臺灣博碩士論文加值系統

本 研 究 主 要 探 討 聚 苯 胺 ( PANI-DBSA ) 與 熱 塑 性 彈 性 體 SEBS (Styrene-Ethylene-Butylene-Styrene) 混摻複合物之材料特性，利用溶液摻合法，溶於共同溶劑甲苯中，以不同重量比例在室溫下，調配製作 PANI-DBSA 與 SEBS 摻合之導電薄膜。藉由傅立葉紅外光譜儀( FT-IR )、紫外光-可見光譜儀( UV-Vis )、熱重損失分析儀( TGA )、掃描式電子顯微鏡( SEM )、穿透式電子顯微鏡( TEM )等測試分析摻合物的結構、導電度、相容性等性質。發現在 PANI-DBSA/SEBS=20/80 (w/w)時，有最佳相容性表現。

The electrically conductive thermoplastic elastomer based on PANI-DBSA ( polyaniline–dodecylbenzene sulfonic acid ) and SEBS ( styrene–ethylene-butadiene–styrene ) were prepared by solution blending followed by casting at room temperature after dissolving both components in toluene which behaves as a common solvent.
The composite films were characterized by infrared spectroscopy (FT-IR) thermogravimetric analysis (TGA), UV-Vis, SEM, TEM microscopy and electrical conductivity, respectively.

摘要 i
Abstract ii
誌謝 iii
目錄 iv
表目錄 vii
圖目錄 viii
第一章 緒論 1
1.1 前言 1
1.2 研究動機 2
第二章 文獻回顧 3
2.1 導電高分子 ( Conducting polymer ) 發展 3
2.2 聚苯胺 ( Polyaniline ) 9
2.2.1 聚苯胺之合成方法 14
2.2.2 聚苯胺之聚合機構 22
2.2.3 聚苯胺之摻雜 23
2.2.4 聚苯胺之性質 28
2.2.5 聚苯胺之應用 33
2.2.6 聚苯胺之混摻 37
2.2.7 SEBS之簡介 40
第三章 實驗程序 44
3.1 實驗藥品 44
3.2 儀器設備 47
3.3 實驗流程 52
3.3.1 聚苯胺(PANI-DBSA)之製備 52
3.3.2 PANI-DBSA/SEBS複合膜之製備 53
3.4 實驗步驟 54
3.4.1 聚苯胺(PANI-DBSA)之製備 54
3.4.2 混摻(Blending)製備PANI-DBSA/SEBS複合膜 55
3.5 性質測試 56
3.6 實驗代號 59
第四章 結果與討論 60
4.1 聚苯胺(PANI-DBSA)與熱塑性橡膠SEBS之FT-IR鑑定 60
4.2 PANI-DBSA/SEBS摻合物之導電度分析 64
4.3 PANI-DBSA/SEBS摻合物之FT-IR分析 68
4.4 PANI-DBSA/SEBS摻合物之TGA熱性質分析 69
4.4.1 熱重損失行為 69
4.4.2 碳殘餘量計算 71
4.5 PANI-DBSA/SEBS摻合物之UV-Vis分析 73
4.6 PANI-DBSA/SEBS摻合物之SEM分析 76
4.7 PANI-DBSA/SEBS摻合物之TEM分析 81
4.8 PANI-DBSA/SEBS摻合物相容性之分析 85
第五章 結論 90
參考文獻 91
自傳 97

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