臺灣博碩士論文加值系統

摘要
有機發光二極體材料近年來成為一種非常重要的電激發光材料，在相關文獻報導中，具1,3,4-(口咢)二唑環與(口卡)唑環衍生物，具有良好傳輸電子及阻擋洞子傳輸的功能，且其相關的衍生物也常被運用於發藍光的電激發光材料中。
本論文以3-(口比)啶甲酸乙酯及α-氯醯基芳香(月井)•氯化氫為原料，經由一連串的反應，合成出具1,3,4-(口咢)二唑環、1,2,4-三唑及(口卡)唑環的多雜環化合物。並將所得的產物透過UV-Vis、PL及CV的測試來探討其光電性質。
希望藉由光電性質的探討，拓展α-氯醯基芳香(月井)•氯化氫在合成小分子有機電激發光材料上的應用。

Abstract
Organic compounds, which can be used to make organic
light-emitting diodes, have recently become an interesting and
important material. Research on looking for potential target
compounds has been studied intensively. Compounds derived from
1,3,4-oxadiazoles and carbazoles had been reported having good
electron-transporting and hole-transporting properties and
had been applied as blue light-emitting materials.
In this thesis, polyheterocyclic compounds containing the moiety of 1,3,4-oxadiazole,carbazole, or 1,2,4-triazole were synthesized through series reactions. The electroluminiecent properties for the obtained products were studied by analyzing UV-VIS, PL,and CV spectra.
In this study we have shown that it is possible to synthesize potential target compounds, polyheterocyclic compounds, by starting from α-chloroformylarylhydrazine•hydrochochloride to make OLED device.

中文摘要
英文摘要
第一章、有機發光二極體的介紹
1-1、簡介 3
1-2、元件介紹 5
1-3、材料特性的需求 10
1-4、元件基本結構 12
1-5、未來展望 20
參考文獻 22
第二章、α-氯醯基芳香(月井)•氯化氫與3-(1,3,4-(口咢)二唑)(口比)啶化合物之環化反應
2-1、簡介 24
2-2、結果與討論 27
2-3、實驗部份 33
第三章、α-氯醯基芳香(月井)•氯化氫與含(口卡)唑之(口比)啶化合物之環化反應
3-1、簡介 50
3-2、結果與討論 50
3-3、實驗部份 58
第四章、光電性質之研究
4-1、實驗儀器與裝置 68
4-2、各化合物光電性質之探討 69
第五章、結論 88
參考文獻 90

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