electron transport layer by spin coating and dried to optimize conditions for the performance of the solar cell of the present paper is better. In this paper, Construction of the solar cell efficiency of up to 7.0 %, short-circuit current of 18.1 mA/cm2 has excellent performance. Lead halide perovskite organic / inorganic hybrid solar cell laden with good efficiency and performance advantages of a large area can be to facilitate the production of large-area components toward future development.

要................................................................................................................................ i
Abstract .......................................................................................................................... ii
誌謝.............................................................................................................................. iii
目錄............................................................................................................................... iv
圖目錄........................................................................................................................... vi
表目錄........................................................................................................................ viii
第一章 緒論.................................................................................................................. 1
1.1 研究背景 ............................................................................................................. 1
1.1.1 前言.............................................................................................................. 1
1.1.2 太陽電池之發展.......................................................................................... 2
1.1.3 有機太陽電池之發展.................................................................................. 4
1.1.4 鉛鹵鈣鈦礦太陽電池之發展...................................................................... 7
1.2 研究動機 ............................................................................................................. 9
1.3 文獻回顧 ........................................................................................................... 10
1.4 論文架構 ........................................................................................................... 18
第二章 實驗原理........................................................................................................ 21
2.1 太陽電池基本簡介 ........................................................................................... 21
2.1.1 太陽電池基本操作原理............................................................................ 21
2.1.2 理想太陽電池等效膜型............................................................................ 22
2.1.3 實際太陽電池等效膜型............................................................................ 24
2.1.4 太陽電池基本參數.................................................................................... 27
2.1.5 太陽電池操作分析.................................................................................... 32
2.2 本論文研究理論 ............................................................................................... 37
2.2.1 主動吸光層材料........................................................................................ 37
2.2.2 電洞/電子傳輸層材料 .............................................................................. 41
2.2.3 陽/陰極材料 .............................................................................................. 43
2.3 元件結構與能帶圖 ........................................................................................... 44
第三章 實驗方法與流程............................................................................................ 45
3.1 有機/無機混成鈣鈦礦太陽電池元件製作流程 ............................................. 45
3.2 ITO玻璃基板設計及圖樣化 ........................................................................... 46
3.3 ITO玻璃基板準備與清洗 ............................................................................... 49
3.4 電洞傳輸層成膜 ............................................................................................... 50
3.5 主動吸光層成膜 ............................................................................................... 51
3.6 電子傳輸層成膜 ............................................................................................... 54
3.7 陰極金屬蒸鍍 ................................................................................................... 55
3.8 元件封裝 ........................................................................................................... 56
3.9 元件量測 ........................................................................................................... 56
第四章 實驗結果與討論.......................................................................................... 59
4.1 結構分析 ........................................................................................................... 59
4.2 主動吸光層溶劑分析 ....................................................................................... 61
4.3 高濃度主動吸光層元件製作 ........................................................................... 63
4.4 高濃度下成膜探討 ........................................................................................... 66
第五章 總結與未來展望............................................................................................ 69
參考文獻...................................................................................................................... 70

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